查询词典 electronegativity

Based on theoretical calculation of electronegativity of groups offlotation-reagent and method of infra-red adsorption spectroscopy, the collection andadsorption of α-nitroso-β-naphthol in hematite flotation have been studied. The chemicaladsorption seems to be predominant owing to formation of pentacyclic nitrosyl chelate com-pound by atoms of nitrosyl bond in α-nitroso-β-naphthol together with Fe~(3+) on hematitesurface.

研究了α-亚硝基β-萘酚对赤铁矿的捕收性能及吸附规律，导出了吸附方程和吸附速率方程用药剂基团电负性理论计算以及红外吸收光谱法论述了其作用机理α-亚硝基β—萘酚主要是以N O键合原子与赤铁矿表面的Fe形成N O五元环螯合物而化学吸附。

This means that the determination of oxide ion polarizability aO2 and optical basicity L by means of optical electronegativity Dwglass may also be used as an alternate approach.

这意味着测定氧离子极化和ao2 光学碱度升的方式光学电 DW的玻璃也可能被用来作为替代办法。

In this paper, we introduce the optical electronegativity Dwglass, to predict basic properties of binary oxide glasses (phosphate, borate, silicate, germinate, tellurite, and titanate).

在本文中，我们引入光学电 DW的玻璃，预测的基本性质二元氧化物玻璃（磷酸盐，硼酸盐，硅酸盐，发芽，碲，钛酸）。

Sythesizing thevalence electron number, electronegativity and atomatic radius of the alloying element, thecharacteristic value may be fixed at 4.223 in Ti alloy, and which may be expressed as4.223=∑N_if_i+0.310△x / x_+0.551 △r / r_Ti

综合合金元素的价电子数、化学负电性和原子半径三个因素，钛合金中ω相形成的特征值可定为4.223，其表达式为 4.223=∑Nf_i+0.310Δx/x_+0.551Δr/r_Ti

Similar to the oxidation process of Si(111)-7×7 by water,the gradual insertion of S atom into Si_a-Si_s backbond is possible to occur,and the insertion pathway,which begins with directly destroying Si_a-Si_s backbonds by a foreign H_2S molecule,remains more favorable.However,when H_2S attacks at the Si_a site to split Si_a-Si_s backbond with its S or H atom,there is no distinct thermodynamical and kinetical difference between these two attacking behaviors,whereas Si_a-Si_s backbond is easilier broken when H_2O attacks at the Si_a site with its O atom.This mainly lies in the fact that the electronegativity of oxygen is larger than that of sulfur.

5类似于H_2O对Si(111)-7×7的氧化历程，S原子逐步插入Si_a-Si_s键是可以发生的，且H_2S直接打开Si_a-Si_s键进而使S原子插入的途径仍是动力学上较为有利的，但H_2S以S或H原子进攻Si_a位从而打开Si_a-Si_s键的两种反应机制在动力学和热力学上并没有表现出明显的差别，而当H_2O以O原子进攻Si_a位时，Si_a-Si_s键则较容易断裂，这应归因于O的电负性比S大。

The smaller the electronegativity is, the higher oxidation activity is. Thus phosphomolybdic acid shows better catalytic oxidation activity than phosphotungstic acid.

由于磷钨酸中的钨可以脱出并少量沉积到催化剂表面，而且从电负性来说Mo-O的键能小于W-O，键能小的杂多酸有较强的氧化性，所以钼系杂多酸催化活性要好于钨系杂多酸。

Because the tungsten from the phosphotungstic acid could pull out and deposit on the surface of catalyst, and the electronegativity of Mo-O is smaller than that of W-O.

最后，根据杂多酸的结构和相应的物理化学性质，对杂多酸与铂基催化电极电催化氧化甲醇的机理进行了初步探讨。

Comparisons show that there is no correlation between the experimental sensitivity of tetrazole compounds and various previously proposed theoretical static criteria, such as the bond length and bond order of relevant bonds, net atomic charges and electronegativity and the content of 2H-teterazole isomers in both gaseous and condensed states.

把四唑衍生物的实验感度与前人曾提出过的各种感度理论判据—一些静态结构性质(如相关键的键长、键级、原子电荷和电负性等)以及平衡体系中2H-异构体的含量—进行比较，均未找到它们之间的规律性联系。

With the assumption that the electrostatic field strength of met a l chelates can be measured by the ratio of electronegativity vs.

在C18柱上试验以各种有机溶剂洗脱金属螯合物，最终选择了甲醇-丙酮的非水体系作流动相。

The fluorescence spectra of Eu~(3+) may be used to study the structure ofcompounds.The band shift of Nd~(3+) in its absorption spectra,the red-to-orangeintensity ratio of the Eu~(3+) emission(~5D_0→~7F_2)/(~5D_0→~7F_1)and the yellow-to-blue intensity ratio of the Dy~(3+) emission~4F_(9/2→~6H_(13/2)/~4F(9/2→~6H(15/2)intheir fluorescence spectra may be used to study the degree of covalency of theLn-O bond and its relation with the electronegativity of M in Ln-O-M.

本文介绍了利用 Eu~(3+)的荧光光谱研究化合物的结构；利用 Nd~(3+)的吸收光谱的谱带位移和 Eu~(3+)的荧光光谱的红橙发射强度比(~5D_0→~7F_2)/(~5D_0→~7F_1)和 Dy~(3+)的黄兰比~4F_(9/2→~6H_(13/2)/~4F_(9/2→~6H_(15/2)，了解Ln—O—M中 Ln—O 化学键的共价程度以及 M 的电负性对共价程度的关系；利用吸收光谱、荧光光谱和磁化率研究稀土的价态以及利用磁化率研究化合物的组成。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。