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The performance and mechanism of corrosion inhibitions of POCA were studied bymethods such as weight-loss, electrochemistry, EDS, XPS and quantum chemistry. It isfound that POCA is cathodic corrosion inhibitor, having synergistic effect with HEDP andZn~(2+). The P and O atoms of phosphono have important electron density contribution toHOMO orbital and the electron gross orbital population is bigger than 1, so it is easy toform absorbing location between phosphono and metal resulting in good corrosioninhibition on mild steel.

通过利用失重法、电化学方法、扫描电镜、X光电子能谱、X-射线能谱和量子化学方法研究膦酰基羧酸的缓蚀性能及其机理，发现POCA是一种阴极型缓蚀剂，与HEDP、Zn~(2+)具有优良的协同增效作用；POCA分子中的膦酰基基团的P原子和O原子对HOMO轨道电荷密度贡献较大，且其轨道电子布居数均大于1，因此比较容易通过膦基与金属形成吸附位而对碳钢具有良好的缓蚀作用；对铜合金具有一定的腐蚀作用，但腐蚀作用比HEDP等有机膦药剂要小得多，同时与BTA具有优良的相容性，添加1mg／L的BTA则可以有效地防止铜合金的腐蚀。

Furthermore, we believe that the general rules for understanding the superstructures formed within boundary areas are correlated directly with different overlapping or connecting operation with respect to building units of flattened hexagons and P-B polygons. These rules are as following:I The adjoined domains at least have their basic structural units a side-shared (that is, sharing two column clustersП) The basic structural units in both domains have overlapping area as large as possible.3 For theξ-Al-Ni-Rh phase formed in the as-cast Al75Ni15Rh10 alloy, phase transition processes induced by electron beam irradiation with different amount of dose were studied by in-situ observations in an electron microscope.

本论文提出了畴界的通用模型：各种畴界及其畴界处超结构都可以用一个通用的叠加覆盖模型去表示，覆盖的基本单元为扁六边形或P-B多边形，连接与覆盖规则如下：I相邻畴中的基本单元至少有一个共用边相邻畴中的基本单元重叠时沿b方向有最大重叠面积。3研究了Al75Ni15Rh10合金中ξ-Al-Ni-Rh相在透射电镜电镜中经不同剂量电子束辐照后引起的辐照损伤和相变过程。

Electron Beam Ion Trap uses highly compressed electron beam to ionize ions and atoms to produces highly charged ions. lonization stages of almost any element in the Periodic Table can be produced and trapped for several hours in the EBIT.

电子束离子阱用磁场中高度压缩的高能电子束来电离离子以获得高价态离子，它可以产生元素周期表中任何元素任何价态的离子，并且能够在EBIT中的强磁场和静电势阱中约束足够长的时间。

However, the spectral stability was increased, and the 0-1 transition and the full width at the half-maximum of photoluminescence spectra was decreased with the increase of the alkoxy length on phenylene. The nature (e.g. electron-donating and electron-withdrawing) of the substituted side groups on phenylene has obvious effect on the optical properties, QY and electrochemical properties of the polymers.

苯环上取代侧基的给吸电子性质变化对聚合物的光电性能具有全面的影响，改变取代侧基的给吸电子性质可调节芴苯共聚物的发光颜色和HOMO、LUMO能级以及HOMO-LUMO能隙等，因此，通过引入不同性质的侧基可以实现对此类聚合物光物理性能的调控。

The most parts of thesis as follows:1. Five symmetrical intra-molecular charge transfer oligomeric phenylene vinylene light emitting materials were designed and synthesized using oligomeric phenylene vinylene as a framework.2. The structures of target molecule were characterized by ~1HNMR,~(13)CNMR, IR, MS and element analysis.3. In order to study the influence of the location and numbers of electron-donor and electron-acceptor on their photoelectric performance by changing length of OPV chain, the UV spectra and fluorescence spectra of target compounds has been compared. We have researched into main factors effecting on material emitting red-shift; organic electroluminescence device was prepared using the compound P4. The capability of eletroluminescence was researched.4. The photoelectric properties of P4 was explained by quantum chemical calculation (the Gaussian 98 quantum chemistry program). It is greatly contributed know the whole process of charge transfer to guide the design of red emitters.

本文研究的内容主要包括以下部分：(1)设计并合成5个对称的以齐聚苯乙烯类为骨架的分子内电荷转移型齐聚苯乙烯类发光材料；(2)通过IR，MS，~1H-NMR，~(13)C-NMR和元素分析对所合成的目标化合物进行表征；(3)通过对目标化合物的紫外光谱和荧光光谱比较分析，研究改变OPV的长度，电子给体和电子受体的位置及数量对其光电性能的影响，探讨材料发射红移的主要因素；选取性能良好的目标化合物P4制备成OELD器件，对其电致发光性能进行研究；(4)运用Gaussian98量子化学程序包，采用量子化学方法对目标化合物P4的光电性能从理论加以解释，进一步认识荷移跃迁的整个过程，为红光材料的设计加以指导。

In electronics, the ability of the CRT phosphor dots to withstand local over- heating due to the conversion into heat of the residual energy of the electron beam, i.e. that part of the electron beam energy that is not converted into visible light.

在电子学中，指阴极射线管的荧光粉承受局部过热的能力，这种过热是由于电子束的残余能量，即电子束没有转变成可见光的那部分能量，转变成了热。

If under ideal conditions, one electron-hole pair injected yields one blue photon and the quantum efficiency of the phosphor equals one, the numbers of electron-hole pair must equal to the numbers of white photons. So LW white LED radiation power output has to consume 1.51 W electric powers and the luminous flux efficiency limitation of electrical to optical conversion for the white LED is 197.8lm/W at above condition.

在理想情况下，注入一个电子－孔穴对产生一个蓝光光子，设荧光粉的量子效率为1，因此，注入的电子－孔穴对数亦等于白光光子数，进而计算出白光LED每辐射1W的光功率所需的电功率为1.51W，上述白光LED发光光谱对应的白光LED的电－光转换的理论极限流明效率为197.8lm/W。

The result showed that the luminous flux for LW white LED radiation power output is 298.7 lm and the total photons are 2.7×1018. If under ideal conditions, one electron-hole pair injected yields one blue photon and the quantum efficiency of the phosphor equals one, the numbers of electron-hole pair must equal to the numbers of white photons.

在理想情况下，注入一个电子-孔穴对产生一个蓝光光子，设荧光粉的量子效率为1，因此，注入的电子-孔穴对数亦等于白光光子数，进而计算出白光LED每辐射1 W的光功率所需的电功率为1.51 W，上述白光LED发光光谱对应的白光LED的电-光转换的理论极限流明效率为197.8 lm/W。

Mn-complexes in which Mn atom ligand with the N atom within ligand can stimulate the recovery of electron transfer and oxygen evolution. The trinuclear Mn-complex is extremely sensitive to the addition of CaCl2. It is suggested that there is an interaction between Ca2 and carboxyl within the trinuclear Mn-complex during photoactivation and this interaction benefits the ligation of Mn atom to the apo-WOC and form an active WOC. Binuclear MnMn complex shows slightly higher efficiency than binuclear MnMn complex in restoration of O2 evolution activity. It is suggested from our results that recovery of electron transport and O2 evolution with synthetic Mn-complexes is affected by different factors. Cl- can stimulate the reconstitution of WOC at the concentration of over 100mM;the maximal recovery of O2 evolution activity requires the presence of CaCl2 and 33 kDa protein polypeptide together. Bicarbonate can stimulate the reconstitution of WOC.

锰配合物中锰原子与配体中的氮原子配位连接时，能显著恢复电子传递活性和放氧活性；三核锰化合物在重组时对CaCl2的存在非常敏感，我们认为Ca2 与三核锰化合物中的羧基之间存在一定的相互作用，而这种作用有助于锰原子的光配位进而使三核锰化合物易于组装成有活性的水氧化复合物：双核锰化合物MnMn比双核锰化合物MnMn在恢复放氧活性方面更有效；影响锰化合物电子传递能力恢复的因素与影响锰化合物放氧活性恢复的因素不同；在锰蔟重组过程中，氯离子的浓度必须在100mM以上，才能有效进行光重组；最大光重组效率的获得必须有钙离子和33kDa多肽同时存在；碳酸氢根离子促进锰化合物与去锰光系统II的光组装。

Objective In order to explore the morphological evidence for the pathway for secretions of pineal body releasing directly into the cerebrospinal fluid. Methods Using the conventional and NaOH-macerational methods for preparing electron microscopic specimens,the pineal bodies and its capsules of adult Japanese monkeys were observed with scanning and transmission electron microscope.

目的 探讨松果体分泌物直接释放入脑脊液途径的形态学依据，方法采用常规及NaOH消蚀法电镜样品制备技术，对成年日本猴松果体及其被囊进行了扫描和透射电镜观察。

Article 144 The Government of the Hong Kong Special Administrative Region shall maintain the policy previously practised in Hong Kong in respect of subventions for non-governmental organizations in fields such as education, medicine and health, culture, art, recreation, sports, social welfare and social

第一百四十四条香港特别行政区政府保持原在香港实行的对教育、医疗卫生、文化、艺术、康乐、体育、社会福利、社会工作等方面的民间团体机构的资助政策。原在香港各资助机构任职的人员均可根据原有制度继续受聘。

Small wonder, then, that the Chinese spend more in the shop than any other group of foreign visitors do .

这样的小惊喜，使中国顾客比任何国家的人消费得更多。