查询词典 electrolysis

The influence and effect of boracic acid,glue and wetting agent during nickel electrolysis cathodic process were studied and the method of on-line control in nickel electrolysis cathodic process was also put forward.

研究了镍电解阴极过程中硼酸、胶、润湿剂的影响与作用，提出镍电解阴极过程中添加剂在线监控的新方法。

Results show that the best value of w is 7~10% and 5~7%, i is 0.08~0.2 A/cm^2 and 0.03~0.05 A/cm^2 respectively, during the electrolysis fluorination of pyridine and tributylamine; the addition of N-butyl mercaptan into the organic mixture can stabilize electrolysis process with its mass fraction 15~20% at best; impulse current polarization work status of low load is helpful to the electrolysis process and reduces corrosion rate of anode; electrolysis temperature is suitable at 0~20℃; electrobath can use electrolyte inner circulation structure, exterior circulation structure or blending structure.

结果表明：吡啶和N-三丁胺电解氟化的最佳值w分别为7%~10%和5%~7%，i分别为0.08~0.2A/平方公分和0.03~0.05A/平方公分；有机混合物中添加N-丁基硫醇可稳定电解过程，其质量分数最佳为15%~20%；采用低负荷的脉冲电流极化工况有利电解过程，降低阳极的腐蚀速度；电解温度0~20℃为宜；电解槽可采用电解液内循环、外循环结构，或其混合结构。

By means of investigation of parameters (reactant strengths electrobath voltage reaction time reaction temperature membrane stuff material variety and the additive) in the sulfate and sulphuric acid electrolysis process, and compared the electrolysis process through analyzing several important technique factors, found the optimized parameters of peroxysulphate and peroxysulphuric acid electrolysis preparation.

通过对硫酸铵、硫酸电解过程中各工艺参数(反应物浓度、槽电压、反应时间、反应温度、膜材料、阴极室物料种类、添加剂)的考察，并结合对电解过程中重要技术指标的比较分析，确定了电解制备过二硫酸铵以及过二硫酸的较优条件，为工业化电解制备过二硫酸铵以及过二硫酸提供了可靠的基础数据以及工艺参数。

In this process, the discharge process of single point to point contact is transformed to the process of both point to point contact and the overall surrounding contact of sphere Ni through the self redox reaction, thus making a highly efficient electron transfer process. In this dissertation, the catalytic electrolysis mechanism is discussed. The influence of various parameters (e.g. kind and concentration of catalyst, reaction temperature and electrolysis duration) on electrolysis were investigated.

本文首次提出了以KMnO_4为代表的高锰酸盐作为电解过程电子传递的媒介，通过锰盐自身氧化还原反应的参与，在阳极和溶液中的球形Ni_2之间建立起高效的电子转移过程，使球形Ni_2和阳极之间单一的固体之间的点点接触放电，转变为点点接触放电和球镍与溶液全方位包围接触放电过程，大大提高了电解过程的效率。

The system consists of electrolysis rectifier unit, electrolysis heat exchange unit, electrolysis temperature control unit, etc.

该实验台由电解整流系统、电解液热交换系统及电解温度控制系统等组成。

The synthesis mechanism of Al_(13)in the process of electrolysis was discussed,the effects of electrolysis voltage,the original concentration of Al~(3+),the circulation mixing rate of the electrolyte and the exchanging frequency of the electrodes on the synthesis velocity of Al_(13),ratio of Al_(13)in total Aland the electrolysis time were studied.

本工作对电解过程中Al_(13)的形成机理进行了探讨，并研究了电解电压、Al~(3+)的初始浓度、电解液的循环搅拌速度和阴阳电极的互换频率对Al_(13)的合成速度、Al_(13)占总铝的比率及电解所需时间的影响，得出了电解法制备Al_(13)的最佳工艺条件：电极互换频率为1次·min~(-1)、电解液中Al~(3+)的初始浓度为0.5000mol·L~(-1)、电解电压为12V和0.5L·min~(-1)的电解液循环搅拌速度，在此条件下电解125min可制得碱化度为82.0%，Al_(13)占总铝的比率达91.2%的液体产品。

Preparation of the cathode includes:shaping under the press of 40Mpa, sintering at 550℃for 1 hour and at 900℃for 8 hours and threading with molybdenum bar; Considering the literatures we choose CaCl2 as salt for preparation titanium. Pretreatment of salt is for 1 hour at 100℃and for 2 hours at 300℃. Partial pressure of oxygen which need lower than 5.11×10-7Pa to reduct titanium oxides and hygroscopic property of salt need a sealed equipment to electrolyse. And finally successfully designed a satisfied one and the results show that the equipment can be satisfied the requirment of the experiment. Flow of the inert gas is 1.5L/min, the voltage is 2.8 V, temperature is 850℃and time is 2 hours during pre-electrolysis. Flow of the inert gas is 0.2L/min, the voltage is 3.1 V, temperature is 900℃and time changes with the mass of TiO2 during electrolysis, namely the greater need the longer time; To eliminate influence of salt and other impurities, the products need to wash with distilled water and dilute chlorhydric acid , then wash with dilute hydrochloric acid under supersonic wave assistant. Finally, electrometical properties of the electrolysis of TiO2 is researched by cyclic voltammetry and chronoamperometry, and results show that there are two main reodox steps, namely from TiO2 to TiO and from TiO to Ti.

阴极制备主要包括40MPa压力下模压成型、两段式烧结(1小时内升至550℃保温1小时，再1小时升温至900℃保温8小时)及烧结后TiO2块打孔用钼棒串接三个主要环节；实验中选用CaCl2作为电解熔盐，并对其进行预处理(100℃，保温1小时； 300℃，保温2小时)；经热力学计算，还原钛氧化物的氧分压至少要低于5.11×10-7Pa，结合电解过程中所用熔盐CaCl2有极强的吸水性的特点，电解装置应有较高的密封性，自行设计了一套密封性可靠的电解装置，便于实验过程中熔盐预处理和氧分压的控制；通过干燥处理预电解过程中Ar流量大约为1.5L/min、电压为2.8 V、温度为850℃、时间为2小时，电解过程中Ar流量大约为0.2L/min、电压为3.1V、温度为900℃，实验结果表明电解时间与TiO2质量密切相关，质量越大需要电解的时间越长；通过自来水冲洗—稀盐酸浸泡、洗涤—在超声波辅助作用下稀盐酸洗涤，可减少熔盐及其它杂质对电解产物检测结果的影响；最后，通过循环伏安法、计时电流法对电解机理的研究，确定电解还原TiO2制备金属钛主要经历了TiO2-TiO-Ti的过程。

The invention relates to an electrochemical method for preparing ultra-fine tantalum powder, wherein it uses the mixture slat flux with CaCl2 or CaCl2 as electrolyte; composites Ta2O5 powder/block with metal collector as solid cathode; uses graphite or inertia anode as anode; uses reference polar to control the electrolysis level, under inertia gas to electrolyze at 500-1000Deg. C; and the electrolysis time should make electrolysis electricity reach needed amount; reduces Ta2O5 into ultra-fine metal tantalum powder.

本发明涉及一种超细钽粉的电化学制备方法，以CaCl2或者含有CaCl2的混盐熔体为电解质，将Ta2O5粉末或块与金属集流体复合作为固态阴极，以石墨或惰性阳极作为阳极，用参比电极控制电解电位在惰性气氛保护下进行电解，电解温度控制在500-1000℃，控制电解时间使电解电量到达到理论所需电量及以上，将五氧化二钽电化学还原为超细金属钽粉。

From the coupled simulation optimization result analysis, the 10KA drained cathode rare earth electrolysis cell may be used trying to produce in the rare earth electrolysis industry, the new direction for the new rare earth electrolysis cell structure research has been opened.

从仿真优化结果分析，该槽型可以用于稀土电解的工业试生产，这为新型稀土电解结构的研究开辟了新方向。

Oxidizing feature which is oxidizing leaching of every element, studied kinetics of anode oxidation, analyzed oxidizing slag with XRD and SEM during suspension electrolysis of zinc sulphide mine. The results show that zinc sulphide concentrate in different suspension electrolysis solution can be oxidized. However, the ore in zinc sulphide, ammiaonia sulfate and sulfuric acid suspension electrolysis solution can be oxidized obviously and has better oxidation rate.

确定了硫化锌矿悬浮电解时的电解液后，我们又对硫化锌矿在悬浮电解过程氧化特征即矿物氧化时其中各元素的氧化溶出情况进行分析，对阳极氧化进行了动力学研究，对氧化渣进行XRD和SEM分析，以了解其含锌矿物在悬浮电解过程中的氧化规律，还进行了渣中元素硫的回收。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。