查询词典 electrode potential

The aqueous phase containing a redox couple is supported on the surface of platinum electrode, then the electrode is inverted and immersed into the organic phase along with reference and counter electrode to construct a classical three-electrode system.

将含有氧化还原电对的水相支撑在铂盘电极表面，倒置后插入到有机相中，与参比电极和对电极构成常规的三电极系统，实现了液/液界面上的电荷转移反应。

The main research work of this dissertation is as follows: Based on the chemical reaction engineering theory and the nitrobenzene electroreduction mechanism, the plate and frame electrolyzer was designed and applied to the process of electroreduction nitrobenzene to p-aminophenol. This dissertation measured the residence time distribution data of the electrolyzer by means of the pulse response method and studied the rule of flow pattern along with the current capacity change. Under different conditions ,this dissertation studied the cyclic voltammetry properties of nitrobenzene on different electrodes by means of the dynamic cyclic voltammetry method and the electrode materials applied to the NB electroreduction have been selected primarily.Baseed on the results of cyclic voltammetry tests, this dissertation used p-electrode systems to measure the steady-state- polarization curves of nitrobenzene on different electrodes in H-type diaphragm cell, and obtained each primary factor s influence rule and the exchange current density value of each electrode.And then on the basis of the conclusions of fundamental researchs upword, the effects of influence factors on the the yield of p-aminophenol and the current efficiency,such as electrode material, current density, quantity of electricity circulated, nitrobenzene concentration . sulpuric acid concentration and so on, have been studied in detail in the systems of hign temperature , strong acidity and oxygen-poorthrough a series of electrolysis experiments in this paper.After all using Pb as anode Monel metal as cathode Dupont Nafion 417 cation-exchange membrane as membrane, this dissertation obtained the optimum technological condition: reaction temperature about 85C, current density 500A m-2, sulphuric acid concentration 20%wt.

论文的主要研究工作为：运用化学反应工程理论，结合硝基苯的电还原机理，设计出用于硝基苯直接电还原合成对氨基苯酚实验的板框式电解槽，并利用脉冲响应法测定了该板框式电解槽的停留时间分布数据，研究了流型随流量变化的规律；通过动态循环伏安法研究了硝基苯在不同电极上、不同条件下的循环伏安特性，初步评选出了用于硝基苯电还原的电极材料；结合循环伏安的测定结果，在H型隔膜电解槽中采用三电极体系测定了硝基苯在不同电极上、不同条件下的稳态极化曲线，得到了各主要因素的影响规律及硝基苯在各个电极上电还原的交换电流密度数值；在基础研究结论指导下，采用板框式电解槽，在高温、强酸、贫氧系统中，进行了一系列的电解实验，分别考察了电极材料、电流密度、通电量、硝基苯浓度、硫酸浓度等因素对收率及电流效率的影响，最终选择以蒙乃尔合金电极作为阴极、铅合金为阳极、Dupont Nofion 417阳离子交换膜为隔膜，得到由硝基苯直接电还原制对氨基苯酚的最佳电解工艺条件：反应温度85℃，电流密度500A·m~(-2)，硫酸浓度20％wt。

1 A mediator modified carbon glassy electrode (NMP-GC electrode) is made by immobilizing N-methyl phenazine sulfate as the mediator on the surfase of carbon glassy electrode, which successfully catalyzes the oxidation of NADH and reduce the over-potential of NADH almost 700mv.

采用N-甲基吩嗪硫酸酯作为氧化还原介体，制作了NMP修饰的玻碳电极，将该电极用于NADH的电催化，实现了NADH在NMP-GC上的可逆氧化还原，并且将NADH在电极上的过电位降低了700mv左右。

At an electrode potential of +0.87 V, the electrode surface was rich of acicular Sn and stannum oxide. This film would prevent the electrode from dezincification, and the current density decreased and homeostasis was reached at the same time. The corrosion mechanism of brass welded line in artificial seawater was dissolution/redeposition.

随后，电极表面积累的锡和锡的氧化物及腐蚀产物层对脱锌腐蚀有一定的阻碍作用，电流密度有所下降，最后腐蚀达到一种动态平衡，腐蚀机制为溶解－再沉积机理。

The silver paste material not only match with the car\'s defog shield heating line, PDP bus electrode, it also suit for those which printing electrode on the glass substrate such as VFD, hybrid multi-layers electrodes and fine line electrode. These material possess widely prospect and potential market.

本项目研制的银浆应用范围除轿车玻璃、PDP显示屏外，同样适用于VFD荧光显示屏等以玻璃基体为底材的电极制作，厚膜多层布线微细线印刷及光刻电子材料工业化应用等领域，应用前景很广阔，可以产生较大的经济效益和社会效益。

The silver paste material not only match with the cars defog shield heating line, PDP bus electrode, it also suit for those which printing electrode on the glass substrate such as VFD, hybrid multi-layers electrodes and fine line electrode. These material possess widely prospect and potential market.

本项目研制的银浆应用范围除轿车玻璃、PDP显示屏外，同样适用于VFD荧光显示屏等以玻璃基体为底材的电极制作，厚膜多层布线微细线印刷及光刻电子材料工业化应用等领域，应用前景很广阔，可以产生较大的经济效益和社会效益。

The iron array electrode covered with concrete as a new electrochemical technique is applied to map the potential imaging and to investigate on the iron electrode corrosion process under concrete: In Cl- solution the corrosion of the iron array electrode covered with concrete had been prevented for a short term since the concrete protection, but the corrosion still occurreed and developed after immersed for a long time.

由于混凝土的隔离和高绝缘性，常规的电化学技术、微探针扫描技术均难于获得在腐蚀介质的浸泡下混凝土/钢筋界面，特别是不同深处的混凝土/钢筋界面的电位分布。本文提出用阵列电极法并结合电子技术和微机控制技术，获得同一水平面上混凝土/钢筋界面以及不同深处的混凝土/钢筋界面的电位分布立体信息图。

In order to prove the importance of three-body interaction, accurate ArH〓 potential surface and accurate ArAr potential surface are added to construct a two-body potential surface. We found that this potential surface is corresponding with a deep potential well and a tight structure, which is far from the real structure of Ar〓H〓. Obviously, this two-body additive potential surface is not suit in this system.

为了证明三体作用在体系中的重要性，我们用精确的ArH〓的势能面与精确的ArAr的势能面构造了一个两体加和的势能面，发现两体加和的势能面表现的是一个深势阱的紧凑结构，与Ar〓H〓的结构相去甚远，因此可以确认，两体加和在此系统中是不适用的。

Is better than that of using Na〓S merely and the profit per year is over 6, 000, 000 yuan. External potential-control flotation column and The Cu-Mo bulk concentrates flotation separation. With appropriate combination of the principle of sulphide flotation pulp electrochemistry and the technology of flotation column show the advantage over flotation equipment, External potential-control flotation column was studied successfully, laboratory potential-control flotation column was designed and its structural principle, the relationship of electrode structure and the activity of separation, the electrochemistry principle of potential-control flotation column also was investigated.

用具有较强电化学还原能力的无机物（如硫化钠、连二亚硫酸盐等）与能和硫化铜矿物表面发生选择性吸附的小分子有机化合物组合使用、成功地实现了混合精矿体系中黄铜矿的抑制、解决了德兴铜矿铜钼混合精矿浮选分离时、硫化钠用量大、生产成本高，生产指标不稳定的技术难题，研究结果表明，用组合抑制剂3.8kg/t可取代生产中硫化钠45kg/t的高用量，并获得优于单用硫化钠的好指标，年直接经济效益600万元以上。

A novel design of reference electrode was developed to in-situ measure the polarization of direct methanal fuel cell.The effect of humidification conditions of electrolyte on the reference electrode potential and its potential stability was investigated.

提出了用于原位测量直接甲醇燃料电池极化的参比电极的结构设计，并考察了电解质的润湿程度对参比电极的电位及其电位稳定性的影响。

Liapunov—Schmidt method is one of the most important method in the bifurcation theory.

Liapunov—Schmidt方法是分叉理论的最重要方法之一。

Be courteous -- even when people are most discourteous to you .

要有礼貌──即使当別人对你最不礼貌的时候。