查询词典 electrode potential

Comparing it with the standard electrode potential of nitric acid,the reason of dissolution of HgS in aqua regia was quantitatively revealed,and this is that the high concentration of chloride ions reduces the reduction potential of sulfur in HgS,thus raising the reducing power of HgS rather than that the oxidizing power.

根据热力学平衡原理和设计的可逆电池反应，由 E~0Hg~(2++S/HgS数据，计算了 E~0HgCl_4~(2++S/HgS+4Cl~-数值，将其与 HNO_3的标准电极电位比较，定量地揭示了 HgS 溶于王水的原因在于该溶液中高浓度 Cl~-离子降低了 HgS 中硫的还原电位，从而提高了 HgS 的还原性所致，并非王水的氧化性比 HNO_3的更强。

A novel design of reference electrode was developed to in-situ measure the polarization of direct methanal fuel cell.The effect of humidification conditions of electrolyte on the reference electrode potential and its potential stability was investigated.

提出了用于原位测量直接甲醇燃料电池极化的参比电极的结构设计，并考察了电解质的润湿程度对参比电极的电位及其电位稳定性的影响。

By controlling the potential of the electrolyte solutions,this technique can be employed in studies formation of DNA strand breaks.CT-DNA was cleaved by adding amounts of CuL or NiL complex in the absence of chemical reagent when appropriate electrode potential(sufficiently negative or positive to reduce or oxidate metal ions) was applied.

根据获得的实验结果，CuL或NiL存在下，电解溶液的电位合适时(足够负或足够正的电位，保证金属离子的还原或氧化)，不需要加入额外的氧化剂或还原剂，同样可以切割小牛胸腺DNA，CuL劈裂能力强于NiL配合物。

At an electrode potential of +0.87 V, the electrode surface was rich of acicular Sn and stannum oxide. This film would prevent the electrode from dezincification, and the current density decreased and homeostasis was reached at the same time. The corrosion mechanism of brass welded line in artificial seawater was dissolution/redeposition.

随后，电极表面积累的锡和锡的氧化物及腐蚀产物层对脱锌腐蚀有一定的阻碍作用，电流密度有所下降，最后腐蚀达到一种动态平衡，腐蚀机制为溶解－再沉积机理。

The current density peak of brass welded line appeared at -0.012 V, and a porous corrosion film was formed. The electrode was passivated subsequently. The passivation film was made up of Cu2O, CuCl and ZnO. The passivation film dissolved with electrode potential, and displacement deposition took place between Cu and Zn. The copper redeposition on the electrode surface induced the increase of electrode activity and corrosion rate.

黄铜焊缝在电位-0.012V时出现电流峰，腐蚀产物膜多孔、疏松，随后电极进入钝化区，钝化膜由Cu2O、CuCl和ZnO组成；随电位升高，钝化膜溶解，发生铜锌置换反应，沉积的Cu导致活性电对的形成，增加了合金的腐蚀速度；当电位为+0.87V时，电极表面富集了针状锡和锡的氧化物。

In this paper,the electrochemical reduction of CO2 by various metal electrodes in aqueous solution,organic solvent and molten salt media is reviewed,which includes reaction activity and mechanism of every kind of metal electrodes. The effect of electrode,temperature,pressure,electrode potential and electrolyte on the selective and Faradaic e...

综述了金属电极在水溶液、有机溶剂以及熔融体中电还原CO2的研究现况，包括各类金属在电还原CO2过程中所表现出的反应活性以及生成相应产物的反应机理；介绍了电极、温度、压力、电极电位和电解质等因素对金属电极电还原选择性及法拉第电流效率的影响；展望了CO2电还原的未来研究方向及应用前景。

The hydrophobic adsorption film gradually grows and passivates on jamesonite from -78 mV to 42 2 mV.The electrode process of jamesonite at 522 mV is quite controlled by the reaction that is depended on ion diffusion.When the electrode potential is over 622 mV,the hydrophilicity on jamesonite becomes strong due to covering an amount of PbSO4 from the electrochemical reactions.

当电极电位为-78 mV～422 mV，矿物表面疏水性膜逐渐增长并产生钝化作用；当电极电位为522 mV时，电极过程完全由离子扩散决定的电化学反应所控制；当电位大于622 mV后，电极反应产生大量的PbSO4沉淀，并覆盖在电极表面，矿物表面的亲水性强。

Experiment shows that for coated wire calcium ion-selective electrodes with copper matrix,there is a linear dependence of the electrode potential on logarithm calcium ion activities over a range of 10'(-1)-2x10~(-5) mol/L,the limit of detection is 8x10~(-6) mol/L,the electrode pote...

结果表明，铜基涂丝钙离子选择电极线性范围为10~(-1)-2×10~(-5) mol/LCa~(2+)，检测极限达8×10~(-6) mol/L，斜率为30±2mV，适用 pH 范围为4。 5-11。 0，响应时间少于15s，内阻低，选择性和稳定性好，使用寿命一般为三个月左右，并成功的用于水质分析及钙离子的有关络合物稳定常数的测定。

Measured positive and negative electrode potential must rely on the reference electrode, to determine its relative value.

前言 Foreword 测量正、负极电极电位要借助参比电极，来确定其相对值。

In this situation,the electrode potential at equilibrium(i.e,when the rate of the anodic reaction equals the rate of the cathodic reaction) will be shifted from the standard electrode potential and can be defined by the Nernst equation:(5)where E0 is the standard electrode potnetial ,RT/F is a constant,n is the number of electrons transferred ,and a is the activity of the anodic and cathodic reactants.

在这个情况，电极电位在平衡(即，当正极反应的率合计负极反应的率)从标准电极电位将被转移，并且可以由能斯脱等式定义：(5) E0是标准电极potnetial的地方， RT/F是常数， n是转移的电子的数量，并且a是正极和负极反应剂的活动。

The absorption and distribution of chromium were studied in ryeusing nutrient culture technique and pot experiment.

采用不同浓度K2CrO4(0，0.4，0.8和1.2 mmol/L)的Hoagland营养液处理黑麦幼苗，测定铬在黑麦体内的亚细胞分布、铬化学形态及不同部位的积累。

By analyzing theory foundation of mathematical morphology in the digital image processing, researching morphology arithmetic of the binary Image, discussing two basic forms for the least structure element: dilation and erosion.

通过分析数学形态学在图像中的理论基础，研究二值图像的形态分析算法，探讨最小结构元素的两种基本形态：膨胀和腐蚀；分析了数学形态学复杂算法的基本原理，把数学形态学的部分并行处理理念引入到家实际应用中。