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New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene Polymerization Facile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that: 1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下:(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2,3-双(2,6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2,6-二[1-(2,4,6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上,研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响,研究表明: 1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理,可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体; 2、BET,XRD,IR,SEM,GPC和DSC研究表明,脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

Occurrence of tectonic heat event on late-Mesozoic in Ordos basin result from intensive thermal mobility of deep lithosphere on the late-Mesozoic,Thermal mobility of deep lithosphere in sourth region is stronger than in north region. Mantle occur underplating and thickness of lithosphere reduce, magma invasion and eruption occur on late-Mesozoic. Ordos basin be in weak extension environment on late-Mesozoic.

鄂尔多斯盆地中生代晚期构造热事件发生的根本原因在于中生代晚期岩石圈深部的热活动增强,盆地南部岩石圈深部热活动性更强,早白垩世鄂尔多斯盆地处于一种弱拉张的构造环境,地幔发生底侵作用,岩石圈减薄,发生岩浆侵入和喷发。

The goal of this thesis is to develop a suit of Forecasting and Early-Warning software system for potato"s Late Blight that can forecast the occurrence time and the trend of potato"s Late Blight so that it can reduce the loss caused by Late Blight to a maximal extent.

本论文的研究目的是建立马铃薯晚疫病的预测预警系统来指导人们对马铃薯晚疫病的感染、发生时间及流行程度、灾变时间进行预测预警,以尽量减少马铃薯晚疫病所带来的损失。

The temperature of basin was influenced greatly by matle heat conduction, magmatic heat and radioelement decay during the time of Early Permian-Late Permian rifting, while in the down-warped basin from the late stage of Late Permian to the present the temperature has been greatly affected by geothermal gradient and tectogenetic transition heat.

认为早二叠世-晚二叠世早期裂谷作用阶段盆地温度主要受地幔热传导、岩浆体热和放射性元素衰变的影响,晚二叠世晚期至今坳陷盆地阶段主要受地热增温率和构造运动转化热的影响。

Of the five stages deformation, the exact ages of the (2) and (3) were determined by 40Ar/39Ar method as 290 and 259 Ma respectively.2. New results on the metamorphic belts and associated metamorphism of the Xiaopu metamorphic rocksBased on detailed microtextural observations and occurrence of typical metamorphic minerals, five metamorphic belts in the Xiaopu metamorphic rocks are identified. From the north to the south, they are biotite belt, garnet belt, staurolite belt, andalusite belt, and sillimanite belt. I suggested that the metamorphic belts occurred in the Xiaopu area belongs to the high temperature/low pressure series, may have resulted from the later Permian crust extension at ca. 290 Ma.3. I suggest that there may have been a Carboniferous backarc basin along the southern slope of the Harlik Mountain.Detrital Zircon SHRIMP U-Pb dating indicated that the sedimentary age of the Julideneng formation lithic sandstone must be later than late Devonian, most likely is Carboniferous rather than previously thought Precambrian. Analyses on its geologic setting, location of provenance, and sedimentary environment suggest the Carboniferous strata may form in a lagged backarc basin bounded by backarc uplifts.5. Reconstruction of the post-Paleozoic tectonic evolution history of the Harlik MountainThe tectonic evolution of Harlik mountains since the Paleozoic were reconstructed as followings:(1) arc-affinity magmative activities occurred during the middle-Ordovician to early-Silurian;(2) the middle-Silurian to late-Devonian was a back-arc uplift stage;(3) back-arc extension featured the Carboniferous period;(4) post-collisional extension and/then compression during Permian;(5) at the Mesozoic, differential uplift developed; and (6) the late Cenozoic is the intra-continental re-orogen stage.6. Primary estimation of the crust shortening is madeThe folded pre-Mesozoic strata were used to estimate crust shortening along the Harliknanshankou-Koumenzi, Shichengzi-Baishitou, and Qincheng-Xiaopu sections. Their shortening ratios are 16.2%, 19.8%, and 20.1% respectively corresponding crust shortening are 4.3, 9, and 11.3 km.

根据Ar-Ar热年代学研究,精确测定了早二叠世伸展变形和晚二叠世挤压变形的峰期时代分别为290Ma和259Ma.2、提出了关于哈尔里克山南麓小铺一带变质带和变质作用的新认识根据显微观察资料和特征变质矿物的出现,把小铺一带的变质岩由SW向NE方向依次划分为黑云母带、石榴石带、十字石带、红柱石带和矽线石带等变质带;初步确定该区的变质作用属于中温-低压型,变质作用发生的时代为290Ma左右,是该区早二叠世地壳伸展的产物。3、首次提出哈尔里克山南麓在石炭纪可能发育弧后盆地的新观点根据哈尔里克山南麓原"居里得能组"岩屑砂岩的碎屑锆石SHRIMP U-Pb定年,确认这套地层的沉积不早于晚泥盆世,很可能是石炭纪,而不是前人所说的前寒武纪;结合对其区域地质背景、源区位置和沉积环境分析,推测该区石炭纪可能为滞后弧后盆地和弧后隆起区构造背景。4、进一步证明哈尔里克山不发育与岛弧演化相关的泥盆纪岩浆活动根据对代表性闪长岩和花岗岩的锆石SHRIMP年代学研究获得的新资料,结合该区已有相关资料的综合研究,确定哈尔里克山岩浆岩分别形成于奥陶纪-志留纪和石炭纪晚期-二叠纪,不存在泥盆纪的岩浆岩,进而认为该区泥盆纪不属于岛弧环境。5、重建了哈尔里克山古生代以来的地质演化过程根据区域资料以及本次研究所获得的资料,把哈尔里克山古生代以来的构造演化划分中奥陶世-早志留世为岛弧、中志留世-晚泥盆世为弧后区、石炭纪弧后伸展、二叠纪为后碰撞伸展与挤压、中生代差异隆升和晚新生代陆内再造山过程等构造阶段。6、初步估算了哈尔里克山地壳缩短率和缩短量根据前中生代地层褶皱估算的哈尔里克山南山口-口门子、石城子-白石头和沁城-小铺三条剖面的地壳缩短率分别为16.2%、19.8%和20.1%,相应的地壳缩短量分别为4.3km、9km和11.3km。

Studies show that regional granitoid of late Triassic, late Jurassic, middle period of early Cretaceous and late period of e arly Cretaceous were formed successively in different stages of interactions of the Yangtze Plate, the North China Craton and the Pacific plate.

研究认为,胶东地区晚三叠世(230~200Ma)、晚侏罗世(160~140Ma)、早白垩世中期(130~125Ma)、早白垩世晚期(120~100Ma)花岗质岩石可以与扬子板块、华北板块、太平洋板块相互作用的不同阶段相对应。

Sixteen ( 15 new) amphibian and twenty-two ( 11 new) squamate species have been reported across China, including the oldest Chinese tetrapod Sinostega pani from the Late Devonian of Ningxia Hui Autonomous Region, the large stereospondyl amphibian Yuanansuchus laticeps from the Middle Triassic of Hubei Province, Late Jurassic/Early Cretaceous lissamphibians ( e. G., the anurans Callobatrachus sanyanensis and Mesophryne beipiaoensis, the caudates Jeholotriton paradoxus and Laccotriton subsolanus) from Northeast China, Paleogene lizards (e. G., Brevidensilacerta xichuanensis and Tinosaurus yuanquensis) from North China, and numerous lizards from the Late Cretaceous of Nei Mongol Autonomous Region.

共报道了16种两栖类和22种有鳞类,其中15种两栖类和11种有鳞类为新种,包括我国最古老的四足动物宁夏晚泥盆世的潘氏中国螈,湖北中三叠世的大型全椎两栖类宽头远安鲵,东北晚侏罗世/早白垩世的多种滑体两栖类(如无尾类三燕丽蟾和北票中蟾,有尾类奇异热河螈和东方塘螈),华北古近纪的蜥蜴类(如淅川短齿蜥和垣曲响蜥),以及内蒙古晚白垩世的多种蜥蜴类等。

Through the age analysis on apatite and zircon fission track, there have five stages of tectonic movements, respectively occurred in late Trias, from mid-late period in early Cretaceous to late Cretaceous, Eocene, Oligocene and Miocene.

通过对盆地内磷灰石和锆石年龄分析,焉耆盆地存在5期构造运动:晚三叠世、早白垩世中晚期-晚白垩世、始新世、渐新世和中新世。

The late Triassic strata unconformably overlying the granite indicates that the formation time of these thrust structures might be from the late Permian to the early Triassic, no later than the Late Triassic.

西北缘晚三叠世地层不整合覆盖于花岗岩之上,这种现象将本区冲断构造发生的时间限定为晚二叠世至早三叠世,最晚不超过晚三叠世。

Based on the regional tectonic evolution, combined with the high precision isotopic ages from this paper and other geologists, we have some new acquaintances as follows: 1 There has no Caledonian granite belt distributed in north margin of North China Craton. So, the traditional evolving model of North China Carton, which formed on this idea and the acquaintance about the collision of North China plate and Siberian plate, must be incorrect; 2 The age date show that the earliest magmatic activity began since late-Palaeozoic Permian, which is inconsistent with the previous idea that there were Caledonian and Hercynian active continental margin in the north of North China Craton and in the south Xingkai Massif. 3 the crust and lithosphere were thickened by the subduction and collision of Siberia plate and North China plate during Late Paleozoic. The magma is formed when the crust is heated and melts caused by thickened lithosphere delamination and caused the Asthenosphere upwelling. But only a little basaltic magma erupted, most magma underplate under the bottom of the crust. Thermal energy derived from basaltic magma underplating made the middle and lower crust melt partially and the late Permian-early Triassic granites is formed in large scale.

根据区域构造演化分析,并结合本文及他人高精度同位素年龄,我们对延边花岗岩形成的大地构造环境有了新的认识:1在华北地台北缘并不存在所谓的加里东花岗岩带,因此,建立在此之上的传统的华北地台北缘演化模式及有关西伯利亚板块与华北板块的碰撞拼合的认识也必然是不正确的;2华北地台北缘和兴凯地块南缘不存在加里东期和海西期花岗岩带,表明两地块边缘最早的花岗质岩浆活动始于晚古生代的二叠纪,即不存在传统观点所认为的加里东期或海西期活动陆缘;3晚古生代由于西伯利亚板块与华北板块的俯冲碰撞,致使地壳和岩石圈增厚,导致加厚岩石圈发生拆沉作用,使得软流圈上涌,加热地壳使之熔融形成岩浆,但玄武质岩浆少量喷出地表,大部分底侵于地壳底部,形成下地壳高密度的玄武质底侵层,玄武质岩浆底侵的热能引起中下地壳广泛部分熔融,形成大面积分布的晚二叠世—早三叠世花岗岩。

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