查询词典 distillation

Based on the success of the industrialization of the process of catalytic distillation of methyl acetate hydrolysis, the new process of catalytic distillation of methyl acetate and methanol azeotrope hydrolysis and related fundamental research were studied. These can make further improvement on the process in order to simplify the process and reduce the energy-consumed of the recovery system. In addition, theoretical system of the simulation and design the catalytic distillation process were established, which can provide the basis of the pilot plant and industrialization in the future.

本文在催化精馏水解工艺工业化成功的基础上，进行了醋酸甲酯和甲醇共沸物催化精馏水解新工艺及其相关基础研究，以进一步改进工艺，达到简化流程及节能降耗的目的，同时建立起催化精馏过程模拟和设计的理论体系，为中试及将来的工业化打下了坚实的基础。

Batch extractive distillation is used to separate azeotrope or the mixture of which the relative volatility is close to 1.0. For it has both advantages of batch distillation and extractive distillation, batch extractive distillation is becoming increasingly important to the production of small scale and high value products like fine chemicals and pharmaceuticals.

间歇萃取精馏是分离共沸物或近沸物的一种方法，由于它结合了间歇和萃取的优点，特别适用于化工、制药、溶剂回收、天然产物提取等产量小，品种多的行业，因此间歇萃取精馏近年来已成为非常活跃的研究和开发领域。

Such factors as distillation temperature and distillation pressure, etc. which affect the process of preparing citral from Litsea cubeba oil and of preparing cinnamaldehyde from cassia oil by molecular distillation were investigated under rotation of 370～390 r/min,flow rate of 1drop/s,and temperature of cooling water 4～5℃.

利用分子蒸馏新技术从天然香料肉桂油和山苍子油中分离提纯肉桂醛和柠檬醛，用GC–MS联用仪对分离物中肉桂醛和柠檬醛的质量分数进行分析，重点研究了压力和温度等主要影响因素。

The following points are emphasized:The operation models of adiabatic and diabatic distillation have been set up and the operation block, thermodynamics model and mathematical model in the simulation have been determined as well;(2)Based on the simulation and exergy analysis with Aspen Plus program, shortcut distillation design—DSTWU model and rigorous distillation design—RADFRAC model, the author has determined the heat duty, exergy losses and the distribution of exergy losses along the adiabatic column, which will help the simulation and optimization of the diabatic distillation;(3)Diabatic distillation under various operation conditions has been simulated by using energy balance method and exergy analysis;(4)How the different mixture and the various degree of separation, number of trays and feed location influence exergy saving in diabatic distillation have also been discussed;(5)On the basis of the total exergy losses along the column, different schema of the heat transfer distribution along the column have been compared and analyzed;they can be classified in three categories: heat duty equipartition approach, empirical approach, separation degree matching approach. In conclusion, different heat transfer distribution along the column will have effect on total exergy losses. In particular, most satisfactory results have been obtained by using separation degree matching approach. In order to diminish the exergy losses, heat transfer distribution should meet the needs of the request of separation degree.And on this premise, the author makes his suggestion in increasing the proportion of heat supplied to the tray with minimum exergy losses and decreasing the proportion of heat supplied to the tray with the maximum exergy losses.

本文对透热精馏过程进行了模拟并对其节能效果的影响因素做了较为全面的分析和深入的研究，主要研究内容如下：(1)建立了常规精馏和透热精馏过程的模拟操作模块、热力学模型以及数学模型；(2)利用化工模拟软件Aspen Plus并分别采用DSTWU简捷模型和RADFRAC严格计算模型对常规精馏进行模拟计算和有效能分析，确定常规精馏塔的公用工程热负荷、有效能损失及有效能损失在塔内的分布，为透热精馏的模拟和优化提供数据参考；(3)对不同物系在不同分离度条件下进行透热精馏的模拟，分别采用能量衡算法和有效能分析法进行计算和分析；(4)探讨了各种因素如物系的选择、不同分离度、塔板数、进料位置对透热精馏节能效果的影响；(5)以全塔总有效能损失为比较基准，对热量在塔内的三种分布方案即热负荷平均分配法、经验法和分离度匹配法进行了对比分析并得出结论：塔内热量的不同分布方案对于全塔总有效能损失会产生影响，其中以分离度匹配法的节能效果最为理想，为减少有效能的损失，应使塔内的热量分布满足各塔板的分离度要求，并在此前提下，尽量减小有效能损失大的塔板的热负荷和增加有效能损失小的塔板的热负荷。

At present, on-line analyzer of distillation range normally use theory of RTP distillation that only can analyze a point or discontinuity of distillation range.

但由于高温操作、微量进样、信号微弱等特点，将色谱模拟蒸馏方法在线化的色谱模拟蒸馏在线分析仪，在国外还处于起步阶段，而在国内则属空白。

The pressure swing distillation is an effective separation of binary azeotropic mixtures, and it has the advantages of simplicity, low energy and low cost.

而变压蒸馏分离系统(Pressure Swing Distillation，PSD)是一种可以有效的分离二元共沸混合物的技术，且具有简易性、低耗能及低成本花费等优点[1]。

TEM shows that drying by direct heating might result in hard aggregation of the tourmaline powder, while hard aggregation might be avoided by azeotropic distillation. Raman spectroscopy reveals that there are O_H and C_H on the surfaces of the tourmaline powder obtained by azeotropic distillation, which indicates that butoxy is chemically adsorbed on the surfaces of tourmaline particles, but not adsorbed on those formed by direct drying. X_ray powder diffraction shows that the intensity of diffraction peaks decreases after grinding. There is no damage to the tourmaline crystal lattice in the process of direct heating, azeotropic distillation, or ultrafine grinding.

透射电镜分析结果表明，直接加热脱去水或正丁醇会使电气石超细颗粒发生硬团聚，而共沸蒸馏法则可有效防止硬团聚的产生；拉曼光谱结果表明，共沸蒸馏法制备的电气石粉末表面存在O—H和C—H键，说明正丁醇在颗粒表面为化学吸附，而直接干燥法得到的电气石粉末表面则没有；X射线粉晶衍射结果表明，研磨过程降低了粉末衍射峰的强度，但直接加热干燥和共沸蒸馏干燥均未破坏电气石的晶格结构。

The presumption that new technology about distillation column with a single reactor can be used in photochlorination of acetic acid is first proposed in this paper. The fact that reaction distillation has obvious advantages in the number of theoretically perfect trays and energy consumption was obtained by theoretical analysis between the coupling of reaction and distillation and the independent operation, which lays a theoretical foundation on the application of the distillation column with a single reactor in photochlorination of acetic acid.

本文首次提出了将背包式反应精馏耦合技术应用于乙酸氯化反应的设想，通过对反应精馏耦合和反应精馏独立操作两种情况进行理论分析，发现反应精馏耦合在理论板数、能耗方面均具有明显优势，因而为背包式反应精馏应用于乙酸光氯化反应奠定了理论基础。

Experiment have proved that the glycerol of hazen≤100can be reˉclaimed via ion exchange and chemistry disposal of glycerol distilled residue ;high quality glycerol and polyglycerol can be gained by Short-path distillation.

实验证明，甘油蒸馏残渣经过化学处理除杂后，通过离子交换，可以回收得到色泽100以下的甘油质；采用短程蒸馏(Short-path distillation)技术，可以得到高质量的甘油和聚合甘油。

On the basis of summarizing separation method of acetic acid-water system, we studied the azeotropic distillation process of acetic acid-water system, selecting butyl acetate, isobutyl acetate and isopropyl acetate as entrainers. The influence of packing height, ratio of water to entrainer and acetic acid initial concentration to separation effect of azeotropic distillation was studied in detail. Simulation calculations of general distillation and azeotropic distillation were carried out. The influence of reflux ratio, theoretical plate, feed position, feed temperature and feed concentration to distillation process were discussed. Preferred process operation parameter, which had guiding meaning to practical production of distillation process were obtained. Basic data for the process amplifying design of azeotropic distillation tower were provided. Invest and operation energy consumption of two distillation methods were compared. The elementary technical design of azeotropic distillation tower was carried out on the basis of result of simulation calculation. The type of major auxiliary equipments and inner parts of packed tower were selected.The research results are as follows:(1) Butyl acetate, isobutyl acetate and isopropyl acetate could be selected as entrainer, and separation effect was near.

本文在综述醋酸-水体系分离方法的基础上，以醋酸丁酯、醋酸异丁酯、醋酸异丙酯为挟带剂，对醋酸水溶液进行共沸精馏过程研究，详细研究了填料高度、水与挟带剂的配比、醋酸初始浓度等对共沸精馏分离效果的影响；对醋酸-水体系进行普通精馏和共沸精馏过程模拟计算，讨论了回流比、理论板、进料位置、进料温度和浓度对精馏过程的影响，获得了对醋酸-水体系精馏过程实际生产具有指导意义的较佳的工艺操作参数、共沸精馏塔的工艺设计放大的基础数据，并对两种精馏方法的投资、操作能耗进行了比较；同时在共沸精馏模拟计算的基础上进行了共沸精馏塔的初步工艺设计计算，并对填料塔的主要辅助设备及塔内件进行了初步选型。

The absorption and distribution of chromium were studied in ryeusing nutrient culture technique and pot experiment.

采用不同浓度K2CrO4(0，0.4，0.8和1.2 mmol/L)的Hoagland营养液处理黑麦幼苗，测定铬在黑麦体内的亚细胞分布、铬化学形态及不同部位的积累。

By analyzing theory foundation of mathematical morphology in the digital image processing, researching morphology arithmetic of the binary Image, discussing two basic forms for the least structure element: dilation and erosion.

通过分析数学形态学在图像中的理论基础，研究二值图像的形态分析算法，探讨最小结构元素的两种基本形态：膨胀和腐蚀；分析了数学形态学复杂算法的基本原理，把数学形态学的部分并行处理理念引入到家实际应用中。