查询词典 diffraction

Pristine Li-Al LDHs are synthesized by hydrothermal process in different reaction conditions by varying the aging time for 1 and 24 hours. Both the Li-Al layered double hydroxides (abbreviated as Li-Al LDH1 and Li-Al LDH24 for aging time 1 hour and 24 hours, respectively) were modified by using sulphanilic acid sodium salt hydrate, modified agent to form modified Li-Al LDH1-SAS and Li-Al LDH24-SAS. The morphology of the pristine layered double hydroxides are investigated by using wide angle X-rays diffraction, scanning electron microscopy and particle size analyzer which indicates that the crystallinity and aspect ratio is increased with increasing the aging time from 1 hour to 24 hours. The particle size of Li-Al LDH24 and Li-Al LDH1 are found to be ~1000 nm and ~250 nm, respectively. Both the pristine and modified LDHs are characterized by XRD, FTIR spectra and thermogravimetric analysis.

本研究目的在於改变长晶时间的长短，合成出同径大小的Li-Al LDHs，再经由改质剂sulphanilic acid sodium salt hydrate将Li-Al LDHs无机层材表面有机官能化制备出改质型Li-Al LDHs-SAS，於是进一步藉由扫描式电子显微镜、射径仪和穿透式电子显微镜等仪器分别观察LDHs改质前和改质后其主层结构型态上的变化；从中可以发现Li-Al LDHs随著长晶时间的增加其径有随之增大的趋势，但经有机化改质后其径会由於改质环境的影响明显低许多，针对此现象本实验将未改质和改质后之Li-Al人工无机层材制备成复材进一步探讨其在热性质和难燃特性上的为表现。

Infrared spectrum, X-ray diffraction, transmission electron microscopy and conductivity measurement were employed to investigate the properties and structure of polyaniline samples, which were synthesized by emulsion polymerization with different concentrations of ammonium peroxydisulfate and dodecyl-benzene sulphonic acid.

采用红外光谱、X射线衍射、透射电子显微术结合电导率测量，研究了以过硫酸钱为氧化剂，十二烷基苯磺酸为掺杂剂，通过乳液聚合法合成的聚苯胺的性能与结构。

This could be a fascinating method for the practical syntheses of chiral synthons as valuable building blocks and important medicinal intermediates.3.Series of novel optical pureγ-aryl-1H-1,2,4-triazole derivatives were designed and synthesized by using the chiral auxiliary(Oppolzer\'s sultam),and all these target compounds were structurally characterized by ~1H NMR,~(13)C NMR,MS and elemental analysis,at the same time,some representative compounds have been elucidated by X-ray diffraction analysis.

应用手性辅剂樟脑磺内酰胺的手性诱导作用，设计合成了一系列光学纯的γ-芳基-1H-1，2，4-三唑类衍生物，所有目标化合物都采用了~1H NMR、~(13)C NMR、MS和元素分析进行了结构表征，同时也获得了部分代表性化合物的晶体结构，进一步确证了化合物的结构。

X-ray single crystal diffraction study reveals that the Zn atom is five-coordinated, Furthermore, a 2D superamolecular network is constructed via the tetracarboxylate bridged binuclear of Zinc SBU ,and the amino substituent results in the formation of hydrophilic 2D structure of the title complex.

该配合物中，锌离子为5配位，2个Zn原子和4个羧基形成的双核锌结构单元，进而形成二维方格式平面结构，氨基取代基导致配合物具有亲水性。

Two organosulfonate complexes, [M22]·H2O (M=Cd 1, M=Pb 2), were obtained from the reaction of 1,10-phenanthroline, sodium 4-aminonaphthalene-1-sulfonate tetrahydrate and Cd2·2H2O or Pb (NO3)2 in a mixed solvent of water and methanol at 25 ℃. The compounds were characterized by elemental analysis, IR, and X-ray diffraction single crystal structure analyses.

合成了2个新型有机磺酸配合物，[Cd22]·H2O(1)和[Pb22]·H2O(2)(phen=1，10-邻菲咯啉，ans=4-氨基-1-萘磺酸根)，通过元素分析、红外光谱等对配合物进了表征，用X-射线单晶衍射方法测定了配合物的单晶结构。

1H-imidazolyl)-1H-imidazolium chloride-4-aminobenzoic acid, 2,2-bi-1H-imidazolium bis(3,4,5-trihydroxy benzoate) tetrahydrate and bis2-(2-1H-imidazolyl-1H-imidazolium 3-carboxy-4-hydroxybenzene-sulfonate monohydrate have been synthesized and characterized by X-ray diffraction methods.

在化合物中，晶体结构中的基本单元是一个通过氢键模式R_2~2(9)和R_2~1(7)构成的氢键三聚体PABA…H_3biim~+…Cl~-，这个三聚体基本单元又通过N-H…Cl氢键相互作用形成了一维带状结构。

These complexes are structurally identified by single-crystal X-ray diffraction to show a variety of metal nuclearity from mononuclear to tetranuclear and dimensionality from 1-D to 3-D.

单晶结构分析表明这些化合物具有多种金属核数（从1到4）以及多种结构维数。

All the ligands and complexes have been characterized with ~1H-NMR, MS and EA.X-Ray single crystal diffraction reveals that zirconium complex containing the tert-butyl substituted N_2O_2 ligand is an oxo- and hydroxyl-bridged dinuclear structure, which is possibly formed by partial hydrolysis of chlorides at one of the zirconium centers. A tetranuclear zirconium complex has been obtained and chacaterized, which is formed by complete hydrolysis of the chlorides at the zirconium centers.

通过研究配合物的单晶结构，我们发现叔丁基取代的不对称N_2O_2配体与ZrCl_4反应生成的锆配合物为氧桥和羟基桥连接的双核锆配合物，中间过程涉及单核锆配合物中氯原子部分水解，并得到氯原子部分水解的双核锆配合物和全部水(来源：8e6eAB67C论文网www.abclunwen.com)解的四核锆配合物的晶体结构，在晶体培养过程中发现双核锆配合物能够以手性自发拆分结晶析出。

Both were measured using X-ray single crystal diffraction. For the crystal in MeOH, X-ray in compound. In an ansymmetry unit, there are two Cu atoms, two ligands and twosolvent methanol molecules. The tetranuclear complex contains two kinds of Cucenter.

本文在MeOH中得到了阶梯型四核铜骨架配合物；在THF中得到了扭曲的立方烷型四核铜骨架配合物，经晶体结构分析表明，阶梯型四核铜骨架配合物是由两个Cu2被μ~3-剪刀撑二个醇羟基O所连接形成中心对称的二铜二聚体结构。

The tetravalence vanadium was found in V2O5 gel thin films by measuring the electrical resistance change of V2O5 gel thin films with temperature, ESCA and X-ray diffraction analysis. in this paper, from miniamount redox in melting V2O5 and crystal structure, the influencing mechanism of miniamount redox on changing valence of vanadium was analyzed and discussed in detail.

通过对V2O5凝胶薄膜试样的电阻随温度的变化测试和电子能谱和X射线衍射分析发现V2O5凝胶薄膜中有四价钒的存在，本文从V2O5熔体的微量氧化还原和晶体结构的角度分析讨论了微量氧化还原影响钒离子价态变化的机理。

Nowadays, most of research are to build a transmutative Petri Nets through adding controlling place sets, controlling arc sets and controlling policy to the basic Petri Nets, while the Controlled Petri Nets could be used to argue many controlling theory problems conveniently and to induce many logically and physically supervisory and solve the Event Feedback Controlling Problems and State Feedback Controlling Problem in DEDS supervisory theory.

目前大多数的研究表现为在变形后的受控Petri网基础上，利用各种方法求得各种逻辑型、结构型控制器，解决DEDS监控理论中的事件反馈控制问题与状态反馈控制问题。

On one hand, there are discussions with the works council and union about extension of short time working up to the end of September.

一方面，有讨论，工程理事会和联盟关于延长工作时间短至9月底。