查询词典 dichroism

In this research, the spider silk from the major ampullate gland of native Nephila pilipes was collected via the forced-silking apparatus at the reeling speed of 3 m/min. The obtained silk was dissolved in hexafluoro-isopropanol. The influence of pH and temperature over the secondary structure of the silk protein in solution state was examined via Circular Dichroism. The effect of silk concentration and electrical field strength on the structure conformation of silk protein during film casting process was investigated via FT-IR. During the drying process, the increase of silk concentration and the presence of electric field tend to form β-sheet and β-turn. Finally, the dried film of silk protein was treated with different temperatures and cation solutions to study the post-treatment effects.

本研究所采用之蜘蛛丝蛋白质系取自本土品种人面蜘蛛之大囊壶腺体，以3 m/min之卷丝速度强迫取丝(forced-silking)收集蜘蛛丝，再将纤维溶於六氟异丙醇溶剂中配制成溶液，以圆二色光谱仪分析在不同 pH 值与温度条件下丝蛋白质在溶液中之二级结构变化，再将蜘蛛丝溶液以不同浓度及电场强度下乾燥成薄膜后，以傅立叶红外线光谱仪检测分析丝蛋白质在固体状态下之二级结构，最后以不同温度加温、离子溶液浸泡等条件对乾燥所得之薄膜进行后处理，并分析其二级结构之变化。

Two different ways of sample tilt were used in CD messurements to prove that the linear dichroism and birefringance had no effect on CD signal of cholesteric helices of the liquid crystal.

分别用两种方法旋转玻片进行CD测试，结果证明线性二向色性分量和双折射分量对胆甾层片螺旋的CD信号强度没有大的影响。

Circular dichroism spectroscopy measurements also reveal that the ordered structure content of α-helical and β-structure of ovalbumin decrease, and the unfolded random structure is enhanced with increasing pressure; While the existence of dextran sulphate to the native ovalbumin, there are no apparent change on the secondary structure of ovalbumin; It seems same to glycinin.

圆二色性光谱分析表明，经超高压处理后，鸡蛋清蛋白分子中规则的二级结构减少，而部分规则的二级结构和无规卷曲含量增加。加入硫酸右旋糖苷的鸡蛋清蛋白溶液经超高压处理后其二级结构中各部分的含量变化不大：对于大豆豆球蛋白，加入硫酸右旋糖苷后，大豆豆球蛋白分子经超高压处理后其有序结构的减少及无规卷曲的增加都相对减缓。

In this dissertation, several recombinant unlabeled as well as 15N- or 15N/13C-labeled proteins were expressed and purified in large quantities. We then carried out circular dichroism and heteronuclear multidimensional NMR experiments to gain insight into the structure-function relationships on these proteins, as described below.

在本篇论文里，我们表现并纯化出大量所欲探讨的重组蛋白质，利用碳-13与氮-15同位素来标定这些重组蛋白，以旋光光谱及异核多维核磁共振技术来探讨这些蛋白质的结构与其功能的相关性，内容如下

Both three-dimensional chiral compounds have intriguing chiral channels, which are built up of homochiral intertwined double helices. The circular dichroism spectra of 1 and 2 in water have shown they are stable in solution, which document they will be significantly useful in asymmetric catalysis and chiral medicine.

以Keggin结构多金属氧酸盐为建筑单元，通过手性的铜-脯氨酸配合物作为模板剂构筑了2个基于Keggin结构多金属氧酸盐的3D纯手性化合物，化合物1和2是一对对映体，代表了世界上第一例3D手性多酸化合物，具有由同手性螺旋缠绕形成的手性孔道，水溶液中的圆二色谱表征这个3D手性化合物可稳定存在，显示这个物种可以在不对称催化及手性药物方面有潜在的巨大的应用价值。

We have investigated the conformational features of four short peptide fragments of Staphylococcal nuclease by homonuclear two-dimensional NMR and circular dichroism with a view to examining the early events in the folding process of SNase.

本论文工作用四个金黄色葡萄球菌核酸酶N-末端短片段作为新生肽链折叠的模型，用同核二维核磁共振谱和远紫外圆二色谱研究了它们的溶液构象特征。

We have investigated the conformational features of four short peptide fragments of Staphylococcal nuclease by homonuclear two-dimensional NMR and circular dichroism with a view to examining the early events in the folding process of SNase.

中文题名金黄色葡萄球菌核酸酶折叠起始位点：N-末端短肽段的NMR研究副题名外文题名 Folding initiation sites of staphylococcal nuclease：exploring the solution conformation of N-terminal fragments by nuclear magnetic resonance 论文作者戴继勋导师王金凤研究员学科专业分子生物学研究领域\研究方向学位级别博士学位授予单位中国科学院生物物理研究所学位授予日期2001 论文页码总数68页关键词金黄色葡萄球菌核酸酶蛋白质折叠核磁共振馆藏号BSLW /2001 /Q71 /89 本论文工作用四个金黄色葡萄球菌核酸酶N-末端短片段作为新生肽链折叠的模型，用同核二维核磁共振谱和远紫外圆二色谱研究了它们的溶液构象特征。

Heparin and DTT had not significant effect on circular dichroism of haFGF, impling no folding alteration of the peptide chain.

肝素和DTT对haFGF的圆二色谱没有明显的影响，说明它们并不改变haFGF的肽链折叠。

In this paper, asymmetric synthesis of oxidation reaction of achiral isophorone influenced by artificial centrifugal force field was studied. The reaction system was characterized by UV, Infrared and Circular dichroism.

摘要本文通过紫外、红外和圆二色光谱表征考察了外在离心力场对非手性化合物异佛尔酮不对称氧化生成光学活性产物的影响。

In this paper, asymmetric synthesis of oxidation reaction of achiral isophorone influenced by artificial centrifugal force field was studied. The reaction system was characterized by UV, Infrared and Circular dichroism.

本文通过紫外、红外和圆二色光谱表征考察了外在离心力场对非手性化合物异佛尔酮不对称氧化生成光学活性产物的影响。

In the days of sailing vessels the crew were afraid they would be becalmed on the ocean.

在使用帆船的时代，船员们担心他们会因为无风而无法在海洋上航行。

As long as foreign donors pay the PA's salary bill, few expect a new intifada.

只要外国继续为巴权力机构的薪水买单，希望发动新暴动的人便寥寥无几。