查询词典 cyano-ethylene

The results have indicated that the introduction of electron-donating methoxy or electron-withdrawing cyano-group at the 7-position of 3-phenylcoumarins caused a bathochromic shift for both absorption and fluorescence spectra. The phenyl group at the 4-position derivative has a hypsochromic shift for both absorption and fluorescence spectra.

结果发现，在3-苯基香豆素的7-位引入给电子基团甲氧基或吸电子基团氰基均使它们的吸收光谱和荧光光谱产生红移，4-苯基香豆素的衍生物的吸收光谱和荧光光谱均产生蓝移。3-苯基香豆素衍生物与4-苯基香豆素的衍生物的基态和激发态的电子转移方向相反。

The bay area has no substituent and has electron-withdrawing groups,such as bromine atom,cyano-group and 4-formyl phenoxy group compounds have strong absorption in 525 nm,when excitated them,they have strong yellow and salmon pink luminescence bettwen 538 and 566 nm.When introduce electron-donating substituents,such as phenoxy group,morpholinyl,piperidinyl and n-butylamino group,the absorption bathochromic shift while the electron-donating ability is improved,bettwen 536 and 692 nm have strong absorption,reach to the near-infrared region. When excitated them,only the phenoxy group compound has strong salmon pink luminescence in 572 nm,the others have no fluorescence.

其中，港湾位无取代的以及含吸电基团(—Br、—CN、对甲酰基苯氧基)化合物在525 nm左右处均有很强的吸收ε＞10~4M~(-1cm~(-1)，当光激发时，港湾位无取代、溴代和氰基取代物发出538～547 nm的强烈黄色荧光，对甲酰基苯氧基取代物则发出566 nm的强烈橙红色荧光；含供电基团(苯氧基、吗啉基、哌啶基、正丁氨基)化合物随着供电子能力的增强，吸收发生红移，在536～692 nm处均有很强的吸收ε＞10~4M~(-1cm~(-1)，达到了近红外区，当光激发时，只有苯氧基取代物发出572 nm的强烈橙红色荧光，而含氮供电基取代物均发生了荧光淬灭。

RCM reactions of 49 and 50 are chosen to evaluate the catalytic performance ofthe complexes 46-48 because they are informative and simple to manipulate. The resultsindicated that ruthenium benzylidene complexes 46 and 48 possess significant thermalstability and cyano group tolerance.

由于烯烃49、50的闭环交互置换反应简单、清晰，故用来考察新钌卡宾配合物的催化性能，结果表明配合物46、48具有良好的热稳定性及耐氰基性能。

They are derived from the condensation of salicylaldehyde with naphthalidine, 2-cyano-4-chloroaniline, o-Toluidine, N-aminoethylmorpholine, benylamine, butylamine, cyclopentylamine and 3-carboxysalicylidene with N-aminoethylmorpholine, benylamine, 2-hydroxyaminoethylamine, ethylenediamine, respectively.

得到了HL1、HL2和HL3配体的单晶；培养出了HL3～HL6、H2L11的Cu配合物，HL7～H2L11的Co配合物和H2L11的Ni配合物的单晶。此外，以5-溴水杨酸(5-bsa)、2-氨基苯甲酸(2-aba)、六次甲基四胺等为原料，合成了3种过渡金属Ag配合物，并培养出了其单晶。

The 6- cyano-1, 1 (1, 3- dioxypropylidene)-7-(carbomethoxyl group- methyl - 5- oxo-Delt6 (8)- tetrahydrochysene indolizine and haloethane reacts with each other for ethylization with existence of alkali and organic solution with or without phase transversion catalyst, and produces mentioned product.

本发明在相转移催化剂或无相转移催化剂存在下，6-氰基-1，1-(1，3-亚丙二氧基)-7-(甲氧羰基-甲基-5-氧代-Δ6(8)-四氢中氮茚类化合物与卤代乙烷在碱和有机溶剂的存在下进行乙基化反应即得6-氰基-1，1-(1，3-亚丙二氧基)-7-1′-(烷氧羰基-丙基-5-氧代-Δ6(8)-四氢中氮茚类化合物。

Based on this monomer, several novel polyimides bearing side chain s composed of cyano-biphenyl mesogenic end groups and hexylene spacer were prepared.

合成了一种含氰基联苯氧基侧链的二元胺单体，然后通过两步法热酰亚胺化工艺制备了新型的含氰基联苯基团侧链的聚酰亚胺。

Based on this monomer, several novel polyimides bearing side chains composed of cyano-biphenyl mesogenic end groups and hexylene spacer were prepared.

合成了一种含氰基联苯氧基侧链的二元胺单体，然后通过两步法热醯亚胺化工艺制备了新型的含氟基联苯基团侧链的聚醯亚胺。

Objective:To establish a RP-HPLC method to quantify a new chemical entity HZ08N-cyano-1-[(3,4-dimethoxyphenylmethyl]-3,4-dihydro-6,7-dimethoxy-N -octyl-2(1H)-isoquinoline carboximidamideand its related substances.

目的：建立HZ08N-腈基-1-[(3，4-二甲氧基苯基甲基]-3，4-二氢-6，7-二甲氧基-N-辛基-2(1H)-异喹啉碳酰亚胺的含量测定及有关物质检查方法。

The first part is to synthesize 5-formyl -8- quinolinol from 8-uinolinol and chloroform , using ethanol as a solvent. Then analysizing the 5-formyl-8-quinolinol by IR. The second part is , according to ideas of molecule designing, to synthesize the new self-assembly Inorganic-Organic coordination polymers Co(u2-bpyV2O6,(C4H4N2)Ni2(H2O)2-V4Ol2,(Cl2Hl2N2)Co-V2O6 using Cu, Ni, and Co as templating, 4-cyano-pyridine(4-CNPy), 4,4-bipyridine,pyrazine, l,2-bis(4-pyridyl)ethane, 5-formyl -8- quinolinol as building blocks and Ammonium Metavanadate (NH4VO3) as subordinate building blocks by Hydrothermal , analysizing their content of element determining their structures by X-Ray diffraction.

本课题实验分为两部分：一是配体的合成，以8-羟基喹啉、三氯甲烷为原料，以乙醇为溶剂，合成了5—甲醛基—8羟基喹啉并且对其进行了IR的分析测定；二是配位聚合物的合成，通过分子设计，采用溶剂热法以Cu、Ni、Co为中心离子，以5—甲醛基—8羟基喹啉、4，4-联吡啶、吡嗪、1，2-二吡啶基乙烷为配体，以偏钒酸根(VO_3~-)为辅助配体，通过水热法自组装合成了新的3-D网状结构配位聚合物Co(μ_2-bpy)V_2O_6，(C_4H_4N_2)Ni_2(H_2O)_2·V_4O_(12)，C_(12H_(12)N_2Co·V_2O_6，并对其进行了元素分析和晶体结构的测定。

The method is characterized in that:(1) the reflux of the 2-[N, N- 2amino]-3-cyano-group-4-thiopheneacetic-5-carboxylic acid tetra ester is carried out in the proper sodium hydroxide aqueous solution of alcohol for 5h to 6h and the pH value is kept over 10 during hydrolysis;(2) the ethanol of 20 per cent to 60 per cent is added and then the strontium chloride aqueous solution with 2times to 2.5times molal weight is directly added, precipitates the crystal, is filtered and dried;(3) water is added to carry out the reflux and the little salt packed in the crude product is removed, and the product is collected through heat filtration.

其特征在于：①将2--3-氰基-4-羧甲基噻吩-5-羧酸四酯在适量氢氧化钠水醇溶液中回流5～6小时，水解过程保持pH值10以上；②然后再加入20-60％乙醇，随后直接加入2-2.5倍摩尔量氯化锶水溶液，析出结晶，过滤，晾干；③加水回流，除去粗品中包裹少量盐，热过滤，收集产品。

What would he tell Judith and the children?

他将怎样告诉朱迪丝和孩子们呢？

I this is at that time, the opinion with peacockish true girl is full of in a heart.

这就是当时的我，一个心中布满虚荣的女孩子真实的想法。