查询词典 customs bond

Palladium-catalyzed Suzuki-Miyaura cross-coupling reaction of organoboron with organic electrophiles has been recognized as one of the most important carbon-carbon bond building reactions.

钯催化的有机硼试剂与有机亲电试剂的Suzuki-Miyaura 交叉偶联反应是构建碳一碳键的最重要的反应之一。

The Suzuki reaction, the coupling of organoborate compounds with organic electrophiles catalyzed by Palladium complexes, is a valuable Csp2-Csp bond forming reaction. The reaction has been drawing increased attention in that the reaction permit the use of organoboron compounds that are thermally stable and inert to water and oxygen.In this section microwave promoted Suzuki reaction of phenylboronic acid with benzyl halides catalyzed by Pd(PPh3)2Cl2 DMF/H2O(v/v=10 : 2) was first reported.

第四章：微波辐射下Pd配合物催化端烯与芳卤偶联反应研究本章中我们在微波辐射条件下，研究了PdclZ(P Ph3)：催化端烯与芳卤的偶联反应，合成出了七种乙烯基化合物；并分别考察了微波辐射功率、辐射时间、原料配比、和PTc等因素对反应的影响，优选出了较佳的反应条件，并根据文献及实验结果，讨论了可能的反应机理。

The new opinion and mechanism that the simultaneously adsorption of complex pollution of both organic and heavy metals will be achieved on soil modified with amphoteric surface modifying agent, which have both charged group and organophilic group on one ASMA molecule, were proposed at first time, and its rationality was testified at the same time; The 50% was the critical CTMAB modifying ratio of soil CEC at which the organophilic bond modifying mechanism was emerged; The thermodynamic characteristics of adsorption of OPT and HMP on OMS were discovered ; The study revealed the surface peculiarity of OMS that the modifying agent were distributed at uneven scatter mode and multi-characters surface were coexisted on surface of OMS, revealed the adsorption peculiarity of OMS that multi-mechanisms were coexisted, confirmed the unequal charge amount modifying mode of OMS in which dual-modifying mechanism of both ion exchange and OPB were processed at the same time, and confirmed that the adsorption hobby to CTMAB was higher than that to Ca2+ on Lou soil.

首次提出了用两性表面修饰剂对土壤进行修饰改性，利用两性表面修饰剂所具有的荷电基团和疏水基团达到对土壤中有机、重金属污染物同时吸附的思路和机理，并通过实验证实了所提设想的合理性；发现了土壤CEC值的50%修饰比例是CTMAB开始显现以疏水键机制对土土样表面进行修饰的临界点；揭示了有机修饰改性土对有机物、重金属吸附过程的热力学特征，填补了该项研究工作的空白；阐明了修饰剂在改性土表面呈分散态的非均匀分布，改性土表面具有不同性质表面共存的表面特征和对污染物多机制共存的吸附特征，确定了阳离子表面修饰剂在土表面的修饰是一种离子交换和疏水键结合两种机制相伴并行且为非等电荷量交换的修饰反应模式，以及土具有对CTMAB的吸附偏好性远大于对钙离子吸附偏好性的特征。

The PMMA/SiO2 hybrid materials with the presence of chemical bond through the reaction of WD-20 with tertraethyl orthosilicate were prepared by in-situ polymerization.

深入研究了偶联剂在聚合物/二氧化硅纳米复合材料中的分散作用，制备了光透过率达90%以上的聚合物/二氧化硅纳米复合材料。

Hydroxyapatite Ca_(10(PO_4)_6_2, HA is the main mineral component of human hard tissues. It has great bioactivity and biocompatibility,and after being implanted, it can form a kind of osteal bond with the organic tissues within a short time.

羟基磷灰石化学式为Ca_(10)(PO_4)_6_2是人体硬组织的主要无机成分，具有良好的生物相容性和生物活性，临床植入后能在短时间内与人体组织形成骨性结合。

In this paper, the multilayer system of Ni-Cr-Al-Y-Si overlayer with a DB and a bond coat was deposited on the DSM11 substrate by one-step AIP.

由恒温氧化、循环氧化和粘胶拉伸实验考察了涂层的抗氧化性、 DB阻挡元素扩散能力和体系的界面结合强度。

The calculated results indicate that the energy bathers for the formation of dimethyl ether and trimethyl oxonium ion inside HSAPO-34 zeolite are 1.68 and 0.93 eV, respectively. The suggested intermediate oxonium ylide is very unstable and the energy barriers for the formation of C-C bond are over 3.0 eV by concerted pathway.

结果表明，二甲醚和三甲基氧鎓离子在HSAPO-34分子筛上的生成能垒分别为1.68和0.93eV，中间体氧鎓叶立德不能稳定存在，同时表明C-C键通过协同反应形成的能垒均超过3.0ev。

Microcrystalline cellulose was activated with NaOH solution, then its C2-C3 bond was oxidized with NaIO4 to generate oxycellulose under the acidic condition. The hydroxy on C6 in oxycellulose was chlorinated with sulfur oxychloride in DMF to give oxycellulose chloride.

将微晶纤维素先用NaOH溶液进行活化，然后在酸性条件下，用NaIO4氧化2，3位成为醛基，使其成为氧化纤维素，再将其在DMF下用二氯亚砜进行六位氯化制得氧化纤维氯化产物。

The oxidation of saturated C-H bond is an important technical method to obtain oxygenous organic compounds.

饱和C-H键的氧化是合成有机含氧化合物的重要方法。

From FT-IR we think that the hydrogen bond between the polar oxygenous group on the thin film surface treated with plasma and acetone molecules would enlarge the distance between the carbon black particles, resulting in the addition of the electrical resistance, then the response behavior of the thin film to acetone was improved greatly.

我们通过FT-IR研究认为，等离子体处理后，薄膜表面引进的极性含氧基团与丙酮分子之间氢键的形成会增大炭黑粒子之间的距离，导致了薄膜电阻的极大增加，使薄膜对丙酮蒸气的响应得到很大改善。

Nowadays, most of research are to build a transmutative Petri Nets through adding controlling place sets, controlling arc sets and controlling policy to the basic Petri Nets, while the Controlled Petri Nets could be used to argue many controlling theory problems conveniently and to induce many logically and physically supervisory and solve the Event Feedback Controlling Problems and State Feedback Controlling Problem in DEDS supervisory theory.

目前大多数的研究表现为在变形后的受控Petri网基础上，利用各种方法求得各种逻辑型、结构型控制器，解决DEDS监控理论中的事件反馈控制问题与状态反馈控制问题。

On one hand, there are discussions with the works council and union about extension of short time working up to the end of September.

一方面，有讨论，工程理事会和联盟关于延长工作时间短至9月底。