查询词典 coordination number

In the aluminum solution ,the trivalence aluminum ion combines with water to form the coordination compound and then the coordination waters hydrolyze into hydroxide ions. The hydroxide ions can join up each other by the hydroxide ion bridges so that the double cores, three cores and multiple cores coordination compounds are formed.

另一方面，在这种铝盐溶液中，三价铝离子是以铝水配合物的形态存在，配位水发生水解生成羟基配离子，其通过羟基桥联结，放出水分子，并逐级由单体配合成双核、三核以致形成多核羟基配合物。

In this thesis, a series of complexes based on aromatic multicarboxylic acids have been successfully synthesized in solutions or under hydrothermal conditions. Their structure and properties are investigated.(1) Eight complex compounds have been synthesized and characterized by X-ray single crystal diffractive technology: The eight complexes are listed as following: [Cu242] complex 1 [Cd22(H2O)4]·4H2O complex 2 [Co(H2btc)(H2O)3] complex 3 [Co2(H2O)2]·H2O complex 4 [Ni22(H2O)4] complex 5 [Cu22(H2O)4] complex 6 [Co(H2biim)2(H2O)2](H2btc) complex 7 [Zn(H2biim)2(H2O)2](H2btc) complex 8 The structure of complex 1 is dinuclear complex resulted from weak interactions（0-D chain）; complex 2 is 1-D chain stucture result from interactions of water molecules; complex 3、4、5、6 are coordination polymers using hydrothermal synthses, where the first kind ligand is H4btc, the second kind ligand is phen and Co2+、Ni2+、Cu2+ as center ions, respectively. While the coordination enviroment of Co2+ is the same in complex 3, the coordination geometries around the Co atoms in complex 4 are obviously different because of the different reaction conditions. In complex 4, the 1-D chains are connected into 2-D layer through carboxy groups of ligand H4btc. The structures of complex 5、6 are 1-D chain stucture result from interactions of carboxy groups in ligand H4btc. Complex 7、8 are homeomorphy compounds. Either of them are linked to the 3-D chains through intermolecular hydrogen bonds. Each H4btc lose two protons and H2btc2- acts as negative electron balance.

合成了8个结构新颖的配合物，并用X-射线单晶结构分析方法确定了晶体结构，分别为： [Cu242] 配合物1 [Cd22(H2O)4]·4H2O 配合物2 [Co(H2btc)(H2O)3] 配合物3 [Co2(H2O)2]·H2O 配合物4 [Ni22(H2O)4] 配合物5 [Cu22(H2O)4] 配合物6 [Co(H2biim)2(H2O)2](H2btc)配合物7 [Zn(H2biim)2(H2O)2](H2btc)配合物8 配合物1是一个依靠弱作用连接的双核铜结构；配合物2借助水分子形成一维链状结构；配合物3、4、5、6是以H4btc为第一配体、phen为第二配体，通过水热法合成的配合物，其中，Co2+、Ni2+、Cu2+为中心离子；配合物3中的二价钴离子具有相同的配位环境，不同反应条件下得到的配合物4中的二价钴离子存在不同的配位环境，在配合物4中，一维链通过H4btc上的羧基形成一个二维层结构；配合物5、6是借助H4btc上的羧基形成的一维链状结构；配合物7、8属于异质同晶结构，它们的分子通过分子间氢键形成三维网状结构，H4btc上的羧基失去2个质子，作为一个二价负离子起到电荷平衡作用。

In the thesis, a series of novel single and multi-armed oxadiazole bridging ligands and pyridyl-4, 5-imidazole dicarboxylic acid ligands have been synthesized. The coordination chemistry of these novel ligands with transition metal ions was investigated. In addition, two 1, 3, 4-oxadiazole bridging ligands end-capped by chelating Schiff-base coordination sites have been designed and synthesized. The coordination chemistry based on one of the two ligands with metal ions was primarily investigated.

本文报道了一系列新颖的含1， 3， 4-Oxadiazole杂环的单臂及多臂有机配体，研究了它们与过渡金属离子的配位反应化学；合成了吡啶基-4，5-咪唑二羧酸有机配体，研究了它们在水热条件下与过渡金属离子的配位反应化学；另外，还合成了1， 3， 4-Oxadiazloe杂环桥联的双Schiff-base有机配体，初步探讨了其与过渡金属离子的配位反应化学。

In this research, two novel compounds in which alkylenedithiomethylene Malonic acid act as the main coordination agents and the compounds containing N atom (such as pyridine, Phenanthroline Ethanediamine and 4,4'-Bipyridinyl) act as the associating coordination agents have been synthesized by the means of solution and solid-liquid diffusing reactions. 9 coordination complexes and polymers have been designed and synthesized in which the transition metals Cu and Zn acted as the centre ions. These compounds have been characterized by X-ray single crystal diffraction analysis, and some properties of them have been tested and analyzed.

本论文设计合成了两种结构新颖的含有二硫缩烯酮结构的丙二酸类化合物，以此为主要配体，以含氮化合物(吡啶、邻菲罗啉、乙二胺和4，4'-联吡啶)为辅助配体，采用常规溶液合成和固-液相扩散等方法，设计合成了9个过渡金属Cu和Zn离子配合物和配位聚合物，采用单晶X-射线衍射等技术对晶体结构表征，并对其部分性质进行了测试和分析。

Dual-manipulator coordination motion planning based satellite attitude control and path optimization strategy and algorithms are proposed. According to the function of two manipulators, four kinds of coordination modes of stabilizing function, counterbalancing function, adjusting function and cooperative operation are defined. Common motion planning algorithm for the four kinds of coordination modes is proposed.

在讨论卫星姿态控制的重要性和实现方法的基础上，指出了通过机械臂运动进行卫星姿态控制的可行性及优越性，提出了基于双臂协调运动规划的机器人卫星姿态控制及路径优化的策略和算法，定义了稳定作用、平衡作用、调节作用和协同作业等四种双臂协调方式，并给出了四种协调方式下统一的运动规划算法。

The coordination problem has been a major issue in supply chain management research. Coordination mechanism is always used to solve non-coordination problems between members of a supply chain.

供应链协调问题已经成为供应链管理研究的主要方向之一，而协调机制的建立往往是解决供应链成员间不协调问题的主要手段。

Then the coupling degree has been analyzed about 31 regions (not including Hongkong, Macao and Taiwan) in China during the year of 2005. The result indicates that all the couping degrees in different provinces are rather higher, but the coordination degrees differ greatly and most of the coordination degrees belong to two types: medorate ang high coordination; from the point of the relation of ecological-environment to economy development most of the provinces have not reach the condition of harmonious reaction due to either sluggish ecological-environment or economy.

并对中国2005年31省区（不包括香港、澳门和台湾）的农业生态环境与经济发展的耦合度进行分析，结果表明，各省区农业生态环境与经济系统的耦合度均处于较高水平，但协调度却差异显著，且以中度协调与高度协调为主；从环境与经济关系看，绝大多数省区处于不同程度的环境滞后型或经济滞后型，农业生态环境系统与经济系统之间还远没有达到良性共振的状态。

As the distances between coordination sites of auxiliary ligands increasing, the distances between adjacent two-dimensional [Er(5-NO_2-bdc)_2]~- anion layers enlarged. As the bulks of auxiliary ligands largening, the coordination configuration of Er optimized and the dimensions of coordination polymers increased.

增大辅助配体的配位点之间的距离，增大了二维[Er(5-NO_2-bdc)_2]~-阴离子层之间的距离；增大辅助配体的空间位阻，优化了金属离子的配位几何构型，使配位聚合物的维度增大。

In addition, the coordination number of coordination complex formed by phosphorus pentafluoride and aether was calculated and the number decreases from 2.04 to 0.8436 when temperature rises from 0℃ to 30℃; the equation of dissolving rate was also acquired: Y = Bi+2 BiX.

此外还计算了五氟化磷与乙醚形成缔合物的配位数，当T从0℃～30℃时，其值为2.04～0.8436；从试验中得出了不同温度下的溶解速率方程：Y′=B_1+2 B_2X。

When using relative number or average number to get averaging, you may use denominator or numerator of this relative number or average number as weight number to weigh the relative number or average number,and use frequency formula or weighted harmonic mean formula of weighted arithmetic mean formula to get its mean value.

在由相对数或平均数求平均数时，可以以这一相对数或平均数的分母或分子为权数，对这一相对数或平均数进行加权，利用加权算数平均数的频数公式或加权调和平均数公式求其平均值。

Metrorrhagia is also gynaecological problems of common diseases.

崩漏是妇科常见病也是疑难症。

WordFTP gives you the convenience and timesaving you need.

wordftp让您的方便和省时您所需要的。