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It is existed competitiveness inhibition of 6APA, non-competitiveness inhibition of PAA and substrate inhibition of Penicillin on the hydrolysis of benzylpenicillin to 6APA and PAA by an immobilized penicillin amidase. The heat conductive coefficients were determined on the vacuum elevation liquid membrane concentration. The thermodynamics and kinetics of PAA extraction were studied on the organic solvent extraction of the above solution.

研究证明固定化青霉素酰化酶裂解反应是典型的底物、产物抑制酶反应,其反应动力学数据表明,青霉素、苯乙酸以及6APA对反应分别存在底物抑制、非竞争性抑制和竞争性抑制;真空升膜浓缩适应热敏性以及粘度不大的物系,对于6APA水溶液的真空升膜浓缩过程研究得到了浓缩实验的传热系数;浓缩液萃取主要是提取出其中的苯乙酸,本文测定了不同温度以及溶剂条件下的苯乙酸溶解度,并观测了苯乙酸萃取动力学。

In addition, some modifications on several computational methods are also presented. Using LMTO method the electronic structure of several systems are studied, and some results are obtained. They are: The ideal Nb (100) surface has three surface states, the multi-layer relaxed surface has two surface states. The surface energy of the ideal surface is higher than that of the relaxed surface, that means that the multi-layer relaxed surface is more stable than the former one, which supports the LEED results. The mono-layer relaxed Ag (111) surface is the most stable one among several" stable surface models"presented by several researchers. The surface energy of Ag (111) surface is higher than that of surface Ag (001), which supports some experimental results such as different reaction rate at different surface orientations for the same material. The surafce states of Si (111) surface not only locate near the Fermi level, but also in the valence band, which agrees well with Cohen's conclusion. Si (111)-H is an effective model for analysing the surface states and H adsorbed on the back surface is a good method for improving the convincingness of the results obtained on thinner slab models. The surface stability depends on three different kinds of MoSi〓(001) surfaces, the surface with mono-layer Si is the most stable one, and the surface with Mo at the first layer is the most unstable one among them. These are consistant with the Kemoda's experimental results. The valence bands of clean or K adsorbed CdTe (111) surface agrees well with the synchrotron radiation studies. The surface of CdTe (111) consists of four kinds of surface models which show different surface electronic structures and different surface structure stabilities. The conclusion agrees well with Wu's experimental work. The different absorbed alkali metals on the CdTe (111) surface give different adsorption characteristics which have relations not only with the valence electrons, but also with the core ones of the alkali metals. The electonic structures of Si-C alloys are different from that of Si-Ge alloys, and the energy band gaps of Si-C alloys do not increase linearly with Carbon concentration, our conclusion supports Alexander's results, but conflicts with Soref's one.

现分述如下: LMTO方法及其应用方面:1)通过对Nb(100)表面电子态分析发现清洁理想表面有三个表面态,多层弛豫表面有两个表面态;表面能大小说明多层弛豫表面更稳定,支持了LEED结果。2)通过对采用不同方法获得的几种不同Ag(111)表面稳定结构的表面能计算分析,给出了单层弛豫表面为Ag(111)表面的最稳定结构;从Ag(111)单层弛豫表面和Ag(001)表面的表面能比较,发现了Ag(001)表面表面能要比Ag(111)小的,表明了同种物质不同表面取向将表现出不同物理、化学性质,这是与实验中得出的结论是吻合的,3)通过对Si(111)表面态分析,不仅发现了Si(111)表面不仅具有居于费米能级附近的悬挂键所对应的表面态,而且还有很多表面态位于价带能量范围内,与Cohen等结果一致,H饱和slab模型背表面相当于增加了slab层的厚度,是一有效的变相增加slab层厚的方法,弛豫表面较清洁理想表面价带谱们低能端的少许移动,预示着总能降低,说明弛豫表面较清洁理想表面稳定。4)MoSi〓具有三种表面,从费米能级上态密度值大小得到单层Si表面最稳定,Mo原子为表层原子的表面最不稳定,双层Si原子表面居中的结论,这与Kemoda等人实验结果是一致的。5)通过对CdTe(111)表面表面电子态、表面结构稳定性及表面H、碱金属吸附的电子结构系列研究,不仅得出了CdTe(111)清洁及碱金属K吸附价带谱与同步辐射光电子谱相吻合的结果,而且发现了CdTe(111)表面具有四类不同原子近邻特征,表现出四类不同的表面结构及电子结构特征:不同表面态分布、不同的表面结构稳定性(表层原子与次层原子成三键有一悬挂键的表面要比表层原子与次层原子成一键有三悬挂键稳定(与Wu等人实验结果一致))、不同的H吸附特性。

The influence of high temperature and high pressure on foaming agent's properties in opened and closed system, and influence of the change of foaming agent's properties on foaming capacity and foam stabilizing capacity are also studied. The multiple regression theory is used to establish the quantitative characteristic functions of foaming agent versus temperature and pressure. Based on the Gibbs Principle, the quantitative characterization is carried out on relation of foam system's free energy versus its surface tension, surface area and concentration, and the analysis of energy concluded that the disintegration of the foam is inconvertible. At the same time, the influence of change of foam's shape and structure on distribution of reservoir temperature and pressure is qualitatively described, and the coupling mechanism between temperature field, pressure field and chemical field is systematically expounded.

同时,研究了不封闭体系、封闭体系下高温、高压对发泡剂性质的影响,以及发泡剂性质的改变对其发泡性能、稳泡性能的影响;采用泡沫实验的相关结果,运用多元回归理论,建立温度、压力与发泡剂浓度的定量表征函数;基于Gibbs原理,对高温、高压下泡沫体系的自由能与其表面张力、体系中液体的表面积以及浓度关系进行定量化的表征研究,从能量的角度得出了泡沫衰变过程具有不可逆性;同时定性地描述了泡沫形态、结构的变化对油藏温度和压力分布的影响,系统地阐述了温度场、压力场、化学场间的耦合作用机理。

This project studies the scale-dependent deformation behavior of the metal matrix composite, the void nucleation and void growth mechanisms at the micron/submicron scale. The main results are:(1) In prophase, growth and coalescence of the void embedded in the graded matrix are analyzed in detailed;(2) Based on the infinite solid model containing a micro-void, coupling effects of the void shape and the void size on the void growth are studied carefully, the results show that it seems to exist a critical equivalent void radius, which is associated with the material length. When radius of a microvoid is close to or smaller than the critical void radius, the micro-void growth rate is essentially eliminated;(3) The coupling effects of the particle shape and size on the mesoscopic stress fields within the particle and matrix are also investigated by introducing the conception of inclusion/matrix interfacial energy. The results show that the stress concentration factors within the particle and on the matrix/particle interface are also strongly size-dependent,so the void nucleation mechanism is size-dependent.(4) By employing a specific orthogonal curve coordinate frame and a 'kernel function' conception, a 'unified method'solving the spheriodal and spherical void problems is suggested; by this unified method, size-dependent plastic potentials of the porous materials containing the spheriodal or spherical voids are obtained, which extend the traditional Gurson model for the spherical void and GLD model for the spheriodal voids to the micron scale.(5) Based on the RVE model containing the spheriodal or spherical particles, the influences of the particle shape and size on the size-dependent mechanical behavior of metal matrix composite are studied.

中文摘要:本项目对金属基复合材料在微细观尺度下的尺度相关变形行为、孔洞形核及长大的机理和模型进行了研究,取得了如下主要结果:1)在前期研究中,探讨了基体的梯度分布对孔洞长大和聚合的影响;2)基于含孔洞的无限大体模型,探讨了孔洞形状和孔洞尺寸对其长大的耦合作用,结果表明:可能存在一个与材料特征长度相关的临界孔洞尺寸,当椭球孔洞的等效半径小于临界孔洞半径时,孔洞的长大受到明显抑制;3)通过引入基体/夹杂界面能的概念,分析了夹杂尺寸、夹杂形状对材料细观应力场的耦合影响,结果表明:颗粒内部和界面上的应力集中因子强烈地依赖于夹杂的尺寸和形状,因此,孔洞的形核机理是尺寸相关的;4)采用一种特殊的正交曲线坐标系和引入"核函数"的概念,"统一"地得到了含椭球和球形孔洞的材料的尺寸相关塑性势,它将传统的Gurson球形孔洞模型和GLD椭球孔洞模型推广到微尺度范围;5)基于含椭球和球形夹杂的体胞模型,初步研究了夹杂形状、夹杂尺寸对金属基复合材料尺寸相关力学行为的影响。

The method on trans fatty acids analysis in food is very important. The effects of methylate sodium, potassium hydroxide, sulfuric acid and boron trifluoride in methanol and their different concentration and dosage on TFA analysis were studied. The chromatographic condition and the influence of time and temperature on the esterifation of TFA using boron trifluoride in methanol were optimized. A method for analyzing TFA were established by GC based on boron trifluoride in methanol and RT-2560(100m×0.25mm×0.2μm) capillary column.

研究了甲醇钠-甲醇、氢氧化钾-甲醇、浓硫酸-甲醇和三氟化硼-甲醇4种甲酯化试剂的浓度、用量及甲酯化时间和温度对反式脂肪酸检测的影响,优化了色谱条件,建立了以三氟化硼-甲醇法甲酯化,RT-2560(100m×0.25mm×0.2μm)毛细管柱为基础的反式脂肪酸气相色谱检测方法,C18:1-9 t, C18:1-11 t, C18:2-9 t, 12 t和C22:1-13 t 4种反式脂肪酸的最小检出浓度在0.774.08 mg/kg之间。4种反式脂肪酸不同添标浓度回收率为98.44%101.23%,重复测定的相对标准差在0.22%1.31%之间,有较好的准确度和重现性。

objective effects of plant tannins,chebulinic acid and tellimagrandin i on chemically induced hemoglobin synthesis in k562 cells were investigated.methods the hemoglobin synthesis situation was assayed with benzidine staining.erythroid antigens glycophorin a expression on the surface of k562 cells was labeled by direct immunofluorescence using fluorescein isothiocyanate-conjugated anti-gpa antibodies.then flow cytometric analysis was performed to detect gpa expression levels on surface of the cells.results both chebulinic acid and tellimagrandin i could inhibit the hemoglobin synthesis of butyric acid and hemin-treated k562 cells in a concentration-dependant manner.however,the ba-induced k562 cells were more sensitive to two tannins than heroin-induced cells.conclusion chebulinic acid and tellimagrandin i have inhibitory effect on the erythroid differentiation.

目的 研究可水解单宁诃子酸和特里马素i对氯化高铁血红素和丁酸钠诱导k562细胞红系分化的影响。方法四甲基偶氮噻唑蓝法分析诃子酸和特里马素i对k562细胞生长的影响,联苯胺染色法检测血红蛋白合成情况,应用免疫荧光和流式细胞术检测血型糖蛋白a在细胞表面的表达。结果诃子酸和特里马素i在0.04~0.09?mmol/l浓度下均可显著抑制k562细胞的生长增殖。2种单宁化合物(0.002~0.01?mmol/l)可显著抑制丁酸钠诱导的k562细胞血红蛋白合成,2种单宁化合物(0.01~0.05?mmol/l)还可显著抑制氯化高铁血红素诱导的血红蛋白合成,特里马素i(0.01?mmol/l)还抑制丁酸钠诱导的gpa在细胞表面表达。结论诃子酸和特里马素i对红系分化有抑制作用。

The minimal bactericidal concentration of PTKE on Escherichia coli, Staphylococcus aureus, Salmonella, Pasteurella multocida and Streptococcus agalactiae were 100, 25, 50, 25 and 50 mg/mL respectively. The isolation of EA, EB and EC had no antibacterial effect on Escherichia coli and Pasteurella multocida. MBC of EA on Staphylococcus aureus and Salmonella were 2.5 and 5 mg/mL, and MBC of EB on Staphylococcus aureus, Salmonella and Streptococcus agalactiae were 1.25, 5 and 2.5 mg/mL respectively, while MBC of EC on Staphylococcus aureus was 2.5 mg/mL. Polygonum taibaishanense Kung.

PTKE对大肠埃希菌、金黄色葡萄球菌、沙门氏菌、多杀性巴氏杆菌和无乳链球菌的最低杀菌浓度分别为100,25,50,25和50 mg/mL;而PTKE的分离物EA、EB和EC对大肠埃希菌和巴氏杆菌无抑菌作用,EA对金黄色葡萄球菌、沙门氏菌的MBC分别为2.5和5.0 mg/mL,EB对金黄色葡萄球菌、沙门氏菌和无乳链球菌的MBC分别为1.25,5.0和2.5 mg/mL,EC对金黄色葡萄球菌的MBC为2.5 mg/mL。

The difference of bulk density of coastal soils took an effect on infiltration rate and diffuse rate. The infiltration rate and diffuse rate of coastal soils which bulk density was small were big. The water transmitting experiment of coastal soils showed that the saturated conductivity of different layers in soil profile were great, and the saturated conductivity of undisturbed soil was highly higher than that of disturbed soil. The saturated conductivity of coastal soils embanked earlier was lower than that of coastal soils embanked later. Under different water content, the unsaturated conductivity of coastal soils had a great change and the bulk density had an effect on unsaturated conductivity. The soil with a low bulk density had a high unsaturated conductivity. Chlorine ion moved in coastal soil was an inert ion. The distribution of CU in soil was definite and repeated, which is no relation with the time and velocity of infiltration. The concentration of infiltration solution and the texture of coastal soils had no apparent effect on solute movement synthetic dispersion coefficient, while bulk density took an apparent effect on solute movement synthetic dispersion coefficient. Synthetic dispersion coefficient of coastal soils increased as bulk density decreased.

浙江大学硕士毕业论文浙北海涂土壤水分特性及溶质运移模拟研究 4、海涂土壤的导水能力强,且土壤剖面备土层的饱和导水率变化大,原状土的饱和导水率远大于扰动土的饱和导水率,围垦时间较早的海涂土壤的饱和导水率较围垦时间晚的海涂土壤的饱和导水率要小;不同含水量下的非饱和导水率变化范围很大,最大值与最小值差距可达 10'③ 5、容重的不同对入渗率、扩散率、非饱和导水率都有影响,容重小,入渗率、扩散率、非饱和导水率也花 6、在海涂土壤中运移的氯离子是一&惰性离子&,氯离子在土壤运移过程中的分布有一定的确定性和重现性,与入渗时间和入渗速度无关,溶质运移过程中,入渗溶液的浓度和海涂土壤的质地对溶质运移综合扩散系数DSh无明显影响,而土壤容重对溶质运移综合扩散系数DSh有影响,容重小,DSh大。

B light to intermediate transfer website performance is if the full-color printed a thick and strong, can be used instead of ultrafine 300, 400-mesh point to no buyang, but there are in the supporting this super fine wire is not a good business card printing and membership card production, resulting in the whole-tone, so use with four color separation business card printing and membership card production, decreased slightly in the optical Department, dot by LC, LM on magenta and supplemental lighting of a thick and are some of the use of laodelphax LB the light grey, LR on peach, LG 浅紫 light-green, LV, and so on secondary light-coloured, and this is the kind of color by the car and it came to technical method of extension, how to make sure the complementary color concentration and minus four dot color separation, is out on the relationship between the original and buyang is the most difficult technical staff must villagers'participation.

平部到洋间调的网不面表示不若印满版色菲薄无力,可以改用超粗300线、400线以上钩不面来弭补,但有见於这栽超粗网线并欠好制卡和会员卡制作,造不败整版色调不佳,所以改用以四色版制卡和会员卡制作,在平部稍降网不面百分比,由LC不深蓝、LM不深洋赤等来补平部之菲薄感有些搁置LB灰不深灰、LR不深桃、LG不深红、LV不深紫等二不主色不深色为之,这是栽由手工开色石版法蔓延来的技艺,如何拿捏补色浓度及增去原有四色版网不面百分比,是开不入来本来及补不出色版时技艺职员最不易也是务必的考量。

The synthesis process of silica using waterglass and sulpHuric acid as materials was studied systematicly. The results show that reacting temperature, reacting time, sulphuric acid concentration, reactive stiring rate, modulus of waterglass,adding salting agent,alkali concentration,the total volume of acid and alkali added , different methods of adding materials may have influence on the specific surface area or dibutylphthalate absorption number of silica in different degree.

本文系统地研究了以水玻璃溶液和硫酸为原料合成沉淀法白炭黑的工艺,研究发现:反应温度、反应时间、硫酸浓度、反应搅拌速度、水玻璃模数、添加盐析剂、底碱浓度、酸碱加入的总量、加料方式对白炭黑的比表面积或DBP吸收值有不同程度的影响。

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In the negative and interrogative forms, of course, this is identical to the non-emphatic forms.

。但是,在否定句或疑问句里,这种带有"do"的方法表达的效果却没有什么强调的意思。

Go down on one's knees;kneel down

屈膝跪下。。。下跪祈祷

Nusa lembongan : Bali's sister island, coral and sand beaches, crystal clear water, surfing.

Nusa Dua :豪华度假村,冲浪和潜水,沙滩,水晶般晶莹剔透的水,网络冲浪。