查询词典 compounds

All the compounds were isolated and identified from the bituminous coals for the first time, bis(2-ethylheptyl) terephthalate and 18-ethyl-17-(hexan-2\'-yl) docosanoic acid are new compounds.Further more, a Colourless Oil Liquid, a white acerate crystals containing some alkanes, a white tabular crystals consisting of some fatty acid esters and a white powder crystals in which some fatty acids exist were isolated and analysed by GC/MS for the first time.Through this research, a study method of"classification extract of bituminous coal- separation with silica-gel and gelatin column chromatographies- identification of the isolated compounds by FTIR, GC/MS, LC/MS, 1H NMR and 13C NMR analyses"was established and proved to be a practical approach toward separable and non-destructive identification of some organic compounds in bituminous coals for coal chemistry research.

本研究建立了&原煤分级萃取-硅胶与凝胶柱层析分离与纯化-GC/MS或LC/MS检测-FTIR、MS、1H NMR和13C NMR波谱解析&这一煤中有机化学成分的非破坏性分离与分析的研究方法，并验证该研究方法有效可行。

The invention relates to a method for preparing arylamine compounds by the catalytic hydrogenation of arene nitro compounds in a H2O-CO2 system, wherein H2O-CO2 is taken as reaction medium, and the arylamine compounds are prepared by the selective hydrogenation of the arene nitro compounds at a low temperature(between 25 and 100 DEG C), and the catalytic process is controllable, highly efficient and green.

本发明涉及H 2 O-CO 2 体系中芳烃硝基化合物催化加氢制备芳胺类化合物的方法。以H 2 O-CO 2 为反应介质，由芳烃硝基化合物低温(25-100℃)选择性加氢制备芳胺类化合物的可控、高效、绿色催化过程。

Replacement of one benzimidazole fragment with benzothiazole or benzoxazole and optimization of the structure to create the new frame of the compounds were also carried out with the exception to find more potent compounds. The purpose of design and synthesis of these compounds is to investigate the QSAR of this class of compounds with the inhibition of HCV NS3/NS4A protease and eventually to develop more potent inhibitors.

本文首次采用了丙二酰胺与邻芳二胺在微波辐射下制备对称性双芳并唑甲烷化合物、用芳并唑-2-乙酸乙酯与邻芳二胺在微波辐射下制备非对称性双芳并唑甲烷化合物、用4-取代噻唑-2-乙酸乙酯与邻芳二胺在微波辐射下制备非对称性(4-取代-噻唑-2-基)(1H-芳并咪唑-2-基)甲烷化合物等合成路线，共合成了48个目标化合物，其中41个为新化合物，用~1HNMR，ESI-MS，FT-IR，元素分析对这些化合物进行了全面表征，确定了这些化合物的结构，并对部分化合物进行了~(13)CNMR分析。

Among these investigated compounds, benzothiophene, dibenzothiophene and thianthrene are stable at the highest pyrolysis temperature and suggest that these compounds are geochemical stable compounds and this is consistent with that these compounds are widely existence in the mature petroleum and sedimentary organic matter.

在所调查的化合物中，苯并噻吩、二苯并噻吩、二苯硫和噻蒽等在最高热解温度下也不发生任何化学反应，表明这些化合物代表了稳定型结构的硫化合物，这与这些化合物广泛存在于成熟原油和沉积有机质中的状况是一致的。

The major results obtained are: PCR-RFLP method is suitable for molecular identification of Shihu; 205 compounds were isolated from 10 species of Dendrobium, including 21 new compounds, and 28 compounds isolated from genus Dendrobium for the first time. Each of the extracts and compounds were screened for anticoagulant and antitumour activities separately. The results indicated that the ethyl acetate extract from Dendrobium chrysanthun has significant anticoagulant function; the antitumour function of the 4 bibenzyl components from Dendrobium chrysotoxum is stronger than that of phenanthrene, of which the erianin has significant anti-angiogenic effect both in vivo and in vitro; components with moderate or stronger antitumour activities were found in the extracts of D. thyrsiflorum, D. chrysanthun and D. trigonopus; quality standard for 5 species of Dendrobium was drawn up use active or indicative components as control.

重要研究结果有：经方法学研究，认为PCR-RFLP法适于作为石斛属药材分子标记鉴定方法；对10种石斛进行化学成分分离鉴定，共分得205个化合物，其中新化合物21个，首次从石斛属分得的28个；对提取物和各单体化合物分别作抗凝血、抗肿瘤等活性筛选，结果说明束花石斛乙酸乙酯部位有显著的抗凝血作用，鼓槌石斛的4个联苄类成分抗肿瘤作用强于菲类，联苄类毛兰素在体内外有显著抗血管生成活性，球花石斛、束花石斛及翅梗石斛均筛到中等或较强抗癌活性的成分；选择有活性或指标性成分作对照品，对5种石斛草拟了质量标准。

Sn with the content of 0.004% in the lithosphere is almost in presence of cassiterite and little in presence of Sn-contained sulfide. Since 1980s, the anticancer active study on organic complex compounds has attracted considerable attentions, it becomes another hot issue after the study on Pt. When time up to the year 1989, the anticancer active measurement of more than 2000 kinds of Sn-contained complex compounds have been carried out by Cancer Academy, U.S, with the results showing half of these Sn-contained complex compounds posses antileucocythemia(P388) activity. Thereafter, Sn-contained complex compounds synthesized by hydrothermal reaction also become a hot issue people focus on.

Sn在地壳中的含量为0.004%，几乎都以锡石的形式存在，此外还有极少量的Sn的硫化物。20世纪80年代以来，人们对Sn有机配合物抗癌活性的研究产生了浓厚兴趣，成为继顺铂之后又一活跃的研究热点，到1989年，美国国家癌症研究所对2000多种Sn的配合物进行了抗癌活性测定，结果表明，50%的配合物具有抗P388白血病活性，故水热溶剂热合成锡的配合物也成为人们的研究热点。

Pymetrazine is chosed as the lead compound, and 21 compounds were firstly designed and synthesized. These compounds were characterized by introducing phenyl derivatives with different functional groups to replace pyridine ring with the isosteric principle and the method of homogeneous synthesis and reasonable biologically designing in order to find new compounds with potential biological activity. These compounds were confirmed by IR, H NMR and MS spectra.

本文选取吡蚜酮为先导化合物，运用电子等排理念，综合类同合成、生物合理设计的方法，引入含有不同官能团的苯基衍生物替代吡蚜酮的结构中心吡啶环，设计合成了21个未见文献报道的化合物，寻找具有潜在生物活性的新三嗪酮类化合物，通过核磁共振氢谱、红外光谱、质谱等手段进行了结构表征，并验证正确。

The present doctoral dissertation was carried out to study the chemical constituents isolated from stems of two medicinal schisandraceous plants.34 compounds were isolated from the ethanol extracts of the stems S.henryi collected in the Jiangxi province by various column chromatographies.27 of them were identified on the basis of spectral analysis.There are 18 lignans,(including 5 dibenzocyclooctadienes,6 aryltetralins,2 tetrahydrofurans,3 diarylbutanes,2 other lignans),3 flavanols,2 glyceroesters,1 naphthoquinone,1 xanthine and 2 steroids,of which 6 compounds were new compounds,and 7 compounds were isolated from this family for the first time.

采用多种色谱技术进行分离纯化，从翼梗五味子藤茎的乙醇提取物中分离到34个化合物，综合运用现代波谱学技术鉴定了27个化合物，包括木脂素类化合物18个(其中联苯环辛烯类木脂素5个，芳基四氢萘类木脂素6个，四氢呋喃类木脂素2个，二芳基丁烷类3个，其他类型木脂素2个)，黄烷醇类化合物3个，甘油酯类化合物2个，萘醌类化合物1个，黄嘌呤类化合物1个，甾体类化合物2个，其中，5个为新化合物，7个为本科首次报道。

This section includes the nonindustrial preparation, purication, and reactions of inoganic substances:elements; inorganic acids, bases, and salts; synthetic minerals; inclusion compounds;charge-transfer complexes; coordination compounds containing inoganic and organic ligands;nonmetal and metalloid compounds; and carbon-containing compounds such as the carbon oxides, metal carbonyls, carbonates and transition metal carbonxylates.

这一章节涵盖了无机物的非工业制备、提纯、及反应：元素；无机酸、基团和盐类；合成矿物质；包藏复合物；转移电荷复合物；包含了无机和有机配合基的配位化合物；非金属与非金属化合物；以及含碳化合物，如碳氧化物、金属羰基、碳酸盐和含有羰基的过渡金属等。

To discover new strobilurin analogues with high pesticidal activity, a series of new strobilurin derivatives containing substituted pyrazole and pyrimide ring, which included 124 novel compounds (73 compounds containing substituted pyrazole ring and 51 compounds containing substituted pyrimide ring) were designed and synthesized. In addition, 36 new intermediates were synthesized. Their structures were characterized by ~1H NMR and elemental analysis, partial compounds were characterized by MS and IR once again.

为了发现具有更好生物活性的新型Strobilurin类化合物，本论文在详尽总结文献的基础上，设计并合成了含吡唑和嘧啶环的新型Strobilurin类化合物124个，其中含吡唑环的新型Strobilurin类化合物73个，含嘧啶环的新型Strobilurin类化合物51个；未见文献报道的中间体36个，所合成的化合物经过~1H NMR、IR、LC-MS或元素分析等确定了结构。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了