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Compounds 1 and 2 were isolated from the genus Coleus for the first time.Compounds 3 and 4 were isolated from C.forskohlii for the first time.

化合物1和2为首次从鞘蕊花属植物中分离得到，并首次运用2D-NMR技术对其碳氢信号进行准确归属，化合物3和4为首次从毛喉鞘蕊花中分离得到。

A method for determinating the activities of pectinase was proposed in this paper. It can produce the red-brown amino compounds when 3,5-dinitrosalicylic acid and aldehyde were heated together. The amino compounds had maximum absorbency at 540nm. In certain range, there was a good linear relationship between the amount of reducing sugar and the color of the reaction mixture.

针对QB1502-92标准测定方法测定高活力果胶酶、固定化果胶酶活力存在的实验误差大，重现性及灵敏度差的缺陷，提出了利用3，5-二硝基水杨酸与醛糖共热产生棕红色的氨基化合物，在一定范围内还原糖的量和含有呈色氨基化合物的反应液颜色深浅成正比的原理，在540nm下测其吸光度，从而计算出果胶酶活力的测定方法，并对测定步骤、影响因素及测定中可能出现的问题进行了试验研究。

1H NMR spectroscopic analysis of aromatic protons combined with theoretical analysis of molecular structures proved the existence of two rotational isomers at 300 K, as well as a rapid interconversion equilibrium at 330 K for both compounds Ⅰ and Ⅱ. However, only one conformer exists for compound Ⅲ and puerarin containing 7-phenolic hydroxyl instead of propyl in A-ring as the case of compounds Ⅰ and Ⅱ. Based on UV-Visible absorption data of neutral and basic solutions, and on the density function calculations, the 7-phenolic hydroxyl group in A-ring was found to be more acidic than the 4'-phenolic hydroxyl group in B-ring. The mechanism of derivation reaction and the structure-reactivity relationship of puerarin as an antioxidant were further discussed.

其中7-丙基葛根素Ⅱ属于新型取代衍生物；变温1H NMR和理论计算结果表明，在300 K时，葛根素和4'-丙基葛根素以单一构型存在；而7，4'-二丙基葛根素和7-丙基葛根素则存在两种核磁可分辨的旋转异构体，当温度升至330 K时，两种异构体可以相互转化；通过对比分析葛根素及其衍生物脱质子产物的紫外可见吸收光谱并结合理论计算，确定了A环上7位酚羟基比B环上4'位酚羟基先脱去质子，并由此进一步阐明了葛根素衍生化反应机理以及在抗氧化作用中可能的活性位点和结构活性关系。

The method, which is capable of effecting very good separation of phenol and the 3 cresol isomers under the same chromatographic conditions, can be used to determine phenolic compounds in phenolic tar by external standard, and to analyze these compounds in the toxic leaching solution of the tar.

摘 要：建立了酚焦油中酚类物质质量分数测定和浸取毒性测定的气相色谱法，此法可以在同一色谱条件下对酚焦油中的苯酚及邻、间、对甲酚实现很好的分离，利用外标法分别进行定量分析，并对酚焦油浸取液中相应组份进行测量。

The results showed that the optimum conditions for pretreatment of coking wastewater were 6 g activated carbon per liter, 30 ℃, pH=9 and reaction for 20 min, under which the removal efficiency of organic pollutants are more than 70%. Among the 56 kinds of organic compounds, 45 kinds such as dolichoalkanes, polynucleation aromatic series, azacyclo compounds could be removed, and the removal ratios of amidobenzene, hydroxybenzene, indoleacetic, acid-2-methyl-phenyl-ester are 63.5%, 42.6%, 88.1%, 28.1% respectively, while cresol and xylenol are more than 70% and 85%.

结果表明，在最佳反应条件即活性炭投加量6 g·L-1，温度30 ℃，pH＝9，反应时间20 min的情况下处理废水有机物去除率大于70％，原水中检测出的56种有机物中的45种被去除，如长链烷烃、多环芳香族及氮杂环化合物等的浓度降至检测限以下，剩余的11种有机物中苯胺、苯酚、吲哚、乙酸-2-甲基苯酯的去除率分别达到63.5％、42.6％、88.1％、28.1％，甲苯酚和二甲苯酚(5种)去除率在70％和85％以上。

The anti-inflammatory activity of five of these compounds (B1, B4, B5, B6 and B7) was tested on mouse ear edema induced by croton oil, and the result showed that the inhibition ratios of compounds B4, B6 and B7 were between 65. 9%, 61. 7%and 52. 5%respectively (P.001%compared with control group), when the hypodermic injection dose was 50mg/kg, which are worthy for further research and development.

测定了其中5个化合物B1、B4、B5、B6和B7的抗炎活性（剂量为50mg／kg，皮下注射），发现化合物B4、B5和B7抗炎活性较好，对小鼠耳廓肿胀的抑制率分别为65.9％、61.7％和52.5％，和对照组相比P.001，这些化合物有进一步研究开发的价值。

All compounds are synthesized starting from the acylation reaction of gallic acid with L-glutamine to form the basic scaffold, followed by the cyclic reaction in acetic anhydride and the key intermediate cyclic anhydride (compound 4) was obtained. The intermediate compound is condensed with different amino acids or primary amines, and produces the target compounds.

本研究以L－谷氨酸为基本骨架，与甲醚化保护的没食子酸缩合后，经过酰化、环合反应得到关键中间体环状酸酐（化合物4），再经胺解反应合成目标化合物，其化学结构经过红外光谱、电喷雾质谱和核磁共振谱（氢谱、碳谱、碳氢异核多键相关谱）确证。

The facts that type I compounds could easily undergo deamination reaction to form α-methylene cyclopentanone derivatives and they could react with glutathione to form an adduct provided sufficient evidence for the hypothesis that the compounds acted as masked α-methylenecyclopen- tanones and reacted with biologically important sulfhydry-containing enzymes, and thus produced anticancer activity.

Ⅰ类化合物在稀溶液中极易进行去胺基化反应形成α-亚甲基环戊酮类化合物。并且Ⅰ类化合物于稀溶液中易与谷胱苷肽进行结合，这些事实为Ⅰ类化合物作为隐蔽的α-亚甲基环戊酮与酶进行加成，从而导致酶失活而具有抗癌活性的设想提供了证据。

All the compounds are characterized by IR and elemental analysis.we design and prepare a bipyridinium supramolecular compound and six coordination compounds, which are also characterized by IR, elemental analysis and X-ray structure analysis. According to X-ray structure analysis, hydrogen bonds and n-n stocking interactions participate in the architecture of three-dimensional framework [H2L1 (NO3)2 (H2O)2]n; one-dimensional zigzag coordination polymer [Hgl21.5CH3OH]n; binuclear metallamacrocycle (HgI2L2)2 3H2O; helical double-stranded one-dimensional coordination polymer [Co2(L2)2-2CH3OH]n; double-stranded one-dimensional coordination polymer [Co2(L3)2-CH3OH-CH3CN]n; and three-dimensional compound [Cu(C5H4NCOO)2(H2O)2]-H2O with hydrogen bonds, three-dimensional coordination polymer {[Cd(C5H6NCOO)2H2O]-DMF}n, which are indirectly obtained from the precursor ligand L3 through metal ion induced the hydrolysis of diamide and self-assembled with the hydrolyzate.

我们首次合成了一个双吡啶鎓超分子化合物和六个过渡金属配合物，并通过IR谱，元素分析和X-ray晶体衍射分析对它们进行了表征。X-ray晶体结构分析表明：超分子化合物[H_2L1·(NO_3)_2·(H_2O)_2]_n是由多种氢键和芳香环间的π-π堆积作用构建的三维无限结构；[HgI_2(L1)·1.5CH_3OH]_n是一维锯齿状配位聚合物；(HgI_2L2)_2·3H_2O是双核金属大环化合物；[Co_2(L2)_2·2CH_3OH]_n是具有一维双螺旋结构的配位聚合物；[Co_2(L3)_2·CH_3OH·CH_3CN]_n为一维双链结构的配位聚合物；以及由非直线形配体L3在金属离子Cu和Cd的诱导作用下发生水解，并且金属离子与水解产物——异烟酸根离子自组装，形成了三维氢键超分子化合物[Cu(C_5H_4NCOO)_2(H_2O)_2]·H_2O和三维配位聚合物{[Cd(C_5H_6NCOO)_2H_2O]·DMF}_n。

Benzoxazine compounds are one kind of highly active protoporhyrinogen oxidase inhibitors. These compounds can effectively control both monocotyledon weeds and dicotyledon weeds at lower dosage. The action mechanism is similar to p-nitro-o-substituted diphenylethers. They can result weeds albinism and decolorization, which are very important albinism herbicide.

苯并噁嗪类化合物是一类高活性的原卟啉原氧化酶抑制剂，低剂量可有效地防除禾本科与阔叶杂草，其作用机理和对硝基邻位取代的二苯醚类似，它们造成白化或脱色，是白化除草剂中较重要的种类，其活性远超过二苯醚除草剂，是目前化学农药研究领域的热点。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。