查询词典 compound crystal

According to the study on solidification behavior of YBaCuO compound, laser floating zone melting technology is developed to grow YBaCuO superconducting crystals, and the microstructure and superconductivity of the crystal have been discussed.

根据对YBaCuO化合物凝固行为的研究，发展了一种用激光浮区熔化法生长YBaCuO晶体的新工艺，並对用此法制备的超导体的组织与性能进行了分析。

SR-B, a colorless crystal antimicrobic compound, was extracted and purified from broth of marine actinomycete N331 isolated and screened from sea mud. Its molecular structure was characterized by MS and various NMR spectra.

从分离筛选的海洋放线菌N331的发酵液中分离、纯化得到一种无色结晶抗菌化合物SR-B，通过对其质谱、多种核磁共振谱的结构信息进行分析，鉴定其分子结构。

The known titanoheterocyclic compound〓 was synthesized in high yield by a new route involving an oxidative addition reaction of "titanocene"with benzil, and its structure was first confirmed by a single crystal X-ray diffraction method.

首次由&二茂钛&与二苯乙二酮的氧化加成反应，高产率地合成了一个已知的高价钛杂环化合物〓，并首次用X-射线衍射法测得该化合物的单晶分子结构。

Bipyridyl and 1,10-phenanthroline (L3), Cl3SnCH2CH2COORo L (L= L1, a; L2, b; L3, c), formed by low-heating solid-state reaction. The crystal structures of 1 and 2 show that the tin atom adopts a distorted trigonal bipyramid geometry via intramolecular carbonyl oxygen to tin coordination [the distances of Sn-0 bond are 0.2351(6) ran for 1 and 0.2362(3) nm for 2]. Compound 1 belongs to monoclinic with space group P2/c, a = 0.9842(2) nm, b =1. 0923(8) nm, c = 1.23948(11) nm,/?= 93.894(15)°, V= 1.3294(4) ran3, Mr = 366.23, 7 = 4. Compound2 belongs to monoclinic with space group P2{/c, a = 1.04443(9) nm, b = 1.04823(7) nm, c = 1.28113(9) nm,/= 90. 953(8)°, V= 1.40239(19) nm3, Mr = 380.25, Z = 4

利用元素分析、红外光谱、核磁共振对其结构进行了表征，并通过X射线单晶衍射测定了1和2的晶体结构，二者均为具有分子内羰基氧原子配位的畸变三角双锥结构。1属于单斜品系，空间群P21/c， a=0.9842(2)nm，b=1.0923(8)nm，c=1.23948(11)nm，β=93.894(15)°，V=1.3294(4) nm^3，Mr=366.23，Z=4.2属于单斜晶系，空间群P21/c，a=1.04443(9)nm，b=1.04823 (7)nm，c=1.28113(9)nm，β=90.953(8)°，V=1.40239(19)nm^3，Mr=380.25，Z=4。

In the crystal, the tin atoms are five-coordinated in trigonal bipyramidal structure by bridging pyridine N atoms, resulting in the chain organotin compound.

该化合物中心锡原子为五配位三角双锥构型，并且通过4-吡啶甲酸配体的氮原子桥联作用形成一维无限链状结构。

The crystal belongs to monoiclinic with space group P2 1/n, a=1.7073(7)nm, b=1.7447(7)nm, c=2.4333(10)nm,β=109.694(7)°, Z=4,V=6.824(5)nm 3, D x=1.282g/cm 3,μ=0.793mm -1, F(000)=2696, R 1=0.0563, WR 2=0.1539. In the crystals of compound, the tin atoms rendered seven-coordinate in a distorted pengonal bipyramidal structure.

我们以 NEt3 作缚酸剂，用 Ph3 Sn Cl与 2 ，6 -吡啶二甲酸以 1∶ 1摩尔比反应时，没有得到预期产物 Ph3 Sn O2 C(2 ，6 - Py)CO2 H ，而是得到一种 Sn- Ph键断裂的离子型有机锡化合物(Scheme1 )。

The title compound was colorless crystal synthesized via the reaction of 4, 4'-bipyridine and HgI2 in the mixtured solution of methanol and tetrahydrofuran.

标题化合物是双齿配体4，4'-联吡啶与碘化汞在甲醇和四氢吨位呋喃混合溶液中反应得到的无色晶体。

The results show that the technical parameters and the concentration of sodium molybdate have obvious effect on the composition of the alloy. The crystal grain size is from 6.2 to 12.7 nm and changes with current density, temperature and the pH value of the electrolyte.The crystalline growth of the alloy accords with the model of three-dimensional growth. The surface morphology is mainly determined by the rate competitions between the growing direction of vertical surface and the expanding direction along the surface towards circumambient. The results of the X-ray data show the presence of the multiphase containing solid solution and intermetallic compound in the deposits. The deposit phases alter from the FeNi and FeMo solid solution to the FeNi and MoNi4structure at 3 A/dm2. The deposits internal stress increases linearly with the decrease of the grain size. The lattice parameter of the deposits are slightly distorted

结果表明：工艺条件和钼酸钠浓度对合金组成的影响较大；所得合金晶粒尺寸为6.2~12.7 nm，并随电流密度、温度和电镀液的pH值的改变而变化；合金的晶体生长符合晶核三维生长模型，镀层表面形貌由平行和垂直于基体的生长速度的相对大小决定；镀层物相为固溶体和金属间化合物的多相结构，当电流密度为3 A/dm2时，镀层物相由FeNi和FeMo固溶相转化为FeNi和

A new organic compound, trans-2--5-dimesitylborylthiophene (abbreviated as DMASBT, 5) with dimesitylboryl, dimethylamino and styryl-thiophene as electron acceptor, electron donor and conjugate bridge respectively, was synthesized. Its crystal structure determined by X-ray diffraction method indicates that the B-C bond between B atom and it bridge is obviously shorter than those of between B atom and mesityl groups. This remarkably strengthened B-C bonding can be regarded as an evidence of additional p-7t conjugation between the B atom and n bridge.

合成了以含硼基团为电子受体，以二甲胺基为电子给体，以苯乙烯基噻吩为共轭桥的新化合物2-[（4'-N，N-二甲胺基）苯乙烯基]-5-二米基硼-噻吩 trans-2-[(4'-N， N-dimethylamino) styryl]-5-dimesitylboryl-thiophene（简写为DMASBT，5）。X射线衍射方法测定其单晶结构表明，硼原子与π共轭桥之间的硼碳键相对于其它的硼碳键明显缩短，硼与π共轭桥之间存在除了σ键之外的p-π共轭作用。

N719 makes the sensitizer by the star dye dipyridyl ruthenium complex compound, Has successfully assembled the dye sensitization unidimensional ZnO nanometer crystal solar battery prototype component.

以明星染料联吡啶钌络合物（N719）做敏化剂，成功地组装了染料敏化的一维ZnO纳米晶光电池原型器件。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。