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The present dissertation deals with:(1) Exploring the feasibility of the CO〓 methanation and the conversion CH〓/H〓 into C〓 hydrocarbons under plasma with catalyst at ambient temperature and atmosphere.(2) Designing a reactor and preparing some catalysts suited for the conversion of carbon dioxide via the cooperation effect of plasma and catalysts.(3) Optimizing reaction conditions of conversion carbon dioxide to C〓 hydrocarbons in the proposed process.(4) Studying the reaction mechanism of conversion carbon dioxide to C〓 hydrocarbons under plasma by using in situ OES technology.(5) By the results of characterizing coked catalysts, exploring the reasons that result in the coking of catalyst and the paths for decreasing the deposit in the catalyst under plasma.(6) Analyzing the energy efficiency of the plasma catalysis and exploring the paths for improving the energy efficiency.

论文的主要研究工作包括:(1)探索脉冲电晕等离子体与催化剂共同作用CO〓/H〓甲烷化和由CH〓/H〓合成C〓烃反应的可行性;(2)研制等离子体催化CO〓转化的反应器和适配的催化剂;(3)优化等离子体催化CO〓转化制C〓烃反应的工艺条件和电参数;(4)利用原子发射光谱原位技术对等离子体反应的诊断结果,对等离子体催化CO〓转化制C〓烃反应的机理进行推断;(5)通过对积碳催化剂的表征结果,分析积碳的类型及其成因,并探讨减少积碳的途径;(6)通过对等离子体催化CO〓转化制C〓烃反应能量效率的分析,探讨提高等离子体催化反应能量效率的途径。

The coking and deactivation process of benzene and ethylene alkylation reaction over AB-97 zeolite has been studied systematically. The results of acceleration deactivation reaction indicate that deactivation process go through three phases, high level activity stability period, activity decline period and low level activity stability period. The mechanism of this phenomenon was analyzed by the way of the experiment research of pore structure and acid quality of coked zeolite. It is concluded that reducing the strong acid active centers and crystal outer-surface active centers are benefit to improve the activity stability of zeolite.

在AB-97型分子筛催化剂上对苯/乙烯烷基化制乙苯反应体系的结焦失活历程系统实验研究,催速失活实验结果表明失活历程经历高水平活性稳定期,活性衰退期和低水平活性稳定期三个阶段,并通过对失活催化剂的孔结构及酸性质的实验研究,对这一现象进行了机理分析,认为催化剂改性研究中采用降低强酸活性位和晶粒表面活性位这两种手段都有利于改善催化剂的活性稳定性。

A preparation method of the visible-light photocatalyst Bi2WO6 nano-powder is characterized by comprising the steps as follows:(1) the selection of raw materials;(2) bismuth nitrate Bi(NO33 question mark 5H2O is added into a citric acid solution to obtain the citric acid solution containing white sediment;(3) EDTA is added into ammonia water which is then added dropwise with the citric acid solution containing the Bi(NO3)3 question mark 5H2O so to obtain a solution of bismuth;(4) the solution of bismuth is added with (NH4)6W7O24 question mark 6H2O solution to form a precursor solution which is then stirred, dried, coked, cooled and ground to obtain decarburized powder;(5) the decarburized powder is roasted for 2h to 4h under 450 DEG C to 550 DEG C to obtain the visible-light photocatalyst Bi2WO6 nano-powder.

可见光催化剂Bi 2 WO 6 纳米粉体的制备方法,其特征在于它包括如下步骤:1原料的选取;2将Bi(NO 3 ) 3 5H 2 O加到柠檬酸溶液中,得到含有白色沉淀的柠檬酸溶液;3将乙二胺四乙酸加到氨水中,并缓慢滴加入含有Bi(NO 3 ) 3 5H 2 O的柠檬酸溶液中,得铋的溶液;4将(NH 4 ) 6 W 7 O 24 6H 2 O溶液加入上述铋的溶液中,组成前驱液;搅拌,干燥,焦化,冷却后,研磨,得去碳的粉体;5将去碳的粉体在450~550℃下焙烧2~4h后,得到可见光催化剂Bi 2 WO 6 纳米粉体。

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It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发,分析对称连杆曲线上鲍尔点的产生条件,提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品,年生产总值3000万美元,产品价廉物美、选料上乘、质量保证,深受国内外客户的青睐

The eˉtiology of hemospermia is complicate,but almost of hemospermia are benign.

血精的原因很,以良性病变为主。