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The phase transition temperature increases and the transition ranges tends to be broad when PNIPA brushes were substituted with P or P(NIPA-co-NVP) brushes obtained by the copolymerization of NIPA with AA and NVP, respectively. However, the phase transition is not obvious if adding excessive hydrophilic comonomer.

结果表明,纯PNIPA刷的相变温度在29℃~33℃之间,通过共聚所得的单一P或P(NIPA-co-NVP)刷均使相转变温度提高,转变区域拓宽,当亲水性共单体的量过多时会导致相变过程不明显。

The metalloproteins which are widely distributed in vivo are very important target molecules of NO. A new Y/〓 reaction system which can form Y-NO bond has been established and has been used to measure the NO affinity of metalloporphyrins as metalloprotein models. Three kind of bond energies of the Co-NO bonds in series of cobalt nitrosyl tetraphenylporphyrins have been determined by thermodynamic cycles combined with calorimetric measurements and relevant electrochemical data.

本文以金属卟啉模拟体内重要的NO靶分子金属蛋白,通过确立新的适于量热和电化学测定的Y/〓成Y-NO键反应体系,利用合适的热力学循环,建立了新的适于金属卟啉体系的NO亲合势的测定方法,得到了苯腈中系列亚硝基四苯基钴卟啉Co-NO键的键能,即钴卟啉NO亲合势的定量标度,以表征钴卟啉的NO结合能力。

Three kind of bond energies of the Co-NO bonds in series of cobalt nitrosyl tetraphenylporphyrins have been determined by thermodynamic cycles combined with calorimetric measurements and relevant electrochemical data.

本文以金属卟啉模拟体内重要的NO靶分子金属蛋白,通过确立新的适于量热和电化学测定的Y/〓成Y-NO键反应体系,利用合适的热力学循环,建立了新的适于金属卟啉体系的NO亲合势的测定方法,得到了苯腈中系列亚硝基四苯基钴卟啉Co-NO键的键能,即钴卟啉NO亲合势的定量标度,以表征钴卟啉的NO结合能力。

As inexpensive and relatively nontoxic metals, Fe and Co are ideal elements for the development of catalysts.

作为廉价而且低毒的金属,Fe和Co是发展催化剂的理想元素。

Cu and Co ions are coordintated with six oxygen atoms from two water molecules and four ligands to form an octahedral geometry. Each ligand links two metal ions in a μ2-bridge coordination mode and two-dimensional wavelike structures are formed.

Cu和Co均为六配位,八面体构型,每个金属离子与4个配体和2个水分子配位,每个配体采取μ2-桥联模式,形成二维层状结构。

In most of cobalt coordination polymers, Co ions are six-coordinated in an octahedral symmetry, whereas five-coordinated ones are seldom.

在大多数的钴配位聚合物中,Co离子是六配位八面体对称性,然而五配位的很少。

Co ion is six?coordinated to form a distorted octahedron.

配合物中Co离子是六配位变形八面体结构。

The results showed that indoor air pollution by CO,NOx,and TSP washeavy in olb darracks with coal stoves in winter,but SO2 concentration was within standard in winter and summet.

结果表明,三市上述六项指标夏季大多在标准以内;冬季CO、NOx、CO_2、总悬浮颗粒物均超过标准,苯并芘冬季高于夏季,室内高于室外,旧营房高于新营房;以沈阳大气质量指数评价夏季哈尔滨新营房属"清洁",余为轻污染,冬季哈尔滨新营房为轻污染,其余新营房为中污染,长春与锦西旧营房为极重污染。

Thecompound 2-1 can also react with CO and DPPB to give osmium vinyl compound 2-4and 2-5,respectively.

这可以看做是[4+1]环化法在合成金属呋喃方面的应用。2-1与CO以及DPPBPh_2P(CH_2_4PPh_2反应分别得到锇乙烯基化合物2-4和2-5。

The result shows that Co and Cu are associated with exchangeable fractions, which represents stonger mobility;Pb in iron-manganese fraction represents stonger potential mobility;Zn and Cr existed in oxidizable and residual fraction and Ni in residues represents weak mobility or immobility.

研究结果表明:Co、Cu、Mn存在可交换态,表现有相对较强的迁移性和生物可利用性;Pb主要以还原态的形式存在,表明具有较强的潜在危害性;Zn、Cr主要以氧化态和残渣态形式存在,Ni主要以残渣态的形式存在,这些元素的迁移性较弱。

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