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A novel polymer of Poly(diglycidyl maleate-co-stearyl methacrylate) was synthesized and its structure was characterized by ~1H NMR. Its self-assembly behavior was studied in different solvents. It was found that vesicles and tubule-liked aggregates can be obtained through self-assembly of P(DGMA-co-SMA)/THF/EtOH system. And spheral aggregates were obtained in P(DGMA-co-SMA)/THF/H_2O system while the spheral aggregates were converted into rod-liked aggregates and line-liked aggregates after aged for different time.

合成了带含环氧基侧链和十八烷基侧链的聚(马来酸二缩水甘油酯-co-甲基丙烯酸十八酯),用~1H NMR对所得的共聚物进行了表征;研究了其在选择性溶剂中的自组装行为,发现P(DGMA-co-SMA)/THF/EtOH体系可以通过自组装形成囊泡形自组装体和支化的管状自组装体,P(DGMA-co-SMA)/THF/H_2O体系最初自组装形成球形自组装体,随着陈化时间的延长,球形自组装体逐渐融合成长条形自组装体和线形自组装体;探讨了自组装过程的机理,建立了可能的自组装过程模型。

The presence of BaO affected the TPR performance of Co/SiO2, and Ba loading of 2% increased the reduction degree of Co/SiO2 at the moderate temperature (450℃). The difference of the TPR performance between unpromoted and promoted catalyst samples could be ascribed to the induction of the reduction of BaO, and the interactions between barium oxide and silica, barium oxide and cobalt oxide.

研究结果表明,氧化钡明显地影响Co/SiO2的还原性能;添加2%氧化钡提高了Co/SiO2在中温(450℃)条件下的还原度;氧化钡的还原对Co/SiO2还原的诱导、氧化钡与氧化硅及与氧化钴之间的相互作用是导致Co/SiO2还原性能变化的原因。

We have epitaxially grown ultrathin Pb and Co films on the Cu(111)surface bymolecular beam exitaxialgrowth technique,and studied in detail the growthand surface alloying of submonolayer Pb on Cu(111),the shift of Pb 5d core levelbinding energy on Cu(111),the surfactant-assisted epitaxial growth of Co on Cu(111)using Pb as a surfactant,and the spin exchange splitting of ultrathin Co films onCu(111)using synchron radiation photoemission spectra as well as Auger electronspectraand low energy electron diffraction.

利用分子束外延生长技术在单晶Cu(111)表面外延生长了超薄Pb和Co膜,并利用同步辐射光电子发射谱,结合俄歇谱和低能电子衍射,详细研究了超薄Pb在Cu(111)表面的生长、表面合金化,Cu(111)表面Pb的5d芯能级位移,以Pb作活性剂时Co膜的活化外延生长,以及超薄Co在Cu(111)表面的自旋交换劈裂,得到了一些有意义的结果。

The present dissertation deals with:(1) Exploring the feasibility of the CO〓 methanation and the conversion CH〓/H〓 into C〓 hydrocarbons under plasma with catalyst at ambient temperature and atmosphere.(2) Designing a reactor and preparing some catalysts suited for the conversion of carbon dioxide via the cooperation effect of plasma and catalysts.(3) Optimizing reaction conditions of conversion carbon dioxide to C〓 hydrocarbons in the proposed process.(4) Studying the reaction mechanism of conversion carbon dioxide to C〓 hydrocarbons under plasma by using in situ OES technology.(5) By the results of characterizing coked catalysts, exploring the reasons that result in the coking of catalyst and the paths for decreasing the deposit in the catalyst under plasma.(6) Analyzing the energy efficiency of the plasma catalysis and exploring the paths for improving the energy efficiency.

论文的主要研究工作包括:(1)探索脉冲电晕等离子体与催化剂共同作用CO〓/H〓甲烷化和由CH〓/H〓合成C〓烃反应的可行性;(2)研制等离子体催化CO〓转化的反应器和适配的催化剂;(3)优化等离子体催化CO〓转化制C〓烃反应的工艺条件和电参数;(4)利用原子发射光谱原位技术对等离子体反应的诊断结果,对等离子体催化CO〓转化制C〓烃反应的机理进行推断;(5)通过对积碳催化剂的表征结果,分析积碳的类型及其成因,并探讨减少积碳的途径;(6)通过对等离子体催化CO〓转化制C〓烃反应能量效率的分析,探讨提高等离子体催化反应能量效率的途径。

In order to study the reaction kinetics of uranium with CO or CO 2,uranium samples of different forms are obturated in reaction vessels and then CO or CO 2 is filled in. Gases in vessels are analyzed at different storage time.

在一定温度下,将不同形态的铀样品密闭贮存在容器中并充入一定压力的高纯CO或CO2 气体,通过定期测量贮存容器中气体组成,初步研究了铀与CO或CO2 的反应动力学。

To culture antibiotic overproducing strains, the study include using different physical and chemical factors to induce Streptomyces thermocarbonxydus var shandaensis to mutation. After original strain were mutagensised by UV combined LiCl、~(60)Co、 DES, 9 high-yield strains were obtained.

通过紫外线加氯化锂复合诱变得到高产菌株UV—18、UV—19、UV—20,其中菌株UV—19的发酵上清液抑菌圈直径是原种的1.875倍;通过~(60)Co诱变得到高产菌株Co—22、Co—36、Co—38,其中菌株Co—38的发酵上清液抑菌圈直径是原种的1.68倍;通过硫酸二乙酯诱变得到高产菌株DES—21、DES—31、DES—37,其中菌株DES—21的发酵上清液是原种的1.52倍。

Better agreement between metallic Pd~n-CO clusters and CO/Pd chemisorption systems demonstrates that the "Metallic State Principle" overweighs the "Lowest Spin State Principle".

总的计算结果表明,依据金属态原则,其结果可以更好地符合CO/Pd吸附体系的实验数据,并认为CO/Pd吸附过程的成键作用主要是CO(5σ)→Pd(5sp)与Pd(5sp)→CO(2π^*)的σ/π授受作用。

A process for partial conversion and low-temp transform of CO in the synthetic ammonia plant where coal is used to generate gas features that the Fe-Mo catalyst for partial conversion of CO, anti-poisoning agent and Co-Mo catalyst for low-temp conversion are used and the temp of semi-water gas is controlled to 200-260 deg.C at entering anti-poisoning layer, and 150-250 deg.C at the segments of said Co-Mo catalyst layer, and lower than 300 deg.C at bed layer to prevent high-temp reversal of sulfurizing reaction and make the catalyst activity optimal. Its advantages are long service life of catalyst, low system resistance, saving energy and convenient operation.

本发明是中小合成氨厂以一种CO部分转化抗毒保护层配低温变换的工艺,涉及煤造气合成氨厂0.6~2.0MPa半水煤气变换工艺流程,该工艺用铁-钼CO部分转化催化剂、抗毒剂,配钴-钼低变催化剂,半水煤气进入部分转化抗毒层温度为200~260℃,进钴-钼低变催化剂各段温度为150~250℃,床层温度控制在300℃以内,避免高温下反硫化反应发生,保护催化剂活性处最佳状态,寿命延长、系统阻力小、节汽、节电,具有比其他变换工艺更好地节能效果,操作方便,有效生产时间长,经济效益显著等特点。

The performance grades in balance beam of B6-Co normal mice, B6-Co single eyed ones and B6-Co double-eyed ones were decreased sequentially, and were negatively correlated with the degrees of cornea lesion.

平衡木的成绩得分:B6-Co表型正常小鼠3.50±0.69、B6-Co单眼小鼠2.17±0.78、B6-Co双眼小鼠1.87±0.80依次降低,且与角膜病变的程度呈负相关。

According to the experimental results the reaction mechanism of gasification is proposed: firstly, the catalyst releases an oxygen atom from its rich-oxygen site to combine with a carbon atom and create a CO, then the CO molecule desorbs from the catalyst surface; next, the catalyst absorbs a CO2 molecule; and finally on the catalyst surface another CO molecule is created and the original rich-oxygen site gets an oxygen atom. On the basis of gasification process the material balance equations were built, which were solved by using numerrical integral methods and the reaction rate constants for four steps were obtained: they are 0.0703mol·g-1·min-1·kPa-1, 0.0959mol·g-1·min-1·kPa-1, 0.00539 mol·g-1·min-1 and 0.0321 mol·g-1·min-1·kPa-1 respectively.

根据实验结果推导得出了该反应过程是催化剂表面富氧活性部位先与煤焦反应生成一个CO分子,然后此CO分子从催化剂表面脱附,接着催化剂吸附气态的CO2生成一个CO并且夺得一个氧原子实现自身还原的过程,在此基础上建立了煤的催化气化的物料平衡方程组,对各步骤的反应速率常数进行了求解,在本文采用的实验条件下,各反应步骤的反应速率常数分别为0.0703 mol·g-1·min-1·kPa-1;0.0959 mol·g-1·min-1·kPa-1;0.00539 mol·g-1·min-1·kPa-1; 0.0321mol·g-1·min-1·kPa-1。

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