查询词典 cis

Keywords: Organozinc reagents; cis-Addition Products; Ring-expansion; Chain-extension

中文关键词：有机锌试剂；环氧的顺式开环；酮酯的扩环；碳链增长

Organozinc reagents; cis-Addition Products; Ring-expansion; Chain-extension

中文主题词：有机锌试剂；环氧的顺式开环；酮酯的扩环；碳链增长

ObjectiveTo investigate the effect of allactin at different concentrations on reduction of the side reaction resulting from cis-platinum during ovarial cancer treatment.

目的观察不同浓度大蒜素对卵巢癌化疗中顺铂副反应的影响。

Oxalyl fluoride neutral molecule ; trans-configuration ; cis-configuration ; density function theory; stability ; frequency analysis

草酰氟分子；平面反式构型；顺式构型；密度泛函；稳定性；频率分析

Finally, the cytotoxic and antibacterial activities of the oxamido-bridged binuclear complexes were studied in vitro.. This dissertation consists of three sections as follows:1. The crystal structure of a oxamide dinitrate,(1) [H_4dmaeoxd](NO_3)_2 H_2dmaeoxd = N,N\'-bis[2-ethyloxamide, has been obtained. The diversity of complexes with different structures is carried out by successful synthetic strategy of controlling species of metal ions, counter anions, pH values and solvents in the course of synthesis. Four dinuclear complexes bridged by trans-dmaeoxd2-: [Cu_2_2](ClO_4)_2 (2), [Cu_2_2](ClO_4)_2 (3),、[Cu_2(Me_2phen)_2](ClO_4)_2 (4), [Cu_2_2(H_2O)_2] (5); Four dinuclear complexes bridged by cis-dmaeoxd2-: [NiNi_2](ClO_4)_2 (6), [CuNi_2](ClO_4)_2·2CH_3OH (7), [CuZn_2]-(ClO_4)_2·2H_2O (8), [Cu(H_2O)Ni_2](ClO_4)_2.0.5CH_3OH (9); three 1-D polynuclear complexes: [Cu_2]_n·nH_2O (10), [Cu_2(H_2O)_2-]_n·4nH_2O (11), [Cu_2(H_2O)]_n(NO_3)_n·2nH_2O (12); one 2-D polynuclear complex,[Cu_6_3(μ_3-OH)_2(H_2O)_2]_n(ClO_4)_(4n).2nH_2O (13); the others: [VO(H_2O)]·2H_2O (14), [Zn_2_4](ClO_4)_2·H_2O (15), [Cu_2]·2DCM (16) have been synthesized and characterized by X-ray single crystal diffraction, elemental analysis, IR spectra.

本论文主要包括以下三部分：一、合成得到了一个草酰胺配体硝酸盐的单晶结构，[H_4dmaeoxd](NO_3)_2 (1)；通过调控金属离子的种类、端基配体、抗衡阴离子、溶剂、pH值等条件定向合成了四个反式草酰胺桥联双核铜配合物：[Cu_2_2](ClO_4)_2 (2)、[Cu_2_2](ClO_4)_2 (3)、、[Cu_2(Me_2phen)_2](ClO_4)_2 (4)、[Cu_2_2(H_2O)_2] (5)；四个顺式草酰胺桥联同/异双核配合物：[NiNi_2](ClO_4)_2 (6)、[CuNi_2](ClO_4)_2·2CH_3OH (7)、[CuZn_2]-(ClO_4)_2·2H_2O (8)、[Cu(H_2O)Ni_2](ClO_4)_2.0.5CH_3OH (9)；三个一维聚合物： [Cu_2]_n·nH_2O (10)、[Cu_2(H_2O)_2-]_n·4nH_2O (11)、[Cu_2(H_2O)]_n(NO_3)_n·2nH_2O (12)；一个二维聚合物： [Cu_6_3(μ_3-OH)_2(H_2O)_2]_n(ClO_4)_(4n)。2nH_2O (13)；单核钒配合物[VO(H_2O)]·2H_2O (14)、草酸根桥联双核锌配合物[Zn_2_4](ClO_4)_2·H_2O (15)、美洛西康铜配合物[Cu_2]·2DCM (16)，利用元素分析、摩尔电导、红外光谱、电子光谱和单晶X-射线衍射对上述所得化合物进行了结构表征，探讨了结构影响因素，并研究了其超分子结构。

Cis dichloroamine (4 amino 2,2,6,6 tetramethylpiperidine 1 oxyl) platinum(abbreviated to HJ5) is a novel platinum anticancer compound which has prospects for research and application.

顺 二氯一氨(4 氨基 2 ，2 ，6 ，6 四甲基哌啶 1 氧自由基)合铂(简称HJ5 )是一种有研究与应用前景的新型铂抗癌配合物。

Chitosan had been modified by polyacrylate sodium, glularaldehyde, and NaBH4, respectively, which afforded three kinds modified chitosan: polyacrylate sodium modified chitosan (CIS- PA4) chitosan bead and pentamethylene diamido crosslinked chitosan bead (CTSB- G- Hy). The adsorption properties of CTS-CTSB and CTSB-G-Hy were studied by L25(56) orthogonal experimental design. They show high adsorption activities for Pb2+ in solution. The highest removal efficiency of Pb2+ for CTS-PA4, CTSB and CTSB-G-Hy is 94%, 96% and 93%, respectively. The results showed the adsorption property of CTSB is the highest. The CTSB- G- Hy has good mechanical property, acid-resistance and alkali-resistance.

第二部分壳聚糖的改性及其对水溶液中铅离子的吸附性能研究以壳聚糖为原料制备了三种改性吸附剂——聚丙烯酸钠改性壳聚糖(CTS——PA_4)、珠状壳聚糖凝胶树脂和戊二氨交联珠状壳聚糖凝胶树脂，着重考察了CTSB—G—Hy的制备条件，并考察了三种吸附剂吸附6.3mg/L铅离子水溶液中铅的最佳使用条件，结果表明对CTS—PA_4而言当pb~(2+)溶液的pH在4～6.5之间，吸附剂用量为5g/L，吸附时间为1h时pb~(2+)去除率高于94％，CTS—PA_4可在酸性条件下使用，在碱性条件下依然有效但处理效果较差；CTSB对pb~(2+)具有很好的吸附能力吸附剂用量为5g/L，吸附时间为1h时处理效果极佳，pb~(2+)去除率高于96％；CTSB—G—Hy对pb~(2+)具有一定的吸附能力，吸附剂用量为3g/L，吸附时间为1.5h时处理效果最佳，Pb~(2+)去除率高于93％，而且CTSB—G—Hy的机械强度高，耐酸碱性强，可在较宽的pH范围内使用。

Cis-1-Propenyl phosphonic acid is the key intermediate in the synthesis of phosphonomycin, a new broad antibacterial drug.

顺丙烯膦酸是新型广谱抗菌药磷霉素合成的关键中间体。

In the presence of different sensitizers, we measured the rate of photoisomerization of t-stilbene to cis-stilbene as a method for evaluating the efficiency of these compounds.

本文还测定了存在不同敏化剂时，芪的顺、反异构化反应速度，以此评价化合物的敏化效率。

The population relaxation dynamics and cis/trans photoisomerization process were carefully examined by the isotropic transient study.

藉由分析等方向性的瞬时行为及瞬时光谱的演变过程，我们得知各异构物分子在激发态的能量弛豫及顺-反异构化的过程。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。