查询词典 cinchonine

The thermodynamic parameters in the separation of enantiomers of amino acid derivatives and diastereomers of cinchona alkaloids were calculated and the dissociation constants of cinchonine and cinchonidine on the cinchonine imprinted monolithic disk were determined by frontal analysis.

计算了氨基酸衍生物对映体以及辛可纳非对映异构体分离过程的热力学参数并利用前沿色谱法测定了辛可宁和辛可尼丁在盘状分子印迹整体柱上的离解平衡常数。

A rapid separation of cinchonine and cinchonidine was obtained under optimizing conditions.

通过对分离条件的优化实现了辛可宁和辛可尼丁的快速分离。

As the retention times of cinchonine and cinchonidine were decreased with the increase of voltage, applied pressure and temperature, a rapid separation of cinchonine and cinchonidine can be obtained within 2 min under optimized conditions.

通过对上述条件的优化，可以在2 min内完成辛可宁和辛可尼丁的快速分离。

Diastereomers of cinchonine and cinchonidine were separated in pressure-assisted capillary electrochromatography mode, and the resulted separation efficiency was much higher than that obtained in high performance liquid chromatography.

采用压力辅助电色谱模式拆分了非对映异构体辛可宁和辛可尼丁，其柱效远高于其在HPLC中拆分的结果。

A new chiral quaternary ammonium sails prepared from cinchonine was designed and synthesized.

本课题设计并合成了一种新的辛可宁型手性季铵盐。

The three new adsorbents were prepared with alkoids cinchonine、quinine and theophylline loaded on cation exchange resin respectively.

以阳离子交换树脂为支撑体，分别以生物碱辛可宁、奎宁、茶碱为衍生化试剂，合成了三种新吸附材料。

Acording to the literature, we improved the yield of N- [4- benzy] cinchoninum bromide from cinchonine.

对光学活性的相转移催化剂N-4-碘苄基辛可宁溴酸盐的进行了改良合成。

A new cinchonine ion selective electrode was prepared by dipping the Ag/AgCl electrode into the sol-gel solution for more than 3 times, and then standing for 48h at room temperature, and finally activating for at least 12h in a 1.0×10^(-2)molL^(-1) cinchonine solution.

将Ag/AgCl电极于溶胶－凝胶溶液中反复浸3次以上，在室温静置48h后在1.0×10^(-2)molL^(-1)，辛可宁溶液中活化至少12h即制成新型的辛可宁选择性电极。

ESI-MS results showed that α-CD could form 3: 1 specific complex with cinchonine in solution and they formed"sandwich"structure type 〓 inclusion complex when β-and γ-CD were blended simultaneously with cinchonine. Semi-empirical AM1 calculations indicated that the H bonds formed between CD and cinchonine played an important role to stabilize the complex in gas phase.

电喷雾质谱研究发现α-CD与辛可宁在溶液中可以形成特异性的3：1型复合物，当β，γ-CD与辛可宁同时混合时它们可以形成"三明治"型〓包合复合物，半经验AM1方法计算显示氢键的形成对这些复合物的稳定起到重要的作用。

Amino(9-deoxy)epi cinchonine was synthesized from cinchonine through the Mitsunobu reaction and was treated with p-toluenesulfonyl chloride,4-chlorobenzene sulfonyl chloride respectively to give two new chiral sulfonamides.

以辛可宁为原料，经Mitsunobu反应合成了9-氨基(9-脱氧)表辛可宁，然后分别与对甲苯磺酰氯、对氯苯磺酰氯反应，合成了两个新手性磺酰胺，其结构经红外光谱和核磁共振确证。

Plunder melds and run with this jewel!

掠夺melds和运行与此宝石！

My dream is to be a crazy growing tree and extend at the edge between the city and the forest.

此刻，也许正是在通往天国的路上，我体验着这白色的晕旋。