查询词典 cinchonidine

The thermodynamic parameters in the separation of enantiomers of amino acid derivatives and diastereomers of cinchona alkaloids were calculated and the dissociation constants of cinchonine and cinchonidine on the cinchonine imprinted monolithic disk were determined by frontal analysis.

计算了氨基酸衍生物对映体以及辛可纳非对映异构体分离过程的热力学参数并利用前沿色谱法测定了辛可宁和辛可尼丁在盘状分子印迹整体柱上的离解平衡常数。

A rapid separation of cinchonine and cinchonidine was obtained under optimizing conditions.

通过对分离条件的优化实现了辛可宁和辛可尼丁的快速分离。

As the retention times of cinchonine and cinchonidine were decreased with the increase of voltage, applied pressure and temperature, a rapid separation of cinchonine and cinchonidine can be obtained within 2 min under optimized conditions.

通过对上述条件的优化，可以在2 min内完成辛可宁和辛可尼丁的快速分离。

Molecular mechanics on the Pt surface showed that there may be an efficientchiral potential around the adsorbed cinchonidine that selects the enantioface of methylpyruvate and determines the enantiodifferentiation in this system.

该反应在传统负载铂催化剂上表现出的结构敏感性可能与金属和载体之间的强相互作用有关。

The Pt/FDU-14 catalysts can be effectively applied in the asymmetric hydrogenation of ethyl pyruvate after chirally modified with cinchonidine.

考察了经过手性分子辛可尼定修饰后的Pt/FDU-14催化剂在丙酮酸乙酯不对称氢化反应中的催化性能。

Diastereomers of cinchonine and cinchonidine were separated in pressure-assisted capillary electrochromatography mode, and the resulted separation efficiency was much higher than that obtained in high performance liquid chromatography.

采用压力辅助电色谱模式拆分了非对映异构体辛可宁和辛可尼丁，其柱效远高于其在HPLC中拆分的结果。

In the asymmetric hydrogenation of ethyl pyruvate catalyzed by 0 5% Rh/PVP TiO 2, the chiral modifier cinchonidine not only induces the enantioselectivity, but also accelerates the reaction rate greatly.

研究了辛可尼定作手性修饰剂修饰的负载型纳米铑簇合物催化剂(0 5 %Rh/PVP TiO2 )催化丙酮酸乙酯不对称氢化反应，在该反应中手性修饰剂辛可尼定不仅具有对产物生成的手性诱导作用，而且对反应具有明显加速作用；在优化反应条件后，反应的TOF和对映选择性分别可以达到 5 8 0min-1和

The highest e.e. formethyl lactate, 97.6%, was achieved on a 1.4 nm PVP-Pt modified with cinchonidine under298K, 4.0MPa, in acetic acid.

PVP-Pt在负载于〓上以后仍表现出不同于传统催化剂的特性，即反应的结构非敏感性。

As well as activity was exhibited. Theaddition of cinchonidine led to a remarkable increase in the reaction rate, as confirmed bythe IR study that the modifier activates the carbonyl groups of the reactant through itsquinuclidine nitrogen. On the contrary,〓 exerted a strong inhibition effect on theenantioselective hydrogenation. Chapter 3 Finely dispersed polyvinylpyrrolidone-stabilized iridium andbimetallic clusters were prepared by the alcohol-water reduction method.

第三章 采用醇水还原的方法制备了聚乙烯基吡咯烷酮稳定的铱纳米簇及双金属纳米簇，对丙酮酸甲酯的催化氢化表明，在铱金属簇催化体系中，辛可尼定不仅诱导了一定的对映选择性，同时对反应活性有明显的促进作用，平均反应速率可提高2-6倍。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。