查询词典 chloro-hydrocarbons

First, the preparation of l,2-dichloro-4-nitrobenzene, which l-chloro-4-nitrobenzene reacted with chlorine in a self-designed chlorinator, in presence of Lewis acid catalyst,.was investigated. By means of the Orthogonal Experiments design and single factor experiments, the influence of several reaction variables on the yield were examined and the optimum reaction conditions under the intervallic operation were obtained, the yield of l,2-diehloro-4-nitrobenzene was 83.26%.

为此，本文首先在自行设计的塔式氯化器中，以对硝基氯苯为原料，路易氏酸作催化剂，分子氯氯化合成3，4-二氯硝基苯(合成3-氯-4-氟-硝基苯的原料)，根据该氯化过程特征，利用正交试验设计方法结合单因素实验考察了有关因素对氯化过程的影响，优化得到了最佳的氯化工艺条件，3，4—二氯硝基苯的收率可达83.26％。

The function of the addition of co-substrate ethanol was to in-situ regenerate NADH. A mathematical model was derived, in which, two substrates were catalytically reacted in sequence. The model was applied to the system involving the reduction of 2'-chloroacetophenone to R-2'-chloro-1-phenyl-ethanol by S.

深入研究了在乙醇存在下生物还原过程中酵母细胞内NADH、NAD〓、NADPH及NADP〓浓度的变化规律，发现胞内NADPH浓度迅速降低到零，而NADH浓度始终维持在较高水平，证明了用于底物还原反应的辅酶是NADH，辅助底物乙醇的加入有利于实现辅酶Ⅰ的原位再生。

CAR has high stereoselectivity for aromtic ketones such as acetophenone,2'-chloroacetophenone, 3'-chloroacetophenone, 4'-chloroacetophenone, 3-chloropropiophenone and2-chloro-2',4'-difluoroacetophenone.

羰基还原酶对芳香酮类化合物具有很高的立体选择性，对苯乙酮、2'-氯-苯乙酮、3'-氯-苯乙酮、4'-氯-苯乙酮、3-氯-1-苯丙酮和2-氯-2'，4'-二氟苯乙酮还原产物的e.e。

Ozonation could not reduce TOC completely, the results of HPLC and GC-MS showed that p -CNB was mainly transformed into p -chlorophenol, p -nitrophenol, 2-chloro-5-nitrophenol, etc ., and carboxylic acids with low molecular weight.

HPLC和GC-MS结果表明，ClNBs主要被转化为氯酚、硝基酚、氯代硝基酚、硝基苯、氯苯和低分子的羧酸等物质。

For developing an immunoassay for multiple residues of pyrethroid pesticides, the hapten N-2- carbanmoyl-(3"-phenoxyphenyl) methyl 3-(2"-Cldoro-3",3",3"-trifluoropropenyl)-2, 2-dimethylcyclopropane- carboxylate was synthesized from cyanohydrin and 3-(2"-Chloro-3",3",3- trifluoropropenyl)-2, 2-dimethylcyclopropanecarboxylic acid via hydrolysis and esterification. The synthesis of the hapten was foundation of preparaing anti- cyhalothrin polyclonal antibodies.

为了制备对单一拟除虫菊酯高特异性的抗体，以菊酸和氰醇为起始原料，通过水解、酯化反应合成了半抗原N-2-氨甲酰-(3-苯氧基苄基)甲基-3-(2-氯-3，3，3-三氟丙烯基)-2，2-二甲基环丙烷羧酸酯，为进一步制备抗三氟氰菊酯的特异性抗体奠定基础。

Herein, we report the enantioselective total syntheses of slagenins A-C and their antipodes. Starting from readily available ethyl -4-chloro-3-hydroxy-butanonate, elongation of the carbon chain with diazomethane, followed by oxidation of the given α-diazoketone using distilled DMD, afforded a key intermediate α-ketoaldehyde .

本文从方便易得的-4-氯-3-羟基-丁酸乙酯出发，经重氮甲烷延伸碳连、DMD氧化相应的α-重氮酮，制得α-酮醛；该化合物与尿素在氢氟酸作用下，以协同方式非对映选择性的直接构建了cis-四氢呋喃并[2，3-d]咪唑啉-2-酮双环结构，进而合成了天然产物slagenins A、B、和C的对映体。

The appropriate temperature of diazotization was-10～-5℃,and the diazotizating fluoborate was decomposed in petroleum ether to get 2-chloro-3-fluoropyridine with 64% yield.

以2-氯-3-氨基吡啶为原料，在40%的氟硼酸溶液中，采用饱和的亚硝酸钠为重氮化剂，在-10~-5℃下进行重氮化反应制得重氮盐，在石油醚中热分解得到2-氯-3-氟吡啶，收率为64%。

Thenew route has some advantages such as simple operation, inexpensive materials andbetter yield compare to other synthesis routes.The synthesis route is showed as follows. First,-2-chloro-3-phenylpropionic acid is synthesized from L-phenylalanine by diazotization.

在参考大量文献的基础上，我们设计了一条新的合成路线，和其它合成路线相比较本路线具有操作简单、原料易得、收率较高等优点。

Two kinds of di aniline derivative s connected with oxamethylene bridge or azamethylene bridge were synthesizied by condensation of o nitrophenol and ethylene dibromide (1,4 dibromobutane)or 4 chloro 3,5 dinitrobenzotyifluoride and ethylene diamine(1,6 hexandiamine)and consequent reduction.

由邻硝基苯酚和二溴乙烷以及由4－氯－3， 5－二硝基三氟甲苯和乙二胺为原料通过桥接、还原合成两类由氧亚甲基或氮亚甲基桥联的双苯胺衍生物。

The main photoproducts in dioxane and hexane are 2-chloro benzamide and 4-chlorophenyl isocyanate.

在二氧六环及正己烷中的主要光解产物为邻氯苯甲酰胺和对氯苯基异氰酸酯。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。