查询词典 chiral

The invention comprises a cyclopalladated catalyst with axial chiral binaphthyl backbone containing phosphine ligand as well as the synthesis thereof, and the application of the catalyst with cyclopalladated catalyst with axial chiral binaphthyl backbone containing phosphine ligand with a similar structure to the hetero atom norbornadiene ring cleavage reaction through an asymmetric catalytic organic boron agent.

本发明包括一类具有轴手性联萘骨架含膦配体的环钯催化剂及其合成，以及其与具有类似结构的轴手性联萘骨架含膦配体的环钯催化剂在不对称催化有机硼试剂对杂原子降冰片二烯开环的应用。

The asymmetric polymerization of methyl methacrylate is carried out using the chiral binaphthyl crown ether macrocyclic compounds binding n-BuLi or t-BuOK as chiral initiator at -78℃.

以手性联萘冠醚为配体，络合n-BuLi，t-BuOK等有机金属化合物形成手性引发剂体系，初步探讨了甲基丙烯酸甲酯单体的聚合反应。

The chiral polymer P-1 shows strong blue fluorescence due to the extended π-electronic structure between the chiral repeating unit-6,6'-di(4-trifluoromethyl-phenyl)-2,2'-bisoctoxy-1,1'-binaphthyl and the conjugated linker 2,2'-bipyridyl group via vinylene bridge.

手性高分子P-1能发射强的蓝色荧光，这是由于手性重复单元-6，6′-二(4-三氟甲基苯基)-2，2′-二正辛氧基-1，1′-联萘和单元2，2′-联吡啶通过亚乙烯基桥连形成共轭高分子结构造成的。

It is a natural chiral compound with three chiral carbon atoms and a reactive carbo- xyl group. Like some natural drugs, it has a aromatic diterpene structure with three rings.

它是含有三个手性碳原子的天然手性化合物，有一个反应性官能团——羧基，具有许多天然药物都具有的芳香型三环二萜结构。

Meanwhile, the β-cyclodextrin- modified chiral amine salt also exhibited the chiral inducibility in asymmetric epoxidation of chalcone.

通过共价键负载于β-环糊精的手性胺在查尔酮的不对称环氧化反应中也显示出立体诱导作用。

A type of chiral molecular tweezers has been designed and synthesized by using diphenic acid as spacer and chiral unsymmetrically disubstituted urea as arm for the first time.

近年来，利用合成的人工受体与适当底物间的分子识别以建立仿生仿酶模型的研究，已成为生物有机化学和超分子化学前沿领域之一lL】。2 J。

The synthesis of chiral pharmaceuticals is a hot issue of the development in pharmaceutical in the world,asymmetric hydrogenization of which is the successful technology in the chiral synthesis .

手性药物的合成是目前全球药物开发研究的热点，而不对称氢化是手性合成中最成熟的技术。

The synthesis of chiral pharmaceuticals is a hot issue of the development in pharmaceutical in the world,asymmetric hydrogenization of which is the successful technology in the chiral synthesis .

手性药物的合成是目前全球药物开发研究的热点，而不对称氢化是手性合成中最成熟的技术。讨论了不对称氢化技术在镇痛类、抗生素类、抗菌类、抗忧郁类以及维生素类等9类手性药物合成中的实际应用

Two chiral centers of 〓 and 〓 are come fromchiral isoamyl alcohol and chiral octanol-2 respectively.

和〓的手性中心分别来自于手性异戊醇和手性辛醇-2。

Based on the different reaction results with-menthyl,-8-(2-naphthyl)menthyl or-8-phenylmenthyl as the chiral auxiliary, it is was proposed that the possible p -stacking effect between the aryl of chiral auxiliary and dienyl group of α,β-unsaturated esters is involved in the diastereoselectivity of these reactions.

该反应手性辅基易于回收、选择性好，产率高，这一工作为合成多取代的光学活性乙烯基环丙烷衍生物的提供了一种较为简便的方法。

They weren't aggressive, but I yelled and threw a rock in their direction to get them off the trail and away from me, just in case.

他们没有侵略性，但我大喊，并在他们的方向扔石头让他们过的线索，远离我，以防万一。

In slot 2 in your bag put wrapping paper, quantity does not matter in this case.

在你的书包里槽2把包装纸、数量无关紧要。