查询词典 chiral

Chiral azaheterocycle triazole derivatives have been paid close attention to by all the world in the research of chiral pesticides.

在手性农药研究中，含氮杂环的手性三唑类杀菌剂一直备受国内外农药研究者的关注。

Reverse-phase chromatography was employed for chiral separation of tropine acid enantiomers on the cellulose tribenzoate chiral stationary phases coated on a small-particle spherical silica support in an eluant system consisting of a mixture of alcohol and water.

摘 要：以乙醇-水流动相，用纤维素-三作为手性固定相对外消旋体托品酸进行了高效液相色谱手性分离考察了不同比例的乙醇-水流动相、不同流速以及用不同醇类酯化对托品酸酯在手性色谱柱上的色谱行为。

Interaction between vicinal supramolecules, distance of chiral centers between host and guest molecules and acetone molecule inclused are not important for the chiral recognition between host and guest molecules.

主客体之间手性中心距离的远近以及溶剂丙酮分子等因素，不是影响主客体之间的手性识别的关键因素。

The aim of this thesis is to synthesize some new chiral quaternary ammonium salts and bis-quaternary ammonium salts from the popular material------Chloramphenicoland abietic acid, and then we used these chiral quaternary ammonium salts in some substitution reactions and addition reactions in order to research their catalytic action and asymmetric induction.

本文利用廉价易得的手性物质——氯霉素和去氢枞酸为初始原料，合成了几种新的季铵盐类手性相转移催化剂，扩大了手性相转移催化剂的来源，并把它们应用于取代反应和加成反应，以探讨其催化机理和不对称诱导效应。

Preparation of the lateral chain-4-benzyloxy-3-hydroxy butyronitrile is introduced as the substrate, the REFORMATSKY reaction is performed, then obtains the dicarbonyl ester, in the structure of which containing a chiral hydroxyl group, then performs the chiral reduction, take off the benzyl group after the protection reaction with acetonylidene,then obtains the lateral chain by oxidation.

手性侧链醛的合成：采用-4-苄氧基-3-羟基丁腈作为底物，通过REFORMATSKY反应缩合得到含有手性羟基的二羰物酯，再手性还原，丙酮叉保护后氢解脱苄，最后氧化得到侧链醛。

In this chapter, the MPV reactions catalyzed by alkoxy dysprosium is used to the reduction of prochiral ketones. The chiral alkoxy catalyst was prepared by chiral binaphthol and Dy 〓.

最后还将烷氧基镝催化下的MPV还原反应应用于潜手性酮的不对称还原，利用光学活性的联萘酚制备了手性烷氧基催化剂，结果表明该催化剂可有效地催化潜手性酮的不对称MPV还原。

The longer fluorinatd alkyl chain on the three-ring was advantageous to the formation of smectic phase. The mesogens with chiral center located between fluorinated tail and mesogenic core exhibited chiral smectic C phase and other smectic phases when the alkoxyl adhering to the other side of the mesogenic core was of intermediate length.

三环系液晶化合物中较长的氟烷基边链有利于近晶相的形成，且当液晶核另一端的烷氧基链的长度适中时，在氟烷基边链和液晶核之间具有手性中心的液晶分子显示了手性近晶C相和其它液晶相。

Practice of opening experiment related to caffeine analysis with MEKC ;2. Amphiprotic chiral drug cetirinine was enantioseparationed by MEKC with two micellar and two chiral additives.

用毛细管胶束电动色谱电化学检测的方法对对氧磷、甲基对硫磷、乙基对硫磷、扑灭松等4种常见有机磷农药进行分离检测。

In chapter four, the chiral recognition properties of one chiral calix [4] crown ether toward amygdalic acid and dibenzoyl-tartaric acid were studied by 〓H NMR,〓C NMR and UV-vis spectroscopy.

研究结果表明，手性杯[4]氮杂冠醚对二者均有一定的手性识别能力，并发现针对不同的客体，主体以不同的构象与之相互作用，证实分子识别过程中存在构象的变化。

Optically active axially dissymmetric binaphthyl derivatives have been extensively used as excellent chiral ligands in asymmetric catalysis and chiral recognition.

光学活性的联萘衍生物以其独特的立体化学性质作为优异的C2轴手性诱导源，已被广泛地应用到不对称催化反应和手性识别中。

They weren't aggressive, but I yelled and threw a rock in their direction to get them off the trail and away from me, just in case.

他们没有侵略性，但我大喊，并在他们的方向扔石头让他们过的线索，远离我，以防万一。

In slot 2 in your bag put wrapping paper, quantity does not matter in this case.

在你的书包里槽2把包装纸、数量无关紧要。