查询词典 chiral

This paper reviews the recent advances in synthesis of chiral allylic amines, mainly discussing the effects of ligands on chemo-and regio-selectivities.

综述了近年来手性烯丙基胺的合成进展，重点介绍了催化剂配体对化学选择性和对映选择性的影响，并阐述了各种类型的反应机理

Chiral N,P ligand 5 was examined for the asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate with up to 89% yield and up to 81.6% ee.

化合物5用于钯催化的1，3-二苯基-2-烯丙基乙酸酯的不对称烯丙基烷基化反应，产率为89%，对映体过量最高为81.6% ee。

The amidation reaction of the chiral unsaturatecd acid with the amine accomplished the synthesis of one target molecule.

第3章叙述了用9步反应、12%的总产率完成了malyngamide M的首次全合成。

A method for chiral analysis of anatabine,nornicotine and anabasine in tobacco has been established.

建立了烟草中新烟草碱、降烟碱和假木贼碱的手性分析方法。

As applications, the 2nd elastic moduli are used to explain the effect of chiral angle on asymmetry behavior of torsion, and finite deformation problems of single-walled carbon nanotubes are successfully simulated by the thin shell model.

作为应用：利用面内的2阶模量解释了纳米管螺旋角相关的力学行为：扭转不对称现象。利用薄壳模型成功模拟了单壁纳米管的大变形弹性失稳行为。

Three chiral phosphorus ligands were prepared using anisole as the startingat material.Their applications in the asymmetric hydroformylation and asymmetric conjug ed addition of diethylzinc to enones were investigated.

以苯甲醚为原料，合成了三种新的手性含磷配体，考察了三种配体在不对称氢甲酰化反应和ZnEt2对环己烯酮的不对称共轭加成反应中的应用。

Based on the addition of vinyl magnesium bromide to the chiral non-racemic synthon 2 derived from-1, an enantioselective total synthesis of-3, the antipode of marine alkaloid halitulin 10 steps, overall yield: 5.3% from (R-1 was achieved using aza-Claisen rearrangement as a key step.

取得的主要结果如下：一、从-苯基甘氨醇1出发，通过已知的哌啶手性合成砌块2的加成反应，建立了经aza-Claisen重排反应进行海洋生物碱halitulin手性分子片断的对映体--isohaliclorensin 3不对称合成的路线。

Based on the addition of vinyl magnesium bromide to the chiral non-racemic synthon 2 derived from-1, an enantioselective total synthesis of-3, the antipode of marine alkaloid halitulin 10 steps, overall yield: 5.3% from (R-1 was achieved using aza-Claisen...

取得的主要结果如下：一、从-苯基甘氨醇1出发，通过已知的哌啶手性合成砌块2的加成反应，建立了经aza-Claisen重排反应进行海洋生物碱halitulin手性分子片断的对映体--isohaliclorensin 3不对称合成的路线。

The reaction-diffusion model was developed to analyze the concentration of enantiomers and the separation factor of the enantioseparation process of chiral emulsion liquid membrane by studying the principle and some factors of mass transfer process. The mass transfer resistance of boundary layer in outer aqueous phase and the interfacial chemical reactions at the liquid membrane interfaces were taken into account in the model equations.

通过对乳状液膜手性分离过程中传质机理的研究以及各影响因素的分析，得到了可以分析和预测乳状液膜手性拆分过程传质的反应-扩散模型，该模型同时考虑了外水相边界层的扩散阻力和手性对映体与载体的反应阻力。

The concentration of D-phenylalanine in the external phase and the separation factorαcan be expressed as: The diffusion of boundary layer in outer aqueous phase is the controlled process while the concentration of D-phenylalanine in the external phase far less than the concentration of chiral carrier in the emulsion liquid membrane phase, then the diffusion coefficient k_e of boundary layer in outer aqueous phase can be achieved by data fitting.

外水相苯丙氨酸对映体的浓度以及分离因子α表示为：当外相对映体浓度远小于液膜相手性载体浓度时，该手性传质过程中外相边界层的扩散为控制步骤，利用数据拟合得到了外水相与液膜相界面边界层扩散的传质系数k_e。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。