查询词典 chiral

For example, using chiral tungsten 2'-pyridinyl alcoholate complex at 50 ℃, the ee value was increased from 54% to 78%.

在磷霉素的不对称合成研究方面只有Giordano等[4]是以顺丙烯膦酸为起始原料进行的。

When chiral molybdenum 2'-pyridinyl alcoholate complexe was used as catalyst, the enantiomeric excess was 79. 5% at 0℃ in CH〓Cl〓.

我们目前经实验优化取得的最佳反应条件是：使用MoO〓〓作催化剂，在CH〓Cl〓中于0℃反应，所得产物的ee值达到了79.5％。

In this paper, chiral molybdenum or tungsten 2'-pyridinyl alcoholate complex catalyzed asymmetric epoxidation of cis-1-propenylphosphonic acid in H2O was reported.

目前磷霉素的生产是通过以Na2WO4为催化剂、在乙醇中以30%的H2O2将顺丙烯膦酸环氧化得到消旋产物，再利用α-苯乙胺进行拆分而得到[2，3]。

The highest ee value of 71% was achieved by using chiral molybdenum 2'-pyridingyl alcoholate complex at 0 ℃. After addition of phase transfer catalyst Bu4NBr, the yield and ee value were remarkably increased.

其中手性吡啶醇二氧合钼在0℃下的对映选择性ee值达到71%；加入相转移催化剂四正丁基溴化铵，催化剂的活性和对映选择性有显著提高，其中手性吡啶醇二氧合钨在50℃下ee值由54％提高到78%。

The main products and business: Pharmaceutical intermediates,Bactericide and Algaecide, Amino acids and derivatives,Polypeptide reagents, Chiral compounds, oxygen absorbers, biochemical reagents and fine chemicals, our products sold in Europe and America, the Middle East and other regions.

主要产品及业务：医药中间体，水处理杀菌剂，氨基酸及衍生物，多肽试剂，手性化合物，脱氧剂，生化试剂和精细化学品，销往欧美，中东等地区。

The cytotoxicity of these compounds were valuated by MTT and SRB methods using three cancer cell lines: HL-60, A-549, P-388. Cyclo-shikonin, and cyclo-alkannin have high cytotoxicity against HL-60.The chiral center of side chain has no effect on their activity. 2- 1-(Acetyloxy-4-methyl-3-pentenyl -5, 8-dihydroxy-1, 4-naphthoquinone (105) has strong inhibition effect on P-388 cells. 2- 1-(isooctyloxy-4-methyl-3-pentenyl -5, 8-dihydroxy-1, 4-naphthoquinone (108) and 2- 1-(2-furoyloxy-4-methyl-3-pentenyl -5, 8-dihydroxy-1, 4-naphthoquinone (112) have high inhibition on A-549.Shikonin (1), alkannin (2), and their derivatives have the structural features of a planar chromophores and short side chain. We examined the ability to inhibit the telomerase.

抗肿瘤活性初步筛选测试采用小鼠白血病P-388肿瘤细胞和人肺癌A-549肿瘤细胞进行，结果表明侧链羟基的手性对抗肿瘤活性无明显影响；有数个化合物具有很好的体外抑制活性，特别是化合物2-（1-异辛酰氧基-4-甲基-3-戊烯基）-5，8-二羟基-1，4-萘醌（108）和2-[1-（2-呋喃甲酰氧基）-4-甲基-3-戊烯基]-5，8-二羟基-1，4-萘醌（112）体外显示对人肺癌A-549肿瘤细胞有强效；2-（1-乙酰氧基-4-甲基-3-戊烯基）-5，8-二羟基-1，4-萘醌（105）对小鼠白血病P-388肿瘤细胞有强效；环紫草素和环异紫草素对人白血病HL-60细胞有强烈抑制作用。

The ligands were found to be effective in palladium-catalyzed asymmetric allylic alkylation to construct chiral quaternary carbon center.

这类配体在前手性亲核试剂的不对称烯丙基化构筑手性季碳中心的反应中，显示了较好的反应活性及对映选择性。

Application of 1, 1'-Planar chiral P, N -ligands into palladium-catalyzed allylic substitution

1， 1'-平面手性二茂铁膦氮配体在钯催化烯丙基取代反应中的应用

It afforded a practical method to synthesize chiral allylic amines.

该方法是合成手性烯丙基胺类化合物的一个非常适用方法。

In this dissertation, the efforts were focused on design and synthesis of new types of chiral and achiral azoamide hosts,bowl-shaped steroid cholic acid methyl esters with one chiral arm under microwave irradiation and heteroaromatic molecular tweezers under microwave irradiation in solid state and their molecular recognition as well as enantioselective recognition.

本文致力于新型手性不对称脲、胆甾和芳杂环类分子钳受体的设计合成及其对阴离子、中性分子和手性分子的识别及对映选择性识别性能研究，取得了一系列具有重要学术意义与应用前景的创新性结果。

They weren't aggressive, but I yelled and threw a rock in their direction to get them off the trail and away from me, just in case.

他们没有侵略性，但我大喊，并在他们的方向扔石头让他们过的线索，远离我，以防万一。

In slot 2 in your bag put wrapping paper, quantity does not matter in this case.

在你的书包里槽2把包装纸、数量无关紧要。