查询词典 chelating

Because the solubility of the complex monomers is very important for polymerization, the bidentate ancillary ligand of the bicycloiridium complexes also has an effect on the luminous properties of the chelating polymer.

实验证明了在这类电磷光聚合物中配合物单元辅助配体合理的分子设计，可以提高配合物单体的溶解度，提高聚合物的分子量和发光性能。

The well-documented chelating properties of bipyridine and the sensitivity of the optical properties of AuNPs have been employed to detect low concentration of metal ions in water.

因为联吡啶具有好的钳合能力，加上金奈米粒子的灵敏的光学性质，所以可以用来侦测水中低浓度的金属离子。

SO〓〓/M〓O〓 solid superacid was applied to the photocatalytic oxidation of organic pollutants for the first time. Porous SO〓〓/TiO〓 solid superacid catalysts with high specific surface area were prepared by sol-gel method. The photocatalytic degradation of bromomethane was used as model reaction. The influence of impregnation with H〓SO〓 solution on the structure of catalysts and their photocatalytic performance was systematically studied by using X-ray diffraction, X-ray photoelectron spectroscopy, N〓 sorption analysis applying BET method, UV-Vis diffuse reflectance spectroscopy, FTIR spectroscopy, O〓-TPD and photocatalytic activity measurement. The acidity of TiO〓-based catalysts was investigated by Hammett indicator method, NH〓-TPD and IR spectra of pyridine adsorbtion. The mechanism of superacidifing effects on photocatalytic performances such as the photocatalytic degradation rate of bromomethane, apparent kinetic constant and apparent quantum efficiency was discussed.The results indicated that SO〓〓 is combined with metal ions of TiO〓 in a chelating bidentate mode.

本文首次将SO〓〓/MxOy型固体超强酸催化剂用于光催化氧化有机污染物研究，采用溶胶-凝胶法制备了具有多孔性和大比表面结构的二氧化钛基固体超强酸光催化剂SO〓〓/TiO〓，以光催化降解溴代甲烷为模型反应，系统地研究了H〓SO〓浸渍处理对催化剂表面酸性及其气相光催化性能的影响，结合XRD、BET、XPS、FTIR、Hammett指示剂法、吡啶吸附红外光谱、NH〓-TPD、O〓-TPD、紫外可见漫反射光谱等多种表征手段，深入地讨论了超强酸化对TiO〓的改性机理，阐明了引起SO〓〓/TiO〓超强酸催化剂光催化降解溴代甲烷的转化率、表观反应速率常数和表观量子效率变化的本质原因。

However, the quality of the copper film deposited by this method is poor. In order to resolve this problem, we study the influence of some additives on two different kinds of electroless copper plating which using sodium hypophosphite as reducing agent and sodium citrate as chelating agent, sodium citrate and ethylene diamine tetraacetic acid disodium salt (EDTA·2Na). Electrochemical methods were used to test the anodic and cathodal polarization processes which can explain the mechanism of the influence of additives.

然而该体系所得的铜膜质量较差，为此我们研究了以次磷酸钠为还原剂，分别以柠檬酸钠为单一络合剂，柠檬酸钠和乙二胺四乙酸二钠为双络合剂体系中，研究了几种添加剂对化学镀铜的影响，并通过电化学方法研究了各种添加剂对化学镀铜沉积电位的影响。

Results Daphnetin exhibited a modest iron-chelating ability compared with the powerful iron-chelator desferrioxamine B.

结果 与强铁螯合剂去铁胺相比，瑞香素具有中度的铁螯合能力。

The chelating fibers with diethanolamine group or diethylamine group present great adsorption capacity , high adsorption rate as well as good selectivity for Au3+ ion.

结果表明，含二乙胺基和二乙醇胺基的螯合纤维对金离子的吸附量较大，而且吸附快、对金的选择性好，还能将所吸附的金离子还原成单质金

Quercetin is one of the effective components contained in sophora japonica flower bud.3-hydroxy 4-carbonyl,4-carbonyl 5-hydroxy,and 3′,4′-dihydroxy groups of quercetin could be become chelating position with metal.

槲皮素（3，5，7，3′，4′－五羟基黄酮）是中药槐花蕾的有效成分之一。槲皮素的3－羟基4－酮基，5－羟基4－酮基及3′，4′－二羟基均为可络合部位。

Three new kinds of thiourea - type chelating cotton cellulose, thiourea cellulose, thiosemicarbazide cellulose and diphenylthiourea cellulose, were synthesized in our Lab, and their absorptive characteristics for copper was investigated.

将自制合成的三种新型硫脲型螫合纤维素——硫晚棉纤维，氨基硫脲棉纤维和二苯硫脲棉纤维应用于钢的吸附性能的研究，采用火焰原子吸收法测定选择了吸附和解吸的最佳条件。

The chelating ability of its enolate anion (TTF-ph-tfac) has been investigated with [MIICl_2·xH_2O] (M = Zn and Co) leading to complexes Zn(TTF-ph-tfac)_2(CH_3OH)_2 (7) and Co(TTF-ph-tfac)_2(CH_3OH)_2 (8), where the metal center is coordinated by two TTF-ph-tfac ligands. This redox active ligand shows promising features for the elaboration of hybrid organic-inorganic building blocks.

具有反铁磁行为的化合物5在110-120K观察到了相转变的发生，是目前已报道的该类化合物中最高的相变温度。3、TTF-ph-tfac烯醇阴离子具有很强的配位能力，与金属氯化物螯合配位分别生成了配合物Zn(TTF-ph-tfac)_2(CH_3OH)_2 (7)和Co(TTF-ph-tfac)_2(CH_3OH)_2 (8)，每个中心金属都桥连两个TTF-ph-tfac配体。

We studied their properties by IR, NMR, OPM and DSC and found that the ratio of Cu2+/DK-C11-C12 affects the mesomorphic temperature range and the results show that chelating units can play a mesogen function.c Synthesis and mesomorphic properties study of Cu-coordinating liquid crystalline polysilsesquioxanes with heptyl group on the side chain.

2对以β-二酮为侧链的梯形无规聚硅氧烷铜络合物用IR，NMR进行了结构表征，用DSC，偏光显微镜等方法进行了液晶性能的表征，并与同类化合物的性能进行了比较和研究，结果表明：Cu~(2+)含量对液晶相温度区间有明显的影响。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。