查询词典 catalyzed

Determination of pyrogallol by Flow Injection Chemiluminescence Assay;2. Study on the Auto-oxidation of Pyrogallol by Electrochemistry;3. The kinetics of pyrogallol oxidation catalyzed by the complexes have been studied.

研究了以邻苯三酚为底物各配合物的多酚氧化酶活性，结果表明：4种配合物催化邻苯三酚氧化都符合米氏方程曲线，且催化活性都随pH值的升高而增加。

Recent development of vapor - phase Beckmann rearrangement of cyclohexanone oxime to ε-caprolactam catalyzed by molecular sieves was reviewed.

介绍了用以代替浓硫酸催化环己酮肟Beckmann重排反应制己内酰胺的各类分子筛催化剂的研究新进展，并对其反应机理、催化剂的失活与再生、反应新工艺进行了阐述。

Such as,(1) Active Zincdust catalyzed the esterification reactions between benzoyl chloride and phenol or alcohol,which needed not solvent, warming and could fulfilled in a very short period (1-2min), andthe handling of the reaction mixtures was very simple. We believe it's the simplest and mosteconomic method for the synthesis of many aryl esters.

包括：(1)活性锌粉催化的酯化反应，在室温下即可反应，毋需溶剂，毋需加热，反应迅速(通常1—2分钟即可反应完全)，处理非常简便，相信目前是合成许多芳香酯最简便的方法，是一种值得加以推广的合成芳香酯的好方法。

Ferric chloride catalyzed direct conversion of carbonyl compounds to the corresponding chloride with silicon hydride ( dichloromethylsilane , chlorodiphenylsilane or trichlorosilane) was realized.

在甲基二氯硅烷作用下，FeCl3能催化羰基化合物的还原氯代反应，得到相应的氯代产物；在甲基二氯硅烷、PBr3或NaI作用下，FeCl3可以催化羰基化合物的还原溴代或碘代反应，分别以良好的收率得到相应的溴代烷或碘代烷

The Pd-catalyzed Suzuki-Miyaura cross-coupling reaction is one of the most efficient methods for the construction of C-C bond.

Suzuki偶联反应是一种形成C—C键的有效方法，在有机合成中发挥着重要的作用。该反应具有反应条件温和、可适用多种活性官能团、受空间位阻影响不大、产率高以及芳基硼酸经济易得且对潮气不敏感等优点，因而得剑广泛应用。

A series of alkyl diphenyl ether were synthesized with low cost raw materials,diphenyl ether and aliphatic alcohol,catalyzed by concentrated sulfuric acid,and followed by sulfonation to produce MADS.On the basis of analysis and characterization,structure of the products was identified,effect factors of the preparation reactions were investigated and the optimum reaction conditions were obtained.2.The surface chemical properties of C_8,C_9,C_(10)-MADS were determined.

通过对产物的表征分析，对其结构进行了鉴定，并对合成反应的影响因素进行了分析讨论，优化了合成条件。2、测定了所合成的系列烷基二苯醚双磺酸钠C_8-MADS，C_9-MADS，C_(16-MADS的表面化学性能，结果表明：合成样品在质量分数高达10%的无机酸、无机碱及无机盐溶液中表面化学性能稳定，同时显示出优良的乳化性能和在硬水条件下较好的去污洗涤性能。3。

A plausible process of this reaction is as following: Aldehyde was in equilibrium with the enol form, aldehyde reacted with aniline catalyzed by 2,2,2-trichloroacetic acid to afford imine, the generated imine immediately reacted with enol to form intermediate via intramolecular cyclization.

我们发现一分子芳基叠氮和一分子三苯基磷反应生成一分子磷亚胺，后者与由两分子取代的苯氧乙酰氯原位生成的烯酮反应生成4-亚烷基-β-烷基-内酰胺，其串联过程涉及烯酮亚胺的形成及其与烯酮的[2+2]的环加成反应。

Base played a crucial role in this reaction: in the Pd2/L1 catalyzed α-arylation of ethyl malonate, K3PO4 is the base of choice; in the α-arylation of ethyl acetoacetate, K2CO3 is the most effective base.

在这类催化反应中，碱的选择具有重要的影响：以K3PO4为碱， Pd2/L1催化体系在丙二酸二乙酯的α-芳基化中，富电子溴代芳烃显示较好的活性； Pd2/L1催化的乙酰乙酸乙酯α-芳基化时，以 K2CO3为碱，催化体系显示较好的活性，这个催化体系可控制反应得到α-芳基乙酰乙酸乙酯，而不是脱乙酰基的产物。

Base played a crucial role in this reaction: in the Pd2/L1 catalyzed α-arylation of ethy malonate, K3PO4 is the base of choice; in the α-arylation of ethyl acetoacetate, K2CO3 is the most effectiv base.

在这类催化反应中，碱的选择具有重要的影响：以K3PO4为碱，Pd2/L1催化体系在丙二酸二乙酯的α-芳基化中，富电子溴代芳烃显示较好的活性；Pd2/L1催化的乙酰乙酸乙酯α-芳基化时，以K2CO3为碱，催化体系显示较好的活性，这个催化体系可控制反应得到α-芳基乙酰乙酸乙酯，而不是脱乙酰基的产物。

Starch acetates with different degrees of substitution were synthesized by reaction of corn starch and acetic acid/acetic anhydride catalyzed with concentrated.

以浓硫酸作催化剂，玉米淀粉为原料，冰醋酸和醋酸配为改性剂，合成了不同取代度的玉米淀粉醋酸酯。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了