查询词典 catalyzed

This paper has firstly reported heterogeneously catalyzed selective oxidationof toluene to benzaldehyde with molecular oxygen in liquid phase. It has beenfound that copper and iron oxides catalyst supported on ?

本论文提出采用多相催化剂，以分子氧为氧源，液相条件下的合成路线是提高目标产物选择性的有效途径之一。

Synthesis methods of bisphenols catalyzed by sulfuric acid, ion exchange resin IER and heteropoly acid were studied in this thesis.

本文研究了硫酸、离子交换树脂和杂多酸用作催化剂合成双酚的方法。

Study on Asymmetric Cyclopropanation of 2,5 Dimethyl 2,4 hexadiene Catalyzed by Chiral Copper Complexes

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The kinetic behaviors of ethylene homo- olymerization and ethylene / l-hexene co-polymerization , catalyzed by the metallocene catalyst PS-DVB-MC in an 0.5 L stainless steel reactor , were studied. The effects of polymerization conditions on ethylene polymerization , such as concentration of catalyst , temperature of polymerization , pressure of ethylene , molar ratio of AI / Z r , etc ., were also investigated . Some leading results were as follows : the activity of the catalyst PS–DVB- MC for ethylene homo-polymerization was high ( 1.053 x 107 gPE / mol Zr·h ), but the molar ratio of AI / Zr was low ( 350:1 ); the catalytic ability for ethyleneα-olefin ( such as l hexene etc .) co-olymerization was great , and the corresponding activity come up to a maximum of 1.753 x 107 gPE / mol Zr·h while concenlration of l-hexene was 0.080 mol / L ; the molecular weight of polyethylene was about 180,000 , meanwhile the molecular weight distribution was narrow ( 2.19 ); the bulk density of polyethylene and ethylene / l-hexene co -polymer were 0.25 and 0.34 respectively .

采用0.5L高压不锈钢反应釜，对催化剂PS–DVB-MC催化乙烯均聚和乙烯/ l-己烯共聚合的动力学行为进行了研究，详细考察了催化剂浓度、反应温度、压力、Al/ Zr比、1-己烯浓度等因素对乙烯聚合反应的影响，得到如下主要结论：催化剂PS-DVB-MC具有催化乙烯均聚的高活性(1.053×107g PE / mo1 zr.hr)，低Al / Zr比( 350：1 )；具有良好的催化乙烯与α-烯烃(如1-己烯等)共聚的能力，在1-己烯浓度为0.080 mol / L时，催化活性达到最大(1.783×107 g PE / molZr.hr)；乙烯均聚产物的分子量在18万左右，分子量分布窄( 2.19 )。

Both catalytic activity and selectivity of Ru(PPh_3)_3Cl_2 were improved in ionic liquid BMImPF_6/DME medium.The conversion of hexene and selectivity ofβ-adduct for the hydrosilylation reaction of 1-hexene with triethoxysilane catalyzed by Ru(PPh_3)_3Cl_2 in ionic liquid BMImPF_6DME (V/V=1/4) medium at 90℃were 100% and 89.0%,respectively.

实验结果表明，在乙二醇二甲醚/离子液体1-丁基-3-甲基咪唑六氟磷酸盐(BMImBF_6)(V/V =1/4)介质中，于90℃下，己烯与三乙氧基硅烷反应的转化率为100%，β加成物的选择性可达89.0%，而用Rh(PPh_3)_3Cl作为反应的催化剂，在纯离子液体BMImPF_6中，就可以高效催化烯烃与三乙氧基氢硅烷的加成反应，过渡金属Rh(PPh_3)_3Cl，Ru(PPh_3)_3Cl_2催化剂/离子液体BMImPF_6催化体系，不仅解决了产物与催化剂分离困难这一难题，同时，离子液体BMImPF_6的存在提高了过渡金属Rh(PPh_3)_3Cl，Ru(PPh_3)_3Cl_2催化硅氢加成反应的活性，特别是β加成物的选择性。

In part Ⅱ, electrophilic substitution reaction of indoles with aldehydes, ketones and 6-Nitro-vinyl catalyzed by dodecylbenzencsulfonic acid in water were studied in detailed.

本文第二部分详细研究了十二烷基苯磺酸水相催化吲哚与醛、酮和硝基烯的反应。

The results indicated that excellent yields of bis(indol-3-yl)methanes were obtained when indoles reacted with aldehydes and cyclo-ketones catalyzed by 20 mol% DBSA in water.

结果表明：在20mol％的DBSA的催化作用下，吲哚与芳香醛、脂肪醛和脂环酮高产率得到相应的双吲哚衍生物。

The palladium-catalyzed heteroannulations of C_(60) with a variety ofο-iodoanilines afforded the first synthesis of C_(60)-fused indoline derivatives.

通过在Pd的催化下，富勒烯和邻碘苯胺类化合物的杂环化反应，首次合成了一系列富勒烯并吲哚啉环衍生物。

A new fused polycyclic indoline compound was synthesized from aniline,with the key step of Pd-catalyzed tandem cyclization using hydroquinidine as the ligand and molecular oxygen as a green oxidant.

以芳香氨为原料，通过烯丙基化、重排、酰基化及钯催化的氧化环合反应合成了一种新的氮杂三环吲哚啉化合物，其结构经1H NMR，13C NMR，IR及HR-MS表征。

The features of molecular structure of aromatics, resins and asphaltenes were investigated by ruthenium-ion-catalyzed oxidation, where involatile acid products were methylated with excess diazomethaneether and volatile acids were esterified with phenacyl bromide.

利用钌离子催化氧化方法对大港减压渣油芳香分、胶质和庚烷沥青质进行了选择性降解，通过GC、GC-MS等分析手段对降解反应产物中一元正构脂肪酸、α，ω-二元正构脂肪酸和苯二～六元羧酸的含量和分布分别进行了定量分析。

Singer Leona Lewis and former Led Zeppelin guitarist Jimmy Page emerged as the bus transformed into a grass-covered carnival float, and the pair combined for a rendition of "Whole Lotta Love".

歌手leona刘易斯和前率领的飞艇的吉他手吉米页出现巴士转化为基层所涵盖的嘉年华花车，和一双合并为一移交&整个lotta爱&。

This is Kate, and that's Erin.

这是凯特，那个是爱朗。