查询词典 catalyzed

Homogeneous catalytic oxidations of organic substrates such as alkane and alkene catalyzed by m-oxo-bismetalloporphyrins and flexible alkoxyl oxygen linked-bismetalloporphyrins were introduced,and the catalytic mechanism of these two bismetalloporphyrins,along with the possible synergetic catalysis mechanism of binuclear central metal were discussed.

主要介绍了μ-氧代双核金属卟啉和以柔韧烷氧链相连的双核金属卟啉作为仿酶催化剂在均相催化烷烃、烯烃等有机底物氧化方面的研究进展，并对这两类双核金属卟啉的催化机理、金属双核的协同催化作用机理作了论述，最后展望了双核金属卟啉仿酶催化剂的研究前景。

Copolymers with the naphthoyimine chromophores were firstly obtained through Pd-catalyzed Heck reaction. The copolymers had good solubility in common solvents due to the presence of alkoxyl substituents in the molecular chains.

在钯催化下利用Heck耦合反应制备了以萘酰亚胺为发色团的共聚物，通过侧链上引入丁氧基醚链，使得聚合物具有很好的溶解度，能溶解在常用有机溶剂中。

In the second part, the first example of Lewis acid catalyzed 1, 3-cycloaddition between nitrones and alkylidene malonates was developed by using trisoxazoline 63 and Co〓.

催化剂的用量可降至1-2mol％。在论文的第二部分，我们首次研究了Lewis酸催化的硝酮与丙二酸酯类衍生物的1，3-偶极加成反应。

HCo 〓-catalyzed hydroformylation and isomerization of allene and propyne Allene hydroformylation favors the linear anti-Markovnikov product in high regioselectivity both kinetically and thermodynamically. The origin of this regioselectivity comes from the enhanced stability of the η〓-allylic intermediate (η〓-CH〓CHCH〓 Co 〓.

HCo〓催化的丙二烯和丙炔氢甲酰化反应及异构化反应 HCo〓催化丙二烯氢甲酰化反应的区域选择性主要由不可逆的丙二烯插入步骤决定，动力学和热力学因素都有利于形成anti-Markovnikov中间物种(η〓-CH〓CHCH〓)Co〓，形成Markovnikov中间物种Co〓是不具有竞争性的。

The palladium-catalyzed allylation is a powerful tool for C-C, C-N, and C-O bond formation, which has been widely applied to organic chemistry.

藉由钯催化烯丙基化反应合成碳—碳键、碳—氮键和碳—氧键是非常有利的方法，主要是因为它在有机化学上广泛的应用性。

The palladium-catalyzed allylation is a powerful tool for C-C, C-N, and C-O bond formation, which has been widely applied to organic chemistry.

而利用金属钯当作催化剂来进行烯丙基化反应，形成碳-碳键，碳-氮键和碳-氧键，在有机化学中是很广泛的合成方法。

Because these substrates are synthesized from the corresponding allylic alcohols, palladium-catalyzed conversion of allylic alcohols directly into allylation products are highly desirable, especially from the viewpoint of the atom economy.

因为这些受质是从烯丙醇合成的，钯催化烯丙醇转换直接变成烯丙基化合物从原子经济的观点来看是较有益处的。

SA catalyzed the amidation of benzhydryl alcohol in good to excellent yields under solvent-free condition.

加热条件下磺氨酸可以催化磺酰胺和酰胺类化合物与二苯甲醇的取代反应，生成新的取代胺类化合物。

A new catalytic spectrophotometric method for the determinati-on of trace copper is described. This method is based on the oxidation of Phloxine by hydrogen peroxide in ammoniacal medium, catalyzed by copp-er.

本文提出了催化光度法测定痕量铜的新方法，此法是基于萤光桃红在氨性介质中被H_2O_2氧化的反应受到痕量Cu的催化。

The test results showed that under low ambient temperature and aphotic storage conditions jet fuel exhibited good color stability.Oxidation reactions,such as photo-catalyzed oxidation and radical oxidation,were the main reaction mechanism of color degradation,and copper played an important role in catalyzing the oxidation reactions.Under static thermal stability testing condi...

试验结果表明，喷气燃料在较低温度、无光储存条件下具有很好的颜色安定性；氧化反应是导致喷气燃料颜色变深的主要反应机理；静态热安定性试验条件下，喷气燃料的颜色随氧化时间呈相对稳定的加深趋势；氧化铝吸附脱除了喷气燃料中的一些原有氧化抑制剂，使喷气燃料在较高温度、有氧条件下易于发生氧化反应；铜在喷气燃料氧化变色反应过程中具有明显的催化作用。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。