查询词典 catalyze

Since aromatic ring is a very stable compound, it would needs very high activation energy to begin the ring opening reaction. It is therefore interesting to investigate how the micro-organism can catalyze this reaction in room temperature at natural buffer condition.

由於芳香环是一种非常稳定的化学结构，如果想要进行开环反应必要要经过极大的活化能，而了解生物体中是如何在常温的环境下进行这样的反应将会是非常有趣的题材。

It is based on the facts that in the presence of sulfuric acid and sodium dodecyl benzene sulfonate, vanadium activated by vitamin C can catalyze potassium bromate to oxidize safranine O, the oxidation products of safranine O can emit intense and stable fluorescence on nitrocellulose membrane.

基于在硫酸介质和十二烷基苯磺酸钠存在下，抗坏血酸活化钒催化溴酸钾氧化番红花红O发射强而稳定的荧光的特性，建立了ⅤC活化溴酸钾氧化番红花红O催化荧光法测定痕量钒的新方法。

When SiO〓-NH〓-Rh-Co complex was used to catalyze the hydroformylation of methyl methacrylate, an optimal conversion of 93.4% and optimal selectivity of 84.4% for the normal aldehyde were both obtained at Rh/Co ratio of 2/1, which were both higher than that catalyzed by SiO〓-SiNH〓-Rh and SiO〓-Si-NH〓-Co momometallic catalysts. Clearly a synergistic action between Rh and Co atoms presented in the complex.

我们以SiO〓-Si-NH〓-Rh-Co催化甲基丙烯酸甲酯的醛化反应，当催化剂中Rh/Co比为2/1时，催化活性最高，可达93.4％，对正构产物β-甲酰异丁酸酯的选择性达到84.4％，都高于单金属催化剂，表明了金属间存在相互作用。

He minim acidity in TS-1 can catalyze the solvolysis reaction of PO to propylene glycol, 1-methoxy-2-propanol and 2-methoxy-1-propanol.

S-1中含有的微量酸中心能够导致环氧丙烷与溶剂反应生成丙二醇、1-甲氧基-2-丙醇和2-甲氧基-1-丙醇。

The results showed that hydrogen peroxide, silanols species and TiO〓 didn't have solvolysis activity of propylene oxide. While framework Al, coordinatively unsaturated Ti〓 ions as Lewis acid sites in the framework, Ti-OH and the five member ring active titanium species formed by TS-1, hydrogen peroxide and solvent can catalyze the solvolysis of propylene oxide.

研究结果表明：原料双氧水和TS-1沸石上的SiOH和TiO〓对环氧丙烷溶剂解反应无催化活性；而下列物种对环氧丙烷溶剂解反应具有催化活性：TS-1中的骨架铝，沸石骨架中配位不饱和的Ti〓形成的L酸中心，TS-1水解产生的钛羟基和由TS-1，双氧水和溶剂相互作用所生成的五元环中间活性钛物种。

Being combining with products distribution in styrene oxidation, we propose the styrene epoxidation carry out with Ti metallacyclo intermediates, And at the same time Ti-ZSM-5 have properties both catalytic epoxidation and acid-catalysis, namely the skeletal Ti can catalyze styrene epoxidation to styrene oxide and the skeletal Ti and Al can provide Lewis acid site to cause the rearrangement of styrene oxide to phenylacetaldehyde rapidly, the solvolysis to glycols and the cleavage of C=C double bond. Ti-ZSM-5 can also provide Bronsted acid site simultaneously, which is also catalytic center for the solvolysis to glycols.

同时结合Ti-ZSM-5催化选择性氧化苯乙烯反应的产物分布结果，提出苯乙烯环氧化反应可能是通过金属有机环机理进行；Ti-ZSM-5同时具有催化环氧化和酸催化两种功能，其骨架钛可催化苯乙烯环氧化生成环氧苯乙烷，而骨架钛和骨架铝等可提供Lewis酸位使环氧苯乙烷迅速发生重排生成苯乙醛从而使其成为反应的主要产物，同时还可发生加成以及碳碳键的裂解等副反应：Ti-ZSM-5也提供Bronsted酸位，它也是生成加成产物的活性中心。

The catalysts such as tetraphenyl tin,aluminium isopropoxide and boron trifluoride etherate complex were used to catalyze the copolymerization.In addition,the copolyester can be given by copolycondensation after monomers were hydrolyzed by phosphoric acid.Boron trifluoride etherate complex was chosen as the catalyst because the catalytic activity was the best among the catalysts.

由于γ-戊内酯为五元环结构，难以进行开环聚合，因此分别考察了四苯基锡、异丙醇铝、三氟化硼乙醚络合物等催化剂，以及以磷酸为催化剂的水解缩聚反应，结果发现三氟化硼乙醚络合物的催化活性最高，因此选择三氟化硼乙醚为本体开环聚合的催化剂。

Macroporous tributyl amine aminating strongly basic anion exchange resin-a phase transfer catalyst with high catalytic activity for nucleophilic substitution,which was screened out via combinatorial chemistry method –was used to catalyze the nucleophilic substitution reactions for synthesis of benzyl acetate,benzyl propionate,benzyl butyrate and benzyl valerate.

用组合化学方法筛选出的对无外加碱条件下的亲核取代催化活性最高的聚合物季铵盐–三丁胺胺化强碱性阴离子交换树脂为相转移催化剂，催化合成了乙酸苄酯、丙酸苄酯、丁酸苄酯、戊酸苄酯等羧酸苄酯。

Imino-1, 3-thiazetidines is the basic structure of a kind ofbioactive herbicide and insecticide. Our method has advantage in synthesis highly substituted2-imino-1, 3-thiazetidines, therefore it has practical value to some extent. We also researched the reactions catalyze by active zinc dust.

提供了成四员噻吖丁啶杂环衍生物的方法。2-亚胺基-1，3-噻吖丁啶是一类具有生物活性的除草剂及杀虫剂的核心结构，我们的方法在合成多取代的2-亚胺基-1，3-噻吖丁啶方面有一定的优越性，从而具有一定的实用价值本文另一部分的工作是探讨锌粉催化的反应。

When MAA yeast was used to catalyze other systems, such as reducing ethyl 4-chloroacetoacetate to ethyl-4-chloro-3-hydroxybutyrate and ethyl acetoacetate to ethyl-3-hydroxybutyrate, the yield also improved at various degrees.

用此酵母在水相中催化乙酰乙酸甲酯的还原，其得率较普通面包酵母要高。pH和温度对MAA酵母与普通面包酵母都有相同的影响。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。