查询词典 catalytic

The results indicated that the copper complexes have the best catalytic effect, and the high temperature of decomposition is dropped 129.01℃at most, the second is nickel complexes, and the catalytic effect is the smallest for the plumbum complexes.

有的催化剂的加入改变了AP的热分解过程，使AP的低温和高温分解峰合并成了一个峰，如7#、13#含铜配合物和8#含镍配合物，对AP的催化效果比较有效。

A new catalytic kinetic method with second derivative oscillopolarography detection for determining trace amounts of NO〓〓 has been developed. The method is based on the catalytic oxidation of Amarath by potassium bromide in the diluted H〓SO〓. The detection limit of the method is 2.8×10〓g/ml, the linear range of the determination 〓is 0.6～14ng/ml for NO〓.

首次研究了鸡冠红的示波极谱行为，并发现NO〓〓在稀硫酸介质中对KBrO〓氧化鸡冠红褪色反应具有强的催化作用，本文采用两阶导数示波极谱法作监测技术，测定了该催化体系的表观反应级数及动力学方程，建立了催化动力学伏安法测定痕量NO〓〓的新方法。

A simple and highly sensitive new kinetic catalytic fluorimetric method was proposed for the determination of trace chromium,based on the catalytic effect of trace amounts of chromium on the oxidation of Pyronine Y by hydrogen peroxide in acetic acid-sodium acetate buffer medium leading to a decrease in the fluorescence intensity.

在HAc-NaAc缓冲体系中，痕量铬对过氧化氢氧化吡咯红 Y的氧化还原反应有催化作用，使吡咯红 Y荧光减弱，据此建立了催化荧光法测定痕量铬的新方法，同时考察了该催化反应的最优条件及动力学性质。

For further studied on nano-Ni catalytic hydrogenation of pyroole and its derivatives at normal temperature and pressure, we have did relevant catalytic hydrogenation experiments to pyrrole, pyrrolidine and pyrrolidone.

为进一步研究常温常压下吡咯及其衍生物的镍催化加氢反应，我们对试剂吡咯、吡咯烷和吡咯烷酮做了相应的催化加氢实验。

It was found that different catalysts has different catalytic activity in saponification, thereinto, solid superacid D4 has optimum catalytic activity.

论文还对用于酯化反应的催化剂——固体超强酸的制备，以及影响其催化活性的因素进行了研究。

Researches in photosensitized catalytic oxidation under irradiation of sodium lamp were reviewed, especially the characteristics and mechanism of photosensitized catalytic oxidation of olefins, alkylphenols and complexes and their application.

加强光敏催化氧化反应的研究，在一些重要的有机化合物或有机中间体的合成中具有重要的意义和广阔的应用前景。

Being combining with products distribution in styrene oxidation, we propose the styrene epoxidation carry out with Ti metallacyclo intermediates, And at the same time Ti-ZSM-5 have properties both catalytic epoxidation and acid-catalysis, namely the skeletal Ti can catalyze styrene epoxidation to styrene oxide and the skeletal Ti and Al can provide Lewis acid site to cause the rearrangement of styrene oxide to phenylacetaldehyde rapidly, the solvolysis to glycols and the cleavage of C=C double bond. Ti-ZSM-5 can also provide Bronsted acid site simultaneously, which is also catalytic center for the solvolysis to glycols.

同时结合Ti-ZSM-5催化选择性氧化苯乙烯反应的产物分布结果，提出苯乙烯环氧化反应可能是通过金属有机环机理进行；Ti-ZSM-5同时具有催化环氧化和酸催化两种功能，其骨架钛可催化苯乙烯环氧化生成环氧苯乙烷，而骨架钛和骨架铝等可提供Lewis酸位使环氧苯乙烷迅速发生重排生成苯乙醛从而使其成为反应的主要产物，同时还可发生加成以及碳碳键的裂解等副反应：Ti-ZSM-5也提供Bronsted酸位，它也是生成加成产物的活性中心。

The different catalytic systems are discussed. The results show that sodium tungstate has effective catalytic ability.

实验结果表明，钨酸钠和双季铵盐催化体系能在温和的条件下，催化稀过氧化氢溶液氧化环己醇、苯甲醇、环己烯。

Using the one-atom theory, the electronic structures of Pt-electrocatalyst with fcc structure was determined as follows:(5dn)6.48 (5dc)2.02 (6sc)1.48(6sf)0.02. Compared to the result obtained by the first-principle method such as FP-LMTO, CASTEP, their results are in good agreement with each other. Comparing the calculations of physical properties such as lattice constants, cohesive energy and bulk modulus by OA method and first-principle method, the result obtained by OA method is in excellent agreement with experimental value, but the result obtained by first-principle method is not accordable. The relationship between the electronic structures and catalytic performance was explained qualitatively by OA method and first principle method according to its electronic structures. Because the d-orbital vacancies increases and static density is high around Fermi energy band, Pt has good catalytic performance.

摘 要：依据纯金属单原子理论确定面心立方结构电催化剂Pt的电子结构为(5dn)6.48(5dc)2.02-(6sc)1.48(6sf)0.02，与采用第一原理的FP-LMTO和CASTEP等方法所计算的电子结构相比较，其结果非常相近；由OA理论和第一原理方法计算的晶格常数、结合能、体弹性模量等物理参数进行比较，OA理论计算的结果与实验值较符合，而第一原理方法计算的结果与实验值相差较大；在此基础上用OA理论和第一原理方法研究了Pt的电子结构与催化性能的关系，由于d带空穴增多和费米能级附近态密度较高，导致金属Pt的催化性能很好。

The structure reveals the catalytic intermediate of DAPDC, in which L-lysine is covalently bonded to PLP to form an external aldimine. This conformation provided the best insight to date on the substrate binding and catalytic mechanism of DAPDC. It also supplied valuable clues for designing specific DAPDC inhibitors.

通过分析我们发现这是DAPDC酶家族的第一个反应中间态结构，即反应产物L-赖氨酸与辅酶PLP共价结合形成了外源醛亚胺的构象，这为了解DADPC的底物结合情况及催化机理提供了迄今为止最详细深入的结构信息，也为针对DAPDC设计特异性抑制剂提供了宝贵的线索。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。