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Synthesis of novel 4-long alkoxyl-L-prolines and their application in catalytic asymmetric direct aldol reaction.

一、研究了新型长链烷基脯氨酸的合成及其作为有机小分子催化剂催化的直接不对称Aldol反应 1。

The catalytic mechanism of prolinamide phenol on the direct aldol reaction was studied using quantum mechanics theory.

利用量子力学理论研究了脯氨酰胺酚类催化剂催化直接不对称Aldol反应的机理。

In order to examine the catalytic activity of the new catalysts, we have carried out the direct asymmetric Aldol reaction of tetrahydro-4H-thiopyran-4-one with aldehydes.

催化剂的基本结构单元如下：为了检验新型有机催化剂的催化活性，我们研究了硫代四氢吡喃酮和各种醛的直接不对称Aldol反应。

The catalytic efficiency of 7a was the best when acetone was used as Aldol donor, and the Aldol products were obtained with up to 78% ee in the presence of 10 mol% 7a.

对丙酮与醛的反应，7a的催化效果最好，在10％催化剂存在下产物ee值高达78％。

The catalytic effects of 1a and 1b on the intermolecular direct asymmetric aldol reaction were evaluated in organic solvents and in water respectively. The activity of 1a was higher than that of 1b.

研究了1a和1b分别在有机相和水中催化分子间直接不对称Aldol反应的性能，发现具有较长烷基链的1a比具有较短链的1b催化活性高。

This catalytic oxidation of alicyclic alkene used H2O2 (30 %) as "green" and "friendly" oxidant. This work had four aspects as follows

本文采用环境友好的、绿色的过氧化氢（H2O2 30 %）为氧化剂，做催化氧化脂环烃的研究，主要开展了如下四个方面的工作

The catalytic efficiencies of a variety of fatty ketones, alicyclic ketones and heterocyclic ketones and the impact factors were reviewed in the paper.

本工作对各种脂肪酮、脂环酮、杂环酮对烯烃环氧化催化能力的大小及其影响因素进行了评述。

The catalytic activity was found to increase with the alkalescence of solvents.

提出在碱金属碳酸盐K_2CO_3的作用下可能遵循两步循环反应的反应机理。

We consider that the proper substrate temperature is more important for the catalytic oxidation effects than the alkali metal coverage.

在有无催化剂K以及在室温和500K的温度下得到了一系列的实验结果。

Promotion effects of alkaline earth metals and rare earth metals on catalytic activity and coking resistance of the catalyst are also described.

阐述了碱土金属和稀土金属助剂在提高催化剂的重整活性和抗积炭能力方面的作用。

You can do some assertiveness training.

你可以进行一些自信训练。

We were well on the path to making a rear-wheel-drive global platform," says Mays."

我们正致力于建立一个后轮驱动的平台，"Mays这样说道。"