查询词典 catalytic

Because of advantages such as containing metal-free, so the organocatalyst has not the potential risk of leaching of toxic metal ion to the environment; generally has good catalytic activity, some might exhibit peculiar character and catalytic mechanism as enzyme; easily handled, can be performed in solution or air without the necessity of severe conditions like water-free and oxygen-free.

因为其不含金属离子，不存在有毒金属离子泄漏而造成环境污染；一般具有较高的催化活性，有些显示出类似酶的特性和催化机理；反应容易操作，可在溶液或空气中进行，不需要无水无氧等苛刻条件；价格一般比较便宜，易于制备、修饰和改性，可调控性大；易于与产物分离及从反应体系中回收等一系列&绿色&的优点。

The metals, such as Fe, Cu and Co, which can be reduced by KBH〓, can not change the catalytic properties obviously if only small amount of them are added to Ni-B alloys; those who can not react with KBH〓, such as Zn〓, are washed out during the preparation, so they also can not change the catalytic properties; while addition of the elements in VIB group, such as Cr, Mo and W, can increase the hydrogenation activity magnificently.

同样，我们通过添加第三组分来修饰Ni-B合金，可以被还原的金属，如Fe、Co、Cu等，少量添加并不能明显改变其反应性能；而与KBH〓不发生反应的金属，如Zn，以离子形式加入后，除了少量离子被吸附在催化剂表面外，基本不残留在催化剂里，因此对反应性能也没有太大的改变；只有VIB族元素，如Cr、Mo、W的加入才会很大改进Ni-B催化剂在蒽醌加氢中的催化性能，尤以Cr的修饰作用最好。

Points of knowledge: To know the definition, performance, category and preparation of solid catalyst; characteristic of solid catalyst, basic course of gas-solid catalytic reaction, physical construction of catalyst; to understand the derivation of intrinsic kinetics of gas-solid catalytic reaction by using the Langmuir 's adsorption isothermal line.

知识要点：了解并掌握固体催化剂的定义、性能要求、种类和催化剂的制法；固体催化剂的特性，气-固相催化反应进行的基本过程，催化剂的物理结构；掌握朗哥缪尔吸附等温线推导气固相催化反应本征动力学的方法。

It is showed that reactivities of the inorganic membrane catalytic reactions are always better than the conventional catalytic ones when carried out under the same conditions.

结果表明，在相同的反应条件下，膜催化反应的转化率和选择性均高于常规催化反应。

This paper introduces the studies of Gerhard Ertl, who is awarded the Nobel Prize in Chemistry 2007, in adsorption of hydrogen on metal surfaces, the mechanism of catalytic reaction in Haber- Bosch process for synthesis of ammonia, and the process of catalytic oxidation of CO.

格哈德·埃特尔的重要贡献主要有3方面：(1)解决了氢原子是如何在Pd、Pt和Ni等金属表面组织排列的问题；(2)对哈伯一博施法合成氨反应催化机理的研究；(3)对C催化氧化的研究及非线性动力学理论的建立。1 氢在金属表面吸附的研究萨巴蒂埃因发现精细金属颗粒催化有机物加氢的方法而获1912年度诺贝尔化学奖。

A catalytic amount of Ln(OSO2CF3)3 affected the stereochemistry of-MOPMAM during radical polymerization: the polydispersities of the polymers prepared in the presence of the Lewis acid were broader than those without the Lewis acid and the absolute value of specific rotation decreased in a majority of solvents.

结果表明，在-MOPMAM的聚合反应中，加入稀土盐可观察到明显的效应：在大部分情况下，随着三氟甲磺酸稀土盐加入量的增加，聚合物分子量分布变宽，旋光度也有很大幅度的下降。

The mechanism of PNPP catalytic hydrolysis has been proposed based on the analytic result of specific absorption spectrum.

通过对水解反应体系的特性吸收光谱的分析，表明在PNPP催化水解的反应过程中形成了由PNPP和Co配合物组成的关键中间体。

The synthesis of acrolein by means of the catalytic vapor phase condensation of formaldehyde and acetaldehyde was studied.

利用冷凝甲醛和乙醛的气相催化法，来研究丙烯醛的合成。

The catalytic esterification of acetic anhydride and nine phenols were investigated in the presence of complex resin catalyst at 20 ℃,and its mechanismes were discussed.

研究了 2 0℃时，醋酸酐与九种酚在复合树脂催化剂下的催化酯化反应，并探索了其反应的机理。

Catalytic activity can be improved by increasing the number of medium-strong acid site.

催化剂的使用寿命与催化剂酸性及结构有关。

The work of this paper is as follows: 1. Looking back the progressing history of the linear motor, introducing the features of the elevator driven by linear induction motor, radicating the topic of this paper "the digital frequency variable control of the elevator bi-side direct driven by linear induction motor". The research of this paper covers the conventional VVVF control, space vector based VVVF control, vector control and DTC.

本文主要开展了以下几个方面的工作： 1 回顾了直线电机发展历史，电机的驱动技术演变，特别是针对直线电机的驱动，简要介绍了直线感应电机驱动电梯的优点和不同结构类型，对传统的v／f控制，基于空间矢量法的v／f控制，矢量控制，和基于电压空间矢量的直接转矩控制进行了比较，确立了本课题的研究主题：直线感应电机双边直推式驱动电梯的全数字变频控制。

The article combines with the treatment of a superficial civil air defense work to introduce how the grouting method to improve the performance of the backfill soil.

文章从治理漂浮人防工事的角度提出了注浆技术在改善回填土性质方面的应用，并详细阐述了注浆技术的施工流程。