查询词典 catalytic

A new catalytic spectrophotometric method for the determination of iridium was established based on its catalytic effect on the oxidative fading reaction between methyl blue and KIO_4 in H_2SO_4 medium and heating on the hot-water bath.

在硫酸和热水浴中，铱对高碘酸钾氧化甲基蓝的反应具有催化作用，依此建立了测定痕量铱的新催化光度法。

At first, the rought C〓F〓 mixed gases are obtained by pyrolysis process of R22. A experimental pyrolysis device is designed and made by ourself. The optimum operating conditions are offered in the paper. Secondly, the much efforts is on the synthesis of R134. After through the discussion of basic thermodynamics and kinetics, selecting and preparating catalyst, it is possible that the synthesis of R134 by pyrolyzed gases hydrogenation. Base on the character of catalytic process, the kinetics equation about C〓F〓 catalytic hydrogenation is established. The rate constant of the reaction is obtained through experiment data regression. In order to achieve higher yield of R134, some optimum technological conditions is determined.

论文首先对R22裂解制成四氟乙烯混合原料气的裂解过程进行了讨论，自行设计和制作裂解反应装置，并确定裂解反应的最佳操作条件；然后，重点对R134的合成进行基础研究，分别从热力学和动力学的角度探讨以含四氟乙烯的R22裂解混合气为原料合成R134这一全新工艺的可能性，选择和制备加氢催化剂，根据催化过程特点建立四氟乙烯催化加氢反应的总包动力学方程，并在此基础上自行设计和制作中试合成装置，获得了以裂解混合气为原料合成R134的最佳工艺条件，为R134的工业化生产提供了必要的理论依据和实验基础。

Alkylation of phenol was used to research catalytic activity of Y/MCM-41. The results have shown that Y/MCM-41 has higher catalytic activity than the traditional Y and MCM-41. For the Y/MCM-41, not only the conversion of phenol raised with tert-butyl alcohol and reaction temperature raising, but also Useful time of Y/MCM-41 was longer. For the Y/MCM-41, the conversion of phenol raised with reaction time raising, But that increased slowly after 3 hours.

结果表明：Y/MCM一41分子筛具有比Y型或MCM一41更高的催化活性；而对于Y/MCM一41分子筛，随着叔丁醇和温度的增加，苯酚的转化率也增加，且使用寿命也较长；对于Y/MCM-41分子筛，随着反应时间的增加，苯酚的转化率增加，但反应3小时之后，苯酚转化率增加就不明显了。

In the one hand, for catalytic double carbonylation of phenyl iodide or catalytic hydroesterification of styrene, the effect of pressure on products ratio reflected the difference in the volume of activation of different reaction routes.

对于碘苯双羰基化反应或苯乙烯氢酯基化反应，由于不同产物反应的活化体积不同，压力对于不同反应速率常数的影响亦不相同，因此压力增大会有利于其中某个反应。

The result of XPS showed that a large amount of inactive iodine absorbed on the surface of the reused electrode, and Pt and Pt resulted from the thermal-sealing process led to the decrease of the catalytic activity of the platinized catalytic electrodes.

结果表明二次利用电极表面吸附的大量非活性的碘和加热密封过程中电极表面生成的低催化活性的Pt和Pt，是使电极的活性下降的主要原因。

Two kinds of catalytic oxidations for naphthalene with Fenton reagent and POD catalyst were studied, and the results showed that there were some common points: Fe ion and OH radical all participated in two kinds of catalytic oxidations and α-naphthol was found.

通过Fenton试剂及POD催化H〓O〓与萘的反应过程分析，可以确定两种反应之间有一些相同点，它们是两种反应过程中均有Fe离子及·OH自由基参与，且反应过程中均有α萘酚生成。

An oxidation catalytic converter is mainly used for catalytic conversion of unburned THC and CO in the exhaust gas, and its primary principle is to reduce the hazardous materials by farther oxidating of the unburned intermediate reactive products in the exhaust gas.

氧化型催化转换器主要用来催化转换排气成分中的THC和CO，其主要工作原理是进一步氧化排气成分中的未完全燃烧的中间产物，以降低排气成分中的有害物质。但是，其工作的热力学环境将大大影响工作性能和效率。

TiO〓/K-M supported Ag/SiO〓 composite ceramic membrane tubes have been prepared and used as a membrane reactor for selective separation of C〓H〓 during the catalytic reaction process of CO〓 partially oxidating C〓H〓. By removing C〓H〓 produced in the catalytic reaction, thermodynamic balance of the reaction is upset and some side reactions from C〓H〓 are avoided, thus the conversion rate of C〓H〓 and the selectivity to C〓H〓 are effectively increased.

本研究设计、制备了硅藻土—莫来石陶瓷管负载的Ag/SiO〓复合膜，并将其应用于二氧化碳部分氧化乙烷催化反应过程中产物乙烯的选择性分离，有效地提高了催化反应的反应物乙烷转化率和产物乙烯选择性。

The mechanism of the phase transfer catalytic polycondensation was investigated, and a diagram of the phase transfer catalytic cycle was suggested. The reaction locus was found to be in the organic phase.

相转移催化反应是近年来发展起来的一种有机合成新方法，特别在有机合成方面已得到广泛的应用，有些已在工业上得到了推广。

Because of advantages such as containing metal-free, so the organocatalyst has not the potential risk of leaching of toxic metal ion to the environment; generally has good catalytic activity, some might exhibit peculiar character and catalytic mechanism as enzyme; easily handled, can be performed in solution or air without the necessity of severe conditions like water-free a...

因为其不含金属离子，不存在有毒金属离子泄漏而造成环境污染；一般具有较高的催化活性，有些显示出类似酶的特性和催化机理；反应容易操作，可在溶液或空气中进行，不需要无水无氧等苛刻条件；价格一般比较便宜，易于制备、修饰和改性，可调控性大；易于与产物分离及从反应体系中回收等一系列&绿色&的优点。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。