查询词典 catalysts

Work 工作:(1) feasible process development for high-pure tetraalkyphosphonium salt as catalysts for polymerizations, potential sale 2-4 million us$;(2) simple and feasible preparation process for phosphonium salt as ionic liquids, biocides and phase transfer catalysts;(3) new and industrially feasible processes for highly sterically hindered alkylphosphines as catalyst ligands, these include tricyclohexyl-phosphine, phosphorinanes and dsmphos2,3- bis(9-phosphabicyclononylbutane;(4) sterically hindered dialkylphosphinic acid as new generation of co/ni extractant;(5) alkylphosphonium wittig reagents and the wittig reactions with them;(6) exploration of the application of borane chemistry in the synthesis of highly sterocally hindered organophosphines;(7) customer preparation of samples of a variety of organophosphorus compounds for customers all over the world.

用作高分子聚合反应催化剂的高纯度四烷基瞵盐的实用生产流程。产品销售前景 2-4 百万美元；(2)用作离子化液体，杀菌剂和相转移催化剂的烷基瞵盐的简单实用合成方法；(3)高位阻烷基磷化氢催化剂配体的工业实用合成路线的研究，这包括，三环己烷基磷， phosphorinanes 和 dsmphos 2，3-bis(9-phosphabicyclononylbutane ；(4)高位阻二烷基膦酸金属萃取剂的工业实用合成路线的研究；(5)烷基膦 wittig 反应试剂的研究；(6)硼化学在高位阻烷基磷化氢合成中的应用；(7)为世界各地提供顾客合成服务。

Advances in ethylene selective trimerization catalysts, especially composition, activity and cost of trimerization catalysts and their overall selectivity to 1-hexene.

对乙烯选择性三聚反应进行了论述，着重分析了催化剂的组成、活性、成本和1-己烯的总选择性，并展望了烯烃选择性齐聚反应的发展。

Progress in researches on catalysts for fluidized bed oxychlorination of ethylene to make dichloroethane;2. The catalytic performance of CuCl2-KCl/MgO-Al2O3 catalysts was evaluated for the oxychlorination of ethane to produce vinyl chlorid.

采用浸渍法制备了不同含量MgO改性的γ-Al2O3，采用X射线衍射、N2物理吸附、NH3的程序升温脱附和程序升温还原等手段表征了催化剂的结构、表面酸性和氧化还原性质，并对CuCl2-KCl/MgO-Al2O3催化剂催化乙烷氧氯化制氯乙烯反应进行了活性评价。

The influence of CFC-12 content, effect of fluorination temperature and fluorinating time on the structure and hydrodesulfurization activity of the catalysts were examined systematically. The results revealed that hydrodesulfurization activity of the catalyst fluorinated by 1% CFC-12 at 623 K was obviously improved With an increase of 20%-30% as compared With that of the unfluorinated catalyst, the commercially available BY2 catalyst, and NH4F-fluorinated catalysts.

通过对0.5%~7%各种氟里昂浓度和473~773K各种温度及不同时间氟化处理的样品进行详细考察，发现在623K下由含氟里昂1%的湿空气氟化的载体制备的催化剂样品，其噻吩的加氢脱硫的活性有明显改善，相对於非氟化样品、BY-2工业催化剂以及氟化铵溶液浸渍处理的催化剂活性提高20%~30%，且非常稳定。

The HDS activity of Co-MoP/ Al_2O_3 catalysts is more effective than commercial catalysts and sulfured ones.

以二苯并噻吩和喹啉混合物为反应物，Co-MoP／γ-Al_2O_3具有较好的HDS活性。

Two hydrofining catalysts, oxidation state RS-1 and sulfurized state RS-1, developed by Research Institute of Petroleum Processing were applied in the pre-hydrofining of 1.20 Mt/a CCR unit of SINOPEC Zhenhai Company, and the startups of using these two catalysts were reviewed.

介绍了石油化工科学研究院开发的硫化态、氧化态RS-1型加氢精制催化剂在镇海1.20 Mt/a连续重整装置预加氢精制单元中的开工情况。

The application, proposed hydrotalcite-like compounds as a new type of environmentally friendly solid catalysts in the aldol condensation, nitrile hydrolysis, epoxide ring-opening reaction of the oxidation of aromatic compounds, alcohols oxidation, reduction of nitro compounds, and many other important reactions in organic synthesis has an important application potential, and with little pollution compared to conventional catalysts, easy separation of advantages of high reactivity.

叙述了水滑石类化合物作为固体酸碱催化剂、氧化还原反应催化剂、催化剂载体等方面的应用情况，提出了水滑石类化合物作为一类新型的环境友好的固体催化剂，在醇醛缩合、腈类水解、环氧化物的开环反应、芳烃类化合物的氧化、醇类氧化、硝基化合物的还原等许多重要的有机合成反应具有重要的应用前景，并且与传统催化剂相比具有污染小、易分离、反应活性高等优点。

Part Ⅰ The Research of Chiral Phosphorus Catalysts in the Enantioselective Borane Reduction of Prochiral Ketones ABSTRACT In this paper, the preparation of varied types of chiral phosphorus ligands and their applications as catalysts in the asymmetric borane reduction of prochiral ketones were investigated.

第一部分对映选择的潜手性酮的硼烷还原反应中手性磷催化剂的研究本文研究了多种不同类型的手性磷配体催化剂的合成及其在酮的不对称硼烷还原反应中的应用。

Latest researches in the catalysts for synthesis of carbamate by ammonolysis of dimethyl carbonate;2. Progress in the catalysts for synthesis of carbamates by ammonolysis of dimethyl carbonate;3.4,4′-Methylene diphenyl carbamatewas synthesized by ammonolysis of dimethyl carbonate, a substitute of phosgene, and 4,4′-diaminodiphenyl methane with anhydrous zinc acetate as catalyst.

用碳酸二甲酯代替光气，以4，4′-二氨基二苯基甲烷为原料，在无水醋酸锌催化剂的作用下，经胺解反应合成了4，4′-二苯甲烷二氨基甲酸甲酯；测定了MDC的熔点；采用傅里叶变换红外光谱和氢核磁共振对产品结构进行了表征；考察了反应温度、DMC用量、反应压力、反应时间、催化剂用量对MDC收率的影响。

The application of them as catalysts in the asymmetric ring-opening of epoxides was investigated. Through the screening of the catalysts, we found that some of them demonstrated good asymmetric induction ability in this reaction.

我们对非手性二硫代磷酸在手性Schiff碱和Ti〓的存在下对环氧化合物的不对称开环反应进行了研究，对手性Schiff碱进行了进一步的筛选。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。