查询词典 catalysts

This thesis studied the alkylationperformances of supported heteropoly acid and zeolite catalysts as well as correlativeprocesses, which is significant for theory and practical application.

本论文研究杂多酸及分子筛两类固体酸催化剂的烷基化性能及其相关工艺，具有实际应用和理论意义。

Latest researches in preparation of hexa aluminate catalysts were reviewed, especially the raw material and preparation technology, including co-precipitation, sol-gel and microemulsion methods.

摘要综述了近年来六铝酸盐催化剂的研究近况，重点介绍了其制备材料及制备技术，包括共沈淀法、溶胶－凝胶法和微乳法。

Then, hydroisomerization pathways and kinetics of normal hexadecane were established on the base of productions yields for both catalysts.

研究了不同催化剂的正十六烷加氢异构反应动力学，并建立了相应的反应网络。

These compounds are of substantial interest both inviewpoints of theory and practical applications, mainlyunder the stimulus to achieve synthetic models either foractive sites of iron-sulfur proteins or for transitionmetal catalysts. This thesis describes the synthesis, structures andconformations of 51 new iron-sulfur cluster complexes,which have been characterized by elemental analysis andstandard spectroscopic methods. In addition, single-crystalX-ray diffraction analyses were performed for 4 representa-tive new compounds. Reactivities of μ-〓 with mono- and di- Grig-nard reagents derived intermediates toward various organicelectrophilic substrates were studied, along with complexa-tion of arynyl-containing iron-sulfur clusters by 〓Thus, several bridged, non-bridged, monomeric, dimeric,homonuclear, heteronuclear iron-sullfur and iron-sulfur co-balt-carbon cluster complexes were synthesized. A novelreaction and convenient route for the synthesis in highyield of tetranuclear iron complexes 〓 containing atetracoordinated sulfur atom was discovered, whereas aplausible mechanism based on experimental results was propo-sed for the formation of the new cluster type.

鉴于有机铁硫原子簇化学在基础理论发展和应用方面的重要意义，因此我们开展了这一课题的研究，并取得以下主要成果： 1、本文共合成了51个新有机铁硫及含钴碳簇基的有机铁硫原子簇配合物，除用元素分析，NMR，IR，MS法表征其结构和构象外，还用X-光衍射技术测得四个代表性配合物的单晶结构和构象； 2、我们业已发现炔基Grignard试剂同〓可形成一种&开环&与&闭环&中间物的平衡混合物，研究该平衡混合物同各种亲电试剂的反应； 3、研究发现了一种可高产率地形成〓含〓四配位硫挛合簇的新化学反应并对此反应提出了—种有趣的反应机理； 4、首次由1，4-二溴丁烷双Grignard试剂与〓制得一种新型铁硫簇双硫阴离子活性中间体，并进而研究了它的亲核反应性能； 5、找到了通过〓的光化学反应来合成簇合物〓-〓的一条有实用价值的新路线。

Hydrotalcite and hydrotalcite-like materials have good heat stability and large specific surface area, and can be used as catalysts and catalyst carriers.

水滑石及类水滑石材料具有很好的热稳定性和较大的比表面积，可以作为催化剂或催化剂载体。

Alumina-supported Pd catalysts were prepared by three different methods: impreg nation, sol-gel-impregnation and sol-gel.

摘 要：采用三种不同方法制备了氧化铝负载的Pd催化剂。

The good catalytic performances were obtained on those catalysts supported by SiO_2. With the increasing calcination temperature from 300℃to 700℃, Co_3O_4 particles augmented and sintered on the samples surface which contained 10 wt.% cobalt, the crystallite size of Co_3O_4 was aggrandized from 7.2 nm to 20.3 nm by inchmeal. On the other hand, the activation energy for the combustion reaction was increased linearly with the augment of average crystallite size of Co_3O_4, the TOF value on prepared catalyst was decreased with it. Thus, the catalytic combustion was a typical structure-sensitive reaction.

在钴含量为10 wt%的样品上，随着焙烧温度由300℃提高到700℃，钴物种出现迁移团聚甚至烧结，在XRD中测定的Co_3O_4晶粒尺寸由7.2 nm逐步增加至20.3 nm；另一方面，催化剂的燃烧活化能随样品上Co_3O_4晶粒的平均尺寸增加而呈现线形增加趋势，而单位时间内单位活性物种上的甲烷转换频数随着粒径增加而逐渐降低，这一现象证实了该反应属于典型的结构敏感反应。

The novel catalysts of Cu supported on ZnO, MgO modified with KF were prepared by the conventional impregnation method, and applied for the first time to the Heck reactions of iodobenzene with n-butyl acrylate as a model reaction.

KF水溶液浸渍MgO或ZnO载体为改性载体制备了负载铜催化剂，以卤苯与丙烯酸正丁酯的反应为模型，考察了对Heck反应的催化性能。

The developed catalysts demonstrated good activities towards the Heck reaction of iodobenzene and methyl acrylate with about 90% yield, easy separation after reaction and reusability. The metal leaching was not apparent after four runs.

以碘代苯与丙烯酸甲酯的Heck反应为例，考察双腈基固载Pd的催化性能，肉桂酸甲酯的收率近90％，四次循环使用后催化活性没有明显的降低，Pd的析出并不严重，该催化剂易回收使用。

The results indicate that little conversion of iodobenzene was observed on unmodified carrier supported catalysts; and a conversion of 100% and a selectivity of above 98% to trans-isomers were found over 10%Cu/5%KF/ZnO, 20%Cu/10%KF/ZnO.

结果表明，对碘苯与丙烯酸正丁酯的Heck反应的催化性能，未改性催化剂基本没有活性，而改性后，10%Cu/5%KF/ZnO、20%Cu/10%KF/ZnO催化剂的催化转化率为100%和反式异构体的选择性为98%以上。

Lugalbanda was a god and shepherd king of Uruk where he was worshipped for over a thousand years.

Lugalbanda 是神和被崇拜了一千年多 Uruk古埃及喜克索王朝国王。

I am coming just now,' and went on perfuming himself with Hunut, then he came and sat.

我来只是现在，'歼灭战perfuming自己与胡努特，那麼，他来到和SAT 。