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The amination activity and selectivity of the catalysts can be improved by properly optimizing the compositions of the catalysts and corresponding preparation method.

苯酚是本实验条件下的主要副产物,通过催化剂的调变,可增大苯胺的选择性,降低副产物苯酚的选择性。

There are many kinds of catalysts that can catalyze the amination of fatty alcohols, among them the catalysts based on Cu and Ni are most popularly used.

脂肪醇催化剂有多种类型,而以Cu、Ni元素为基础的催化剂的应用最为广泛。

The downshift of diffraction angle of XRD indicates some precious metals enter crystal lattice of LaMnO3, the crystal sizes of catalysts become larger after precious metal loading; BET and SEM results show sintering happened to catalysts after catalytic reaction.

XRD衍射角向低角度出现了少许偏移,显示负载在表面的贵金属部分进入钙钛矿LaMnO3的晶格结构中,使其晶粒增大;BET和SEM结果表明催化剂在反应后出现了轻微团聚现象。

The self-supported chiral catalysts as novel immobilization of homogeneous catalysts strategy demonstrated excellent enantioselectivities in heterogeneous catalysis of a variety of asymmetric reactions.

近年来,手性自负载催化剂作为一种新的负载模式,已经成功地应用于一些非均相催化的不对称反应中。

In summary, the alkylation performances of isobutane with butene over bothheteropoly acid and zeolite catalysts have been investigated in this thesis, and theresults are helpful for further development of the solid acid catalysts for this process.

通过本论文的研究,对杂多酸和分子筛催化剂的烷基化性能有了进一步认识,能对今后开发固体酸的碳四烷基化催化剂有所帮助和借鉴。

Platinum and rhodium catalyst are applied largely and widely, because these two kinds of catalysts are so efficient for hydrosilylation that they were researched since a long time ago. Very recently, N-heterocyclic carbene Pt and N-heterocyclic carbene Rh complexes were used as catalysts in hydrosilylation.

最近,铂和铑的卡宾金属配合物作为催化剂应用于各种不饱和化合物的硅氢加成反应,表现出非常优良的催化性能和稳定的物理化学性质,受到了化学工作者们广泛的关注。

The supported WP catalysts showed considerable activity in HDS reaction of dibenzothiophene and HDN reaction of quinoline. The ibenzothiophene HDS activity and quinoline HDN activity of the spported WP catalysts synthesized by co-impregnation method was better than that synthesized by mixing method. The HDS and HDN activities of 25~30% WP catalysts synthesized by co-impregnation method and reduced at 650~750℃ were better than those of the corresponding sulfurized catalyst.

负载型WP催化剂具有较好的二苯并噻吩加氢脱硫和喹啉加氢脱氮活性,共浸渍法制备的磷化钨催化剂二苯并噻吩加氢脱硫和喹啉加氢脱氮活性要高于混合法制备的磷化钨催化剂。650~750℃还原制备的负载量25~30%的浸渍法磷化钨催化剂具有较高的二苯并噻吩加氢脱硫和喹啉加氢脱氮活性,高于相应的硫化态催化剂。

The activity and stability of the close-coupled catalysts supported by different supports were studied. The results showed that the supports have little effect on the reaction performance of the fresh catalysts, but much effect on the stability of the catalysts.

通过对比不同载体制备的密偶催化剂的反应性能,观测到载体对新鲜催化剂的活性影响并不明显,但催化剂的抗老化性能取决于载体材料的高温稳定性。

And precipitation rate of vanadium was higher than 98.5%. Five vanadium catalysts were made withγ-Al_2O_3 and the mesoporous molecular sieve MCM-41 as carrier, and were made by dipping method, intermingle process and functionalizing method respectively. The characterization of their pore size, crystal structure, specific surface area and V_2O_5 load of catalysts were studied by XRD, the adsorption /desorption of N_2 technique, Raman spectroscopy and XRF. The activities of the catalysts estimated by the synthesis of DPC with DMC and phenol.

钒催化剂的制备与表征及活性评价:是分别以γ-Al_2O_3和介孔分子筛为载体,采用浸渍法,掺杂法及官能化法制备了5种钒催化剂;分别对其进行了XRD分析、N_2吸附-脱附分析、红外光谱分析和荧光分析,对其孔径、晶型结构、比表面积和V_2O_5负载量进行了表征;以碳酸二甲酯和苯酚的酯交换合成碳酸二苯酯的典型反应为依据,对钒催化剂进行了活性评价。

The influence of plasma treatment on phase of catalysts, redox properties and catalytic activities were investigated. In Ni-Ru/ZnO bimetallic catalysts Ni-Ru alloy maybe formed in the catalysts and the reduction of ruthenium oxide enhanced reduction of nickel oxide.

本文还初步研究了等离子体处理制备Ni基催化剂在乙醇水蒸气重整制氢中的应用,考察了等离子体处理对催化剂的晶相,还原能力以及催化活性的影响。

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