查询词典 catalysts

Eight kinds of solid acid catalysts for esterification of acetic acid and isopentyl alcohol are studied in this paper.

本文研究了8种固体酸催化剂催化乙酸与异戊醇的酯化反应，结果表明：FeCl3。

The two catalysts supported on USY zeolites with surface acid amounts of 626 and 203μmol/g, respectively, showed excellent sulfur tolerance, while the catalysts of higher and lower acid amount showed decreased sulfur tolerance. Energy dispersive spectroscopic analysis proved that the support with a large acid amount adsorbed more sulfur, which might lead to the lower sulfur tolerance of the catalyst.

结果表明硫含量为200μg/g时，载体酸量为626和203μmol/g的两个催化剂的耐硫性最好，而载体酸量更低和更高的催化剂的耐硫性较差，表明载体的酸量太大或太小都不利于催化剂的抗硫性。X射线能量散射分析表明，酸量大时S在酸性位吸附很多，这可能导致催化剂中毒。

The use of rare earth vanadates as supports for active gold catalysts opens up new routes in the research work for high performance catalysts. Bismuth vanadate micro/nanocrystals with different morphologies were synthesized by surfactant assisted hydrothermal/solvothermal methods.

建立了表面活性剂辅助的水热及溶剂热合成方法，通过选用合适的表面活性剂及控制单体浓度，获得了一系列不同晶形及形貌的BiVO4微/纳米晶，研究了晶体结构与生长行为的相关性。

A series of transition metals, transition metal oxides and composite metal oxides were investigated as catalysts for phenol hydroxylation. Twelve new types of phenol hydroxylation catalysts with good activity and application prospect were reported.

考察了一系列过渡金属氧化物、复合金属氧化物及金属作为苯酚羟基化作用催化剂的反应性能，筛选出12种具有良好活性与应用前景，尚未见文献报道的苯酚羟基化新型催化剂。

The surface reaction of thiophene leads to the sulfidation of molybdenum nitride catalysts and the formation surface σ-bonded C〓 species, which are considered as the reasons for the deactivation of nitride catalysts in HDS process.

噻吩的表面反应使得催化剂表面被硫化，并产生σ键合的表面C〓物种，这些被认为是氮化物催化剂在噻吩HDS反应中失活的原因。H〓S对氮化钼表面位的影响较噻吩更明显。

Propanediol phenyl ether was synthesized from phenol and propylene oxide in the presence of a series of solid-based catalysts derived from hydrotalcite-like compounds. The effects of the composition and structure of the catalysts, and the reaction conditions on the synthesis of propanediol phenyl ether were studied.

以不同类水滑石化合物为前驱体制得的复合氧化物作为合成丙二醇苯醚反应的固体碱催化剂，考察了催化剂组成、结构及反应条件对催化合成丙二醇苯醚反应的影响。

Improvement and modification of traditional metal sulphide catalysts, and the current situation of new catalysts such as metal carbides, metal nitrides and metal phosphides are emphasized.

着重概述了传统金属硫化物催化剂的改性方法，新型的金属碳化物、金属氮化物和金属磷化物催化剂的研究现状。

Nickel phosphide was chosen as the HDN catalyst in the present dissertation because it is reported to have the highest activity among transition metal phosphides. For the supported nickel phosphide catalysts, mesoporous MCM-41 was used as the carrier. The effect of support modification and the introduction of a secondary metal species on the activity of supported nickel phosphide catalysts were studied.

本论文以磷化镍催化剂为研究对象，考察了MCM-41负载的磷化镍催化剂的制备及其对喹啉的HDN反应性能，载体和活性组分的改性对喹啉HDN反应性能的影响，以及TiO_2的引入对非负载的磷化镍催化剂HDN反应的影响。

Generally the catalysts have high activity and good selectivity. At present the coupling reactions of organoborahes with terminal olefins s acid chlorides and aryl halides play an important synthetic approaches in organoborane chemical. The catalysts can be used by many kinds of organometal compounds such as: irons cobalt nickel ruthenium rhodium palladiums titaniums zirconiums tins indium and lithium organic compounds; The achievement has been amazed in preparing of unsaturated or saturated compounds and in synthesizing of natural products bioactive molecules and chiral compounds.

目前，卤代烃与不饱和烃的偶联反应和有机硼试剂与酰卤和卤代烃的偶联反应已成为有机合成的研究热点，此类反应可用铁、钴、镍、钌、铑、钛、锆、锡、铟、锂等多种有机金属化合物来催化，用于形成含饱和或不饱和C-C键的化合物，并已在天然产物、液晶、具有生理活性物质和手性化合物的合成中应用。

Solid acid-base catalysts instead of liquid Bronsted and Lewis acid/base catalysts is one of the most important ways with the direction of the development of green chemistry.

而用固体酸碱代替液体酸碱催化有机反应是实现环境友好的一条重要途径，符合绿色化学的发展方向。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。