查询词典 catalyst

Then the composition and particle size distribution of Ni catalysts at different sulfuration time were analyzed,and the coke-restraining activity of the catalyst was also studied.The results show that the structure of nickel sulfide catalyst changed with different sulfuration time,and the coke-restraining activity of the cata...

结果表明，硫化时间的增长，生成的硫化态催化剂晶形发生了相应的变化，随着硫化时间的延长和催化剂质量分数的提高，催化剂的抑制生焦活性提高；当硫化时间超过3h，催化剂质量分数大于2000μg/g时，催化剂抑焦活性的变化趋于平稳。

However, the esterification rate and yield reach 94 % and 89 % with the oil of vitriol as catalyst, and the best reaction conditions are that the weight ratio of catalyst and inhibitor are 2.5 % and 0.6 %, the volume of toluene is 60 mL, the molar ratio of MAA and TEG is 2.2:1 and reaction time is 3 h, and the content of TEGDMA is 88 % analyzed by GC.

以浓硫酸为催化剂，当阻聚剂的用量分别为原料的2.5 %和0.6 %，甲苯用量为60 mL，n：n=2.2∶1和反应时间为3 h时，酯化率和产率分别为94 %和89 %，气相分析TEGDMA的质量百分数为88 %。

Catalyst The catalyst consists of oxygenated compounds of tellurium, cerium and molybdenum supported on a microspheroidal silica carrier.

催化剂。催化剂由支持在微球形二氧化硅载体上的碲、铈和钼的氧化混合物构成。

The invention relates to a process for producing polyethylene terephthalate 1, 3-propanediol, which comprises the following steps: using titanic acid ester as major catalyst, using germanium compounds and cobalt compounds as synergic catalyst, conducting esterification reaction for poly terephthalic acid and 1, 3-propanediol according to the molar 1:1.05-2.2 under the nitrogen pressure of 0.1-0.4MPa and 230-265 DEG C, or conducting ester exchanging reaction for poly terephthalic acid and 1, 3-propanediol according to the molar ratio 1:1.8-2.2 in 160-220 DEG C, decompressing reaction to high vacuum 10-150Pa, wherein the final temperature of reaction is 265-275 DEG C, recovering to normal pressure with nitrogen to obtain the PTT product.

本发明涉及一种生产聚对苯二甲酸1，3-丙二醇酯的方法，采用以钛酸酯为主催化剂，锗化合物和钴化合物为协同催化剂，对苯二甲酸二甲酯和1，3-丙二醇按摩尔1∶1.05-2.2，在0.1-0.4MPa氮气压力和230-265℃下进行酯化反应，或对苯二甲酸二甲酯和1，3-丙二醇按摩尔比1∶1.8-2.2，在160-220℃进行酯交换反应，将反应减压至高真空10-150Pa，反应终温在265-275℃，用氮气恢复到常压，得到本PTT产品；大大缩短了反应时间，直接聚合制备特性粘度在0.7-1.05dL/g的PTT切片，使反应产物色相良好，PTT产品可用于纤维加工及工程塑料领域。

The invention relates to a preparation process for synthesizing polyethylene terephthalate 1, 3- terephthalate catalyst, which comprises adding titanic acid ester, germanium compounds and cobalt compound into liquid dispersed phase of organic solution, wherein the total weight concentration is 4-10%, and preparing the catalyst through mechanical stirring or ultrasonic wave mixed ligand for 10-60 minutes in 0-120 DEG C, wherein the adding content of titanic acid ester, germanium compounds and cobalt compound are respectively 200-500ppm, 50-300ppm and 100-400ppm of reaction monomer mass of terephthalic acid or dimethyl terephthalate.

本发明涉及一种合成聚对苯二甲酸1，3-丙二醇酯催化剂的制备方法，将钛酸酯、锗化合物和钴化合物加入到有机溶剂的液体分散相中，总重量浓度为4～10％，在0-120℃通过机械搅拌或超声波混配10-60min制得；钛酸酯、锗化合物和钴化合物加入量分别是对苯二甲酸或对苯二甲酸二甲酯反应单体质量的200-500ppm、50-300ppm、100-400ppm；用此催化剂制备PTT产品，酯化和缩聚反应时间相对于单独使用钛酸四丁酯缩短了30-60min，产品特性粘数0.70-1.05dL/g，色相b值在2-6之间，切片可用于加工新型合成纤维及工程塑料产品。

It was shown that urushiol resin immobilized ferric trichloride catalyst was an excellent catalyst.

考察了原料配比、反应时间、催化剂用量等因素对酯化反应的影响。

The experimental results show that the purity of product with sodium bicarbonate as catalyst is higher than that with triethylamine as catalyst.

实验结果表明，采用碳酸氢钠做缚酸剂得到的产品纯度更高，约为99.0%以上，颜色更加澄清透亮。

D. of the catalyst increased, i. e. the acid volume of the catalyst increased, the conversion for isobutene and the selectivity for trimer increased also, while the selectivity for dimer decreased, and the selectivity for tetramer was almost unchanged.

D。增加时，即催化剂的酸量增加时，异丁烯的转化率和三聚物的选择性也增加，但二聚物的选择性降低，四聚物的选择性则几乎没有变化。

The activity test shows that the Ni/Ce-Zr-Al-Ox catalyst has a CH4 conversion of 89％ and a good stability, and the CH4 conversion increases to 94％ by adding 3.2％ steam. In addition, due to the suppression to unreactive carbon, it can be expected that the stability of catalyst will be further promoted.

活性测试结果表明， Ni/C-Zr-Al-Ox催化剂显示了89％的CH4转化率和良好的稳定性，添加3.2％的水蒸汽后活性提高到94％，由于对非活性积碳的抑制，可以预料其稳定性也将进一步提高。

The alloy catalyst was found to be unstable in the acidic solution because of the electrochemical and chemical dissolution of the catalyst.

发现在酸性溶液中，钯铁合金催化剂对氧还原反应的催化活性不稳定，原因是钯铁合金催化剂在酸性溶液中发生电化学/化学溶解；在碱性溶液中，覆盖在电极表面的钯铁合金催化剂的质量及电化学活性面积在电化学扫描过程中不发生明显变化，保持对氧还原反应的催化活性，证明钯铁合金催化剂在碱性介质中非常稳定。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。