查询词典 catalyst

While the adsorptions of 1-propanol and 1-Br-propane at 100℃ give rise to 1-propoxy species, which mainly converted to propanal at higher temperature. IR spectrum arising from the interaction of propene with the catalyst at 100 ℃ shows the IR bands of allyl alcoholate and isopropoxy species. As the temperature was increased to 150℃, the bands ascribable to the adsorbed acetone and acrolein were observed. Based on these results, it is suggested that isopropoxy species is one of the intermediates for SOP to acrolein over MoPO/SiO〓 catalyst.

2原位IR光谱实验结果表明：200℃时丙烷/O〓混合气在催化剂表面吸附后的IR谱与同温度下异丙醇吸附的IR谱相似，均检测到吸附态丙酮物种和丙烯醛物种的IR谱峰；溴代异丙烷和异丙醇在催化剂表面吸附后均转化为异丙氧基，异丙氧基主要转化为丙烯和丙酮，丙烯进一步转化为丙烯醛；溴代正丙烷和正丙醇在催化剂表面吸附后均转化为正丙氧基，正丙氧基主要转化为丙醛；丙烯在催化剂表面吸附后转化为σ-氧烯丙基和异丙氧基，升温后σ-氧烯丙基转化为丙烯醛而异丙氧基转化为丙酮。

While the adsorptions of l-propanol and 1-Br-propane at 100 癈 give rise to 1-propoxy species, which mainly converted to propanal at higher temperature. IR spectrum arising from the interaction of propene with the catalyst at 100 癈 shows the IR bands of allyl alcoholate and isopropoxy species. As the temperature was increased to 150 癈, the bands ascribable to the adsorbed acetone and acrolein were observed. Based on these results, it is suggested that isopropoxy species is one of the intermediates for SOP to acrolein over MoPO/SiO2 catalyst.

原位IR光谱实验结果表明：200℃时丙烷／O_2混合气在催化剂表面吸附后的IR谱与同温度下异丙醇吸附的IR谱相似，均检测到吸附态丙酮物种和丙烯醛物种的IR谱峰；溴代异丙烷和异丙醇在催化剂表面吸附后均转化为异丙氧基，异丙氧基主要转化为丙烯和丙酮，丙烯进一步转化为丙烯醛；溴代正丙烷和正丙醇在催化剂表面吸附后均转化为正丙氧基，正丙氧基主要转化为丙醛；丙烯在催化剂表面吸附后转化为σ-氧烯丙基和异丙氧基，升温后σ-氧烯丙基转化为丙烯醛而异丙氧基转化为丙酮。

The invention relates to a method for making oligomeric isocyanates by reacting diisocyanates in the presence of a catalyst, wherein the catalyst comprises a saline compound prepared from an anion selected from 1,2,3- or 1,2,4-triazole, a substituted species of 1,2,3- or 1,2,4-triazole and carbocyclically and/or heterocyclically annellated species of 1,2,3- or 1,2,4-triazole and the cation selected from an alkali metal, alkaline-earth metal and/or monovalent ammonium cation and/or phosphonium cation of formula (5), wherein the E, R1, R2, R3, R4 are as defined in the descriotion.

本发明涉及一种制备低聚异氰酸酯的方法，包括二异氰酸酯在催化剂的存在下进行反应，其中所述催化剂由盐化合物组成，该盐化合物由选自1，2，3-或1，2，4-三唑、1，2，3-或1，2，4-三唑的取代系列者、1，2，4-三唑的碳环稠合系列者、1，2，3-或1，2，4-三唑的杂环稠合系列者的化合物及其混合物的阴离子和选自碱金属、碱土金属和/或通式(5)的一价铵阳离子和/或磷友衾胱拥难衾胱又票福其中E、R 1 、R 2 、R 3 和R 4 如说明书中所定义。

Results showed that using aluminum trichloride combined catalyst under the conditions of a catalyst dosage of 5%, a benzene/olefin molar ratio of 8, a reaction temperature of 60℃ and a reaction time of 6 h, the yield of alky-benzene reached 19.6% and the quality of the obtained alkylate was significantly improved as compared with coker gas oil.

结果表明，采用三氯化铝复合催化剂，在催化剂质量分数为5%、反应温度60℃、苯烯摩尔比为8、反应时间6 h的条件下，烷基苯收率达到19.6％，烷基化油的质量明显优于焦化柴油。

Poly was synthesized with calcium ammine as catalyst system and hexane as solvent,and the relationship among catalyst amounts,polymerization temperature,polymerization time and moisture of solvent with the yield of PEO and its relative molecular mass were investingated.

阐述了采用氨钙体系催化剂、以正己烷为溶剂的沉淀聚合制备聚氧化乙烯的方法。研究了催化剂用量、反应温度、反应时间及溶剂含水量与PEO收率及其相对分子质量的关系。

Anisaldehyde was synthesized from p-hydroxybenzaldehyde with dimethyl carbonate by microwave irradiation under phase transfer catalyst tetrabutylammonium bromide, The effect of power, time, solvent and catalyst of reaction on yield were researched.

以四丁基溴化铵为相转移催化剂，采用对羟基苯甲醛和碳酸二甲酯为原料，微波辐射下合成大茴香醛。考察了反应溶剂、功率、时间和催化剂对反应产率的影响。

However, the apparent frequency factor of curing increases with the increase of the catalyst , being one order of magnitude higher with 0.6 % catalyst than without.

在空气中增高温度时其侧基破坏分为二个阶段，即甲基比苯基先破坏。当引入聚铝苯基硅氧烷作为硅树脂固化催化剂，可提高其甲基的起始分解温度，同时降低苯基的起始分解温度。

The results show that the castor oil with barium hydroxide as catalyst in the transesterification reaction in the appropriate conditions: methanol to oil molar ratio of 6:1, 10:1, catalyst amount, reaction time 90 min

结果表明，蓖麻油在以氢氧化钡为催化剂的酯交换反应中适宜条件为：醇油摩尔比6：1，催化剂量10：1，反应时间90 min 不要翻译软件的！追加50！

The results show that the appropriate conditions of castor oil with barium hydroxide as catalyst in transesterification reaction are: the molar ratio of methanol to oil is 6:1, castor oil to catalyst is 10:1, reaction time 90 min, the yield is 98.20%, the castor oil conversion rate is 75.13%.

结果表明，蓖麻油在以氢氧化钡为催化剂的酯交换反应中适宜条件为：醇油摩尔比6：1，蓖麻油与催化剂摩尔比10：1，反应时间90 min，生物柴油收率98.20%，蓖麻油转化率为75.13%。

The comonomer in the copolymer by cat247 is trend to isolated. A few amount of comonomer could make the melting point remarkably decreased and maintain the crystalline at a relative high level. This catalyst can be use to produce the material with low melting point and high intensity such as packing film with low hotsealing temperature. The copolymer by cat24 is characteristic of uniform comonomer distribution and low melting temperature and crystallinity. Therefore, this catalyst could be used to produce LLDPE and POE according the comonomer content; cat246 has a strong copolymerization ability, and the resultant polymer has relatively high blockiness. If this trend is strengthened by adjustment of polymerization condition, the polymer can be used as thermal plastic elastomer with random and crystalline blocks.

由于各个催化剂所产生的聚合物各具特点，所以其潜在的工业用途不同。cat247的产物中共单体趋于孤立分布，极少的共单体即可使熔点明显降低而结晶度仍保持较高水平，有利于制备低熔点、高强度的材料（如低热封温度的包装膜等）。cat24的催化聚合产物无规程度比较高，对降低熔点和结晶度都十分有效，通过控制产物中共单体含量的多少，可以生产LLDPE和POE；cat246共聚合能力强，且产物有嵌段倾向，通过调整聚合条件强化这一倾向后，可以用来生产具有无规-结晶嵌段结构的热塑性弹性体。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。