查询词典 carboxylic acid

Ugi-4CC(four-component condensation) reaction is one of isonitrile-based MCR＇s(multi-component reactions), which is started with an amine, an aldehyde, a carboxylic acid and an isocyanide, after one-potreaction to produce a compound composed of the whole four starting materials.

Ugi-4CC四组份缩合反应是基于异腈的MCR＇s之中一类，它以异腈、羧酸、醛、胺为原料，可经一罐反应缩合生成由四种起始物共同组成的产物。

The method is characterized in that:(1) the reflux of the 2-[N, N- 2amino]-3-cyano-group-4-thiopheneacetic-5-carboxylic acid tetra ester is carried out in the proper sodium hydroxide aqueous solution of alcohol for 5h to 6h and the pH value is kept over 10 during hydrolysis;(2) the ethanol of 20 per cent to 60 per cent is added and then the strontium chloride aqueous solution with 2times to 2.5times molal weight is directly added, precipitates the crystal, is filtered and dried;(3) water is added to carry out the reflux and the little salt packed in the crude product is removed, and the product is collected through heat filtration.

其特征在于：①将2--3-氰基-4-羧甲基噻吩-5-羧酸四酯在适量氢氧化钠水醇溶液中回流5～6小时，水解过程保持pH值10以上；②然后再加入20-60％乙醇，随后直接加入2-2.5倍摩尔量氯化锶水溶液，析出结晶，过滤，晾干；③加水回流，除去粗品中包裹少量盐，热过滤，收集产品。

Combining chemical complexation and physics extraction of monobasic and polybasic carboxylic acid, the universal liquid-liquid equilibrium model with clear physical meaning was successfully induced.

详细研究了萃取剂浓度、稀释剂浓度、水相pH值、温度和羧酸初始浓度等因素对络合萃取平衡的影响以及萃取剂的再生条件。

Distribution ratios of complex extraction for different operation conditions were forecasted. Using mass action law, the liquid-liquid equilibrium models of complex extraction of monobasic and polybasic carboxylic acid have been successfully induced, and physical extraction were also considered in the model. On the basis of orthogonal experiments, the models of equilibrium distribution ratios were established. The processes of complex extraction were tested and verified. Comparing experimental data with model values, it could be held that the regression precision of model was rather high and the model supplied fundamental data for industrial amplification and practical use of complex extraction.

采用质量作用定律分析方法，成功地推导了同时考虑物理萃取的一元及多元羧酸络合萃取通用液-液平衡数学模型，并在正交试验基础上建立了磷酸三丁酯络合萃取丁酸、三烷基胺（7301）萃取丁酸、丁二酸、柠檬酸的平衡分配系数模型，从平衡角度对络合萃取过程进行了验证与预测，通过实验数据与模型计算值比较，表明模型的拟合精度较好，从而为络合萃取技术的工业放大与实际应用提供了重要依据。

In the paper, the multidentate carboxylic acid ligands were used to combine with Cd, resulting in the three dimensional MOCPs single crystals—C12H16CdN2O8, with a low temperature hydrothermal synthesis method. The sample was characterized with IR spectra to affirm the organic groups in the frameworks, single-crystal X-ray diffraction to determine the crystal structure and composition of the frameworks, N2 adsorption isotherms at low temperature to measure the specific surface area and pore size distribution, and with TGA/DGA analysis to scale the thermal stability. Furthermore, the dissolution property and the photocatalytic activity of MOCPs under the ultraviolet ray condition were explored.

本文用低温水热合成法，用多齿羧酸配体异烟酸和Cd配位合成出[Cd(C6H4O2N)2(H2O)4]∞三维晶体并进行了表征：采用红外光谱法确认骨架中的有机官能团；用单晶X射线衍射分析法测定MOCPs的晶体结构，并确定其骨架的组成；通过低温氮气吸附等温线测定了其比表面积和孔径分布；以热重分析和差热分析测定材料骨架的热稳定性；测定了晶体的溶解性能；最后以亚甲基蓝为目标降解物，对[Cd(C6H4O2N)2(H2O)4]∞的光催化活性及亚甲基蓝的氧化动力学进行了探索(来源：A2444BC论文网www.abclunwen.com)。

Herein,two nitrophenyl pyrrolic amide receptors,p-nitrophenyl-1H-pyrrole-2-carboxamide(1) and m-nitrophenyl-1H-pyrrole-2-carboxamide(2),were synthesized by coupling pyrrole-2-carboxylic acid with nitroaniline in the presence of dicyclohexylcarbodiimide.

阴离子识别主体分子在膜运输载体、催化、化学传感及酶仿生模拟等方面都具有广阔的应用前景[1，2]。

And the ability of antioxidant of polyhydroxy benzamides don't have too many differences with Trolox (IC50 =13.90 μg/ml), the substition of hydroxy group at amino benzene ring doesn't affect the whole ability of antioxidant apparently, but while the single hydroxy group at carboxylic acid benzene ring, they are apparently decrease to scavenge the ability of free radical, as a result, the hydroxy at amino benzene ring substitutes its function, without the hydroxy group, the ability of antioxidant is worst, but it upgrades its function while the hydroxy and amino are in the ortho-position or para-position.

而当多酚醯胺化合物其抗氧化能力与Trolox差不多时(IC50 =13.90 μg/ml)，胺基苯环上之羟基取代对整体抗氧化能力影响不明显，但在羧酸苯环上具单羟基时，其清除自由基能力明显下降，使得胺基苯环上羟基取代发挥了影响力，无羟基取代时，抗氧化能力最差，而羟基与胺基互为邻位或是对位时较间位有提升效果。

Pyrazole; pyrazolyl carboxylic acid; synthesis; complexes; crystal structure

吡唑； 羧酸；合成；配合物；晶体结构

Furthermore, some discrepancies in earlier literature have been pointed out and our results may provide guidance for hydrogen-bonding association, in particular for the design and assembly of supramolecular polymers based on carboxylic acid/pyridyl pairs.

指出了早期文献报道的一些不一致甚至矛盾的结果。通过不同系列的对比研究，得出的一些规律性对氢键组装尤其对羧基/吡啶氢键缔合超分子体系设计与构筑具有一定指导意义。

Secondly,UV spectrophotometry was adopted to research the combination action on SM_2 and SIZ with MAA and 4-Vp.The combination action of functional monomer with template molecules were produced in the results. Then,the prediction imprinting principle of SM_2 and SIZ were given. The diagrams of infrared spectrum were analysed in MAA and 4-Vp and IMPs of SM_2. It was discoved that the absorbability peak of C=C function group in the IMPs were turn to be very low ,but the function group of carboxylic acid and pyridyl in the IMPs were no evidence change, and the condition was created in the molecular recognition of MIPs. Thermal Analysis was adopted to research IMPs ,in which ,a better thermal stability and its decompose temperature were showed in the results.

其次，本文利用紫外分光光度法研究磺胺二甲嘧啶和磺胺异噁唑与甲基丙烯酸或4-乙烯基吡啶的结合作用，结果表明，溶液中的功能单体与模板分子之间产生了结合作用，并预测磺胺二甲嘧啶和磺胺异噁唑印迹机理；分别分析了功能单体甲基丙烯酸、4-乙烯基吡啶、磺胺二甲嘧啶和磺胺异噁唑分子印迹聚合物的红外谱图，经过对比发现制得的印迹聚合物中C=C双键峰很小，并且功能键羧酸键和吡啶氮没有明显变化，这为聚合物特异识别特性创造了条件；利用综合热分析仪，对分子印迹聚合物进行综合热分析，结果表明分子印迹聚合物具有较好的热稳定性，分解温度也较高。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。