查询词典 carboxyl

Mol/L. 3 A study on the ECL of acridinum esters including 10--acridinium-9-carboxyl-phenyl-ester iodinate and 10-methyl-9-(p-formylphenyl)-acrdiniumfluorosulphonate in neutral solution was carried out. It was found both CACPEI and MFPA give strong ECL in KNO〓 solution when an appropriate voltage was applied on Pt electrode.

本文研究了碘化10-乙羧基吖啶-9-羧酸苯酯和对甲酰基苯基-10-甲基吖啶-9-羧酸酯氟磺酸盐的ECL行为，发现在中性KNO〓介质中，这两种吖啶酯都能在一定的电位下产生很强的ECL信号，考察了各种影响因素，确定了发光的最佳条件，探讨了可能的发光机理。

Chemically, fluoroquinlones are an amphoterics molecule processing major ionizable groups, a basic piperazine amine and acidic carboxyl. The form of drugs was greatly affected by the acidity in aqueous solution. Thus the effect of pH values in aqueous solution on the fluorescent properties of fluoroquinolones was studied in details, the spectral properties of each form was characterized. It was found that the fluoroquinolones exhibit weak fluorescence in strong basic solution.

氟喹诺酮类药物分子结构中既有羧基，又有哌嗪氨基，它们所处环境的pH值对其存在型体有很大影响，因此我们详细研究了水溶液的pH值对该类药物光谱特性的影响，并对于各型体光谱特征进行归属，发现强碱性溶液中其发光较弱。

From the structural analysis of three praseodymium complexes, we could draw a conclusion that as the dentate arms of carboxyl group on ligands elongating, the coordination numbers of Pr and the coordination modes of ligands increase, and the mean distances between metallic atoms of metallic helices existing in these complexes augment.2. By altering 5-substituting group of isophthalic acid three series of lanthanide complexes 8～19 with 5-methylisophthalic acid and 5-nitroisophthalic acid have been prepared.

从得到的三个配体的镨配合物的结构分析可以看出，随配体的羧基齿臂的增长，Pr的配位数逐渐增大，配体的配位模式增多，配合物中存在的螺旋金属链中的金属间平均距离增大。2、通过改变间苯二甲酸配体的5位取代基，制备了5-甲基间苯二甲酸和5-硝基间苯二甲酸的三个系列稀土羧酸配合物8～19。

In complexes 8～16 synthesized by hydrothermal method, most of the ligands adopt multidentate coordination modes joining several lanthanide ions into high-dimensional coordination polymers. And changing of 5-substituting group on isophthalic acid has a little effect on the coordinated abilities of the meta-carboxyl groups.

水热法制备的配合物8～16中，配体多采取多齿配位模式桥连多个稀土离子，形成高维配位聚合物，同时由于羧基氧原子和稀土离子的强的键合力，间苯二甲酸的5位取代基的变化对间位羧基的配位能力的影响不大。

Furthermore, the one-dimensional complexes 26 and 28 with strongπ-πpacking interactions are prepared from DMF solvent, which indicates that the traditional solvent volatilizing method could bring low-dimensional complex.4. By measuring the enthalpy changes of the liquid phase formation reaction for complexes a~e, and calculating the electronic densities of five 5-substituted derivation of isophthalic acid, we can make a conclusion that 5-substituted group changing of the ligand has a little influence on oxygen atoms of carboxyl groups.5. Fluorescence experiments of these complexes indicated that they could be used for luminescence materials in future.6. Using packing saturation rule we calculated and analyzed these series of complexes, and the results showed that the changes of complexes with changes of ligands could be explained from the rule.

在DMF溶剂中得到了具有强π-π堆积作用力的一维配位聚合物[Ln(5-NO_2-bdc)(NO_3)]Ln=Pr(26和Ho(28)，表明传统的溶剂挥发合成条件可以得到低维的配合物。4、通过配合物a～e的液相生成反应焓的测定，以及配体阳离子的电子密度计算，进一步佐证了间苯二甲酸的5位取代基变化对配体的羧基氧原子配位能力影响不大的结论。5、荧光特性表明此类配合物可以用于发光材料。6、利用堆积饱和规律对所得系列的配合物的进行计算和分析，发现随着配体的变化，配合物的变化可以从堆积饱和规律出发进行解释。

The corrosion-inhibiting efficiencies of isoquinoline and its hydroxyl and carboxyl derivatives on Fe electrode in HCl solution have been determine with electrochem.

本文在30℃， 1.0mol.dm^-3 HCl溶液中用电化学方法测定了异喹啉及其羟基，羧基衍生物对Fe电极的缓蚀效率。

The neural network's outputs included the corrosion-inhibition efficiencies of isoquinoline and its hydroxyl and carboxyl derivatives for iron electrode in HCl solution or electrode parameters which were determined with electrochemical methods in 1.0 mol·dm-3 HCl solution at 30℃.

以缓蚀剂分子氮净电荷、自由价、亲核前沿电荷密度等量子化学参数为输入变量，考察了异喹啉及其羟基、羧基衍生物在30℃，1.0mo1·dm~(-3)HCl溶液中对铁的缓蚀效率，建立了相应的预测模型。

Based on our intensive studies on the lactonization of oligo/polysialic acids, we proposed for the first time that the lactone-ring formation of oligo/polysialic acids has three stages. We also provided a novel model to explain the conformational changes of oligo/polysialic acids caused by the repulsing forces among the carboxyl groups of sialic acid residues. Our results should provide novel approaches for further investigation of the structural-functional relationships of oligo/polysialic acids.

在对多/寡聚唾液酸内酯化过程进行深入研究的基础上，于国际上率先提出多/寡聚唾液酸内酯的形成具有三个阶段的观点，并首创性地提出了羧基排斥所致多/寡聚唾液酸分子空间构象改变的模型，为深入研究多/寡聚唾液酸结构与功能的关系提供了新生长点。

The experiment result shows that favorable colour development performance can be achieved for the adhesive with polyvinyl alcohol as major component and the waterproof quality can be improved when the carboxyl tetraphene latices was mixed into the adhesive in a certain proportion.

实验发现，使用聚乙烯醇为主体的胶粘剂可使热敏纸获得良好的发色性能，胶粘剂中混入一定比例的羧基丁苯类胶乳可以使热敏纸的防水性能得到改善。

By chemical treatment of LS, a kind of modified lignosulphonate based plasticizer was obtained. The modification was confirmed to be connected with carboxyl groups through infra-red spectroscopy analysis.

通过化学方法对LS改性，得到了一种接有羧基基团的改性木质素磺酸盐减水剂。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。