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Many data and discussions about carbonate rock dissolution in CO2 solution have been published. In this paper, special simulation experiments were carried out in order to understand the dissolution behaviors of carbonate rocks in organic acid and H2S solution. The results show that, as the temperature rises from 20℃ to 200℃, the dissolution rate of carbonate rock in organic acid increases with temperature below 90℃ and decreases above 90℃.

CO2对碳酸盐岩储层的溶蚀作用已有不少学者进行了研究,本文则以一个全新的模拟实验方式对不同类型碳酸盐岩在有机酸和H2S水溶液中的相对溶蚀能力进行了研究,结果发现随温度从常温升高至200℃,有机酸对碳酸盐岩的溶蚀能力由弱变强再变弱,在90℃左右溶蚀能力最强。

Because nanometer barium carbonate has more excellent qualities than ordinary barium carbonate, it has been one of the important directions of the barium carbonate industry.

纳米BaCO_3具有不同于常规BaCO_3的优良性能,因此,纳米是BaCO_3制备工艺发展的一个重要方向。

Production of high purity level of fluorescence strontium carbonate, electronic-high purity strontium carbonate, barium carbonate, such as high purity level of electronic materials in powder technically in a peer-leading position, its level of quality has been engaged in domestic and foreign professional Long Lasting luminous powder, PTC, NTC thermistor, such as electronic components manufacturer of the high degree of recognition and trust and become their long-term, stable supplier.

生产的荧光级高纯碳酸锶、电子级高纯碳酸锶、电子级高纯碳酸钡等粉体材料在技术上处于同行领先地位,其质量水平受到了国内外专业从事长余辉发光粉,PTC、NTC等热敏电阻电子元件生产厂家的高度认同和信赖,并成为他们长期的,稳定的供应商。

TheJiyang depression located in paleomonsoon climate zone in the period of the sahejieformation sedimentation, the wet and hot climate made ancient lake become deeperwater, enhanced stratification, reduced primary productivity of plankton, decreasingsedimentary velocity of carbonate, increasing sedimentary velocity of clay, fortifiedreductibility on certain degree, and then would be available for development of blackshale, dark shale and oil shale; In the contrast, the cold and dry climate lead ancientlake to shallower water, subdued stratification, increaser primary productivity ofplankton, enhancive sedimentary velocity of aphanitic carbonate, decreasedsedimentary velocity of clay, and then would be available for development calciteshale, calcite laminar shale, calcite mudstone, shaly carbonate rock, even laminarcarbonate or dolomite rock.

济阳坳陷在古近系沙河街组沉积期属于古季风气候带,在湿热的气候条件下古湖水加深,分层性增强,浮游生物的古生产力降低,隐晶碳酸盐的沉淀速率变小,粘土沉积速率加快,还原性一定程度上有所加强,有利于黑页岩、油页岩和暗色泥岩的形成:而相对干冷气候下,古湖水变浅,分层性减弱,浮游生物的古生产力增高,隐晶碳酸盐的沉积速率变大,粘土的沉积速率减慢,有利于钙质页岩、钙质纹层页岩、钙质泥岩、泥灰岩甚至纹层状碳酸盐岩、灰岩的发育。

In order to obtain the thermodynamic data of the synthesis of ethyl methyl carbonate from dimethyl carbonate and diethyl carbonate, the standard molar enthalpies of formation, Gibbs free energy and molar heat capacity under constant pressure are calculated by the method of Benson group contributions.

为了得到碳酸二甲酯和碳酸二乙酯酯交换合成碳酸甲乙酯反应的热力学数据,用Benson基团贡献法计算了相关物质的标准摩尔生成焓、吉布斯自由能和摩尔定压热容。

Mission:"equality and mutual benefit, reputation first, unity and cooperation and friendship between the long-term" supply products: ethylenediamine; diethylamide; triethylamine; Diethylenetriamine; three ethylene diamine; three ethylene amines 40; 40 Five ethylene amines; five ethylene amines 6; caprolactam; DMF; allyl amine; N, N dimethylaniline; propylamine; are butylamine; are TOA; 3 Poly Cyanamide; 1,2 c diamine; ethanolamine; diethanolamine, triethanolamine; potassium iodide, potassium hydroxide, potassium permanganate, toluene, xylene, toluene of chlorine ; Acetone, butanone; acetylacetone; ethyl acetate, butyl acetate; Y-butyrolactone; DMC; acetyl of methyl acetate; Sanfu acetyl acid; Sanfu acetyl B Ethyl; methanol, ethanol, isopropanol; propylene glycol; glycerol; propargyl alcohol; 1.3 propylene glycol; xylitol; acetic acid; have acid; mercaptoacetic acid; vary Bitterness; adipic acid; trifluoroacetic acid; oxalic acid, the amino acid; o-amygdalin acid; DL-Acid; anhydrous piperazine; six non-piperazine, furfural, castor oil, ethylene Aldehyde; glutaraldehyde, multi-POM; isopropyl ether; anisole; tetrahydropyrrole; pure pyridine; 1.2 dichloroethane; methylene chloride, chloroform, carbon tetrachloride; hydrazine hydrate; Nonylphenol;-m-cresol; Se phenol; phenol; the tert-butyl phenol; Titanium Dioxide; iron; full Tangfen; Bisphenol A; azo two different nitrile; sodium azide; sodium carbonate ; Sodium chloride; iron oxide; cuprous chloride; thionyl chloride; D4; sodium bicarbonate; ammonia, potassium chloride; anhydrous sodium sulphite; ammonium persulfate; glycol Dingmi; B Glycol ether; calcium chloride; cyclohexanone; cyclohexane, methyl tertiary butyl ether, potassium carbonate, ferric chloride, potassium nitrate; Linsuansanna; zinc oxide; sodium nitrite; antimony oxide; Tartrate; OP-10; TX-10; tablets base; AES; sodium benzoate, sodium citrate; partial sodium silicate, sodium perborate, a sodium carbonate, sodium benzene; Asia sodium chlorate; Wuluo Care products; urea; hydrochloric acid, sulfuric acid, lactic acid; amino acid, hydrogen peroxide, ammonium bicarbonate

公司宗旨:"平等互利,信誉至上,团结合作,友谊长久"乙二胺;二乙胺;三乙胺;二乙烯三胺;三乙烯二胺;三乙烯四胺;四乙烯五胺;五乙烯六胺;己内酰胺;二甲基甲酰胺;烯丙基胺;N,N二甲基苯胺;正丙胺;正丁胺;正辛胺;三聚氰胺;1,2丙二胺;一乙醇胺;二乙醇胺;三乙醇胺;碘化钾;氢氧化钾;高锰酸钾;甲苯;二甲苯;对氯甲苯;丙酮;丁酮;乙酰丙酮;醋酸乙酯;醋酸丁酯;Y-丁内酯;碳酸二甲酯;乙酰乙酸甲酯;三伏乙酰乙酸;三伏乙酰乙酸乙酯;甲醇;无水乙醇;异丙醇;丙二醇;丙三醇;丙炔醇;1.3丙二醇;木糖醇;冰醋酸;己醛酸;巯基乙酸;异辛酸;己二酸;三氟乙酸;乙二酸;对氨基苯乙酸;邻氯苦杏仁酸;DL-扁桃酸;无水哌嗪;六无哌嗪;糠醛;蓖麻油;乙二醛;戊二醛;多聚甲醛;异丙醚;苯甲醚;四氢吡咯;纯吡啶;1.2二氯乙烷;二氯甲烷;三氯甲烷;四氯化碳;水合肼;壬基酚;纯间甲酚;硒酚;苯酚;对叔丁基苯酚;钛白粉;铁粉;全糖粉;双酚A;偶氮二异丁腈;叠氮化钠;碳酸钠;氯化钠;三氧化二铁;氯化亚铜;氯化亚砜;D4;碳酸氢钠;氨水;氯化钾;无水亚硫酸钠;过硫酸铵;乙二醇丁醚;乙二醇乙醚;氯化钙;环己酮;环己烷;甲基叔丁基醚;碳酸钾;三氯化铁;硝酸钾;磷酸三钠;氧化锌;亚硝酸钠;氧化锑;酒石酸;OP-10;TX-10;粒碱;AES;苯甲酸钠;柠檬酸钠;偏硅酸钠;过硼酸钠;过碳酸钠;苯磺酸钠;亚氯酸钠;乌洛托品;尿素;盐酸;硫酸;乳酸;氨基磺酸;双氧水;碳酸氢铵

This dissertation involves the study of the growth dynamics of colloidal particles under unequilibrium and irreversibility condition. Firstly, it is of interest to investigate whether the ideal diffusion or reaction-limited aggregation universal behavior can be observed for the initially polydisperse practical system of basic yttrium carbonate as well. The fractal structure of basic yttrium carbonate aggregate cluster was observed using transmission eletron microscopy. The aggregation kinetics of basic yttrium carbonate colloids was studed using dynamic 1ight-scattering techniques. At 1.00mol/l NaCl solution the fast diffusion-limited aggregation behavior was observed with an increase in the aggregate size over time described by a power law. The aggregates are characterized by a fractal dimension D=1.82. The disordered and ramified cluster is consisted of primary colloidal particles and tenuous and more open. These are in good agreement with those observed for other colloidal system such as colloidal gold (1.86), silica (1.85) and polystyrene latex (1.82) in diffusion-limited aggregation from the static and dynamic light scattering by Lin. Therefore ideal diffusion-limited aggregation behavior can be observed in practical polydisperse system as well. Smoluchwski and fractal theories were used to obtain the aggregation rate constant for initially polydisperse system for the first time.

本论文研究胶粒的非平衡不可逆聚集动态学,分为两个部分,第一部分是通过实验研究一个新的初始多分散的碱式碳酸钇胶粒实际体系中,聚集标度性质的普适性,即使用透射电子显微技术观测聚集粒子簇的分形结构,使用动态激光光散射研究碱式碳酸钇胶粒的聚集动力学,胶粒带电而产生静电排斥作用使得碱式碳酸钇胶粒处于稳定状态,当加入电解质NaCl溶液时,碱式碳酸钇胶粒间的Debye-Hückel屏蔽距离缩短,从而降低静电排斥能垒,引起胶粒发生不可逆聚集,加入电解质NaCl的浓度为1.00mol/l时,碱式碳酸钇胶粒进行快速聚集,经历扩散控制聚集机理,形成结构疏松、更为开放的分形聚集粒子簇,其分形维数为1.82,碱式碳酸钇胶粒聚集增长动力学遵循幂函数增长规律,与Lin等使用静态激光光散射和动态激光光散射测量硅胶(1.85)、金胶(1.86)和聚苯乙烯胶乳(1.82)在扩散控制聚集状态形成聚集粒子簇的分形维数值以及粒子簇聚集增长的动力学规律相一致,表明胶粒聚集标度性质的普适性质在初始多分散的实际体系中也是存在的,首次由动态激光光散射的实验数据得到初始多分散胶粒分形粒子簇的聚集速率常数,并且其值与Smoluchowski聚集速率理论预期相符。

The DSC results showed that calcium carbonate,sodium benzoate and terephthalic acid were the nucleating agents of polypropylene with high thermal stability of the nucleating effect,while the thermal stability of nucleating effect of pimelic acid,suberic acid,azelaic acid,and the two component nucleating agents suberic acid/calcium carbonate and azelaic acid/calcium carbonate were poor.

研究了碳酸钙、苯甲酸钠、对苯二甲酸和脂肪二元酸:庚二酸、辛二酸、壬二酸及其与碳酸钙组成的双组分成核剂对聚丙烯结晶成核效果的热稳定性。结果表明,高熔点物质碳酸钙、对苯二甲酸、苯甲酸钠的成核效果的热稳定性高,而脂肪二元酸的成核热稳定性低。庚二酸与碳酸钙组成的双组分成核剂的成核热稳定性高,但辛二酸、壬二酸与碳酸钙组成的双组分成核剂的成核热稳定性没有得到改善。

By the testing means of electron-spectroscopy for chemical analysis , thermogravimetric analysis , differential scanning calorimetry , transmission electronmicroscopy , the results have shown that the emulsion polymerization in situ in the presence of nano-particle of calcium carbonate can happen smoothly and successfully and the surface of nano-particle of calcium carbonate have been capsulated by polymer of acrylates, which prevent from the agglomerating of nano-particles of calcium carbonate. Because the copolymer of acrylate has good compatibility with some plastics such as PVC, ABS, AS and so on, so the dispersion of nano-scale calcium carbonate as nanometer size in these plastics can be reached more easily and the effects of nanometer can happen.

通过X射线光电子能谱、热失重分析、动态扫描量热分析、透射电子显微镜等手段,证实在纳米碳酸钙原生粒子存在下,可以进行丙烯酸酯类的原位乳液聚合,乳液聚合顺利,纳米碳酸钙表面被丙烯酸酯类聚合物所包覆,使纳米碳酸钙粒子间的团聚不易发生,同时由于丙烯酸酯类聚合物与PVC、ABS、AS等极性聚合物具有较好的相容性,从而使纳米碳酸钙在聚合物基体中能达到纳米状态分散,从而发挥纳米效应。

When other alcohols is as the raw material, the yield ofaim product (diethyl carbonate, n-butylethyl carbonate, sec-butylethyl carbonate,benzylethylcarbonate and phenethyl ethyl carbonate) was 67.3, 52.3, 56.7, 37.6 and32.8%.

考察了此合成方法适用的普遍性,初步得出了此电合成方法适用于底物为伯醇和仲醇类,而不适用于叔醇和苯酚的反应。

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