查询词典 carbene

Studies on olefin-coordinating transition metal carbene complexes II.

含烯烃配体的过渡金属卡宾配合物的研究II。

The study of this thesis enlarges the application of rare earths metal- samarium in organic synthesis that has quite important meaning for our country having abundant rare earths resources. It promotes to explore the new use of rare earths metals in organic synthesis. There will be a great break in the theory and application of the production of carbene.

通过本研究扩大了稀土金属钐在有机合成中的应用范围，这对于我国具有丰富的稀土资源(贮量占世界总贮量的85%以上，稀土金属产量及质量占世界首位)而言，促进开发稀土金属在有机合成中的新用途，具有十分重要的意义；并在产生卡宾的理论上有所突破，填补了卡宾研究领域的空白，取得一些极具价值的学术成果。

In recent years, with the development of various good catalysts especially the ruthenium alkylidenes bearing N-heterocyclic carbene ligands, the RCM reaction has been applied widely in the synthesis of complex organic molecules, biological molecules and natural products etc. The Nobel Prize in Chemistry 2005 goes to Yves Chauvin, Robert H.

近二，三十年来，随着各种性能优良的催化剂的不断发展，尤其是含氮杂环卡宾配体的钌催化剂的出现，关环复分解反应在合成复杂有机分子，生物活性大分子以及天然产物等方面已得到了极为广泛的应用。2005 年的诺贝尔化学奖分别授予了 Yves Chauvin，Robert H。

The structures of the trimetal bridging carbene complex 28 and the ion-pair bridging carbyne complex 31 have been further confirmed by X-ray diffraction studies.

在与羰基金属阴离子络合物PPN和Na的反应中，我们得到了桥卡宾碳键合氢的桥卡宾络合物，并对两个此类桥卡宾络合物进行了晶体和分子结构的研究。

Studies on olefin-coordineting transition metal carbene complexes XVI.

含烯烃配体的过渡金属卡宾配合物的研究 XVI。

The empty p orbital and the occupied σorbital by a lone electron pair of carbene point towards H atom and C atom of the C—H bond respectively.

卡宾空的p轨道和占有一对孤电子的σ轨道分别指向C—H键的H原子和C原子。

But when the trimanganese tetrathiolated compound having a semicubic structure reacts with the cationic carbyne complexes 1 and 2, only some single-metal carbene complexes are isolated.

但当我们使用具有半立方烷结构的钼锰羰基化合物分别与阳离子卡拜络合物1和2反应时，只分离得到了一些单金属卡宾络合物。

ROMP of DCPD initiated by the well-definined carbene complex RuCl〓 was conducted for the first time. Influence of polymerization conditions was investigated.

首次以结构明确、组分单一的催化剂〓催化双环戊二烯活性ROMP反应，考察了聚合反应条件对反应结果的影响。

Moreover, we found that N-heterocyclic carbene could served as an efficient and novel catalyst for the reactions of aziridines with silylated nucleophiles or acid anhydrides.

随后，我们发现氮杂环卡宾也可以作为一种有机小分子催化剂，分别催化各类硅试剂或酸酐对氮杂环丙烷化合物的开环。

Three kinds of novel N-heterocyclic carbene allyl palladium complexes (Catalyst 1, 2 and 3) were synthesized. Norbornene polymerizations were carried out using three catalysts activated with methylaluminoxane in toluene.

研究了以3种N-杂环卡宾螯合烯丙基钯配合物1、2和3为催化剂，甲苯为溶剂，甲基铝氧烷为助催化剂催化降冰片烯的聚合。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新