查询词典 carbene

The metal catalyst complex has an N-heterocyclic carbene ligand, and thus, is excellent in thermal stability and reactivity.

所述金属催化剂配合物含有N-杂环卡宾配位体，因此，其具有极好的热稳定性和反应性。

In the chapter four,the main study was focused on [60,70]fullerene reaction with 4,4,5,5-tetramethylidazoline- 2- thione and DL- valine and other α-aminoacids. The results ofcharacterization showed that it was a carbene reaction. The possible mechanism wasput forward based on the results of characterization.

第四章，主要研究了[60，70]富勒烯，4，4，5，5-四甲基咪唑啉-2-硫酮与DL-缬氨酸和其它氨基酸的反应，通过对反应产物的详细的表征，发现该类反应是一个产生卡宾的新反应。

The reaction mechanism of ozone and singlet carbene has been studied by means of the Gaussian-3 method to optimize the geometries of reactions, transition states, intermediates and products.

为了研究单态卡宾与臭氧反应机理，本文采用密度泛函理论Gaussian-3方法(G3B3)优化了反应物、中间体、过渡态和产物的几何构型。

Based on this model, the structures, dipole moments and the nuclear magnetic resonance parameters were calculated for a series of functionalized nanotubes, including nitrene and carbene modification, as well as 1,2- and 1,4-fluorination.

本文采用C80H20模型来表示(10，0)碳纳米管，基于此模型计算了一系列氮烯、卡宾和氟化的单壁纳米管的结构、偶极矩，以及核磁共振参数。

Lactam was gained by the Staudinger reaction of imine and olefineketone in the presence of N-heterocyclic carbene catalyst.

以N-杂环卡宾催化剂1催化亚胺与烯酮之间的Staudinger反应，得到相应的β-内酰胺。

Because of special stereostructure and property, N-heterocyclic carbene complexes have been diffusely applied in organic chemistry and organic sythesis during the past few years.

N-杂环卡宾化合物具有特殊的结构和性质，近年来在有机化学及有机合成反应中得到了广泛的应用，并已经成功地运用在有机催化反应中。

The experimental results indicated that the two N-heterocyclic carbene palladium complexes with coordination of pyridine could catalyze the coupling of bromobenze and gave yield of 80%.

结果表明，这两个含吡啶配位的N-杂环卡宾钯络合物，对溴苯与丙二腈的交叉偶联，产率可达80％。

It can be seen from the above initial results, the two N-heterocyclic carbene palladium complexes should participate in the catalytic reaction or at least did partly.

初步结果可以得出，这两种N-杂环卡宾钯络合物参与或部分参与了卤代芳烃的催化偶联过程，对产物的顺利生成有某种程度的贡献。

This thesis is mainly about the research on the synthesis, structures and reactivity of di-or tri-metal bridging carbene and bridging carbyne complexes

过渡金属桥卡宾和桥卡拜络合物本身即为简单的金属原子簇化合物或是合成金属原子簇化合物的重要前体，在有机合成和烯炔烃的聚合和异构化等催化反应中有广阔的应用前景以及在某些过渡金属参与的反应的机理研究中具有重要的研究价值。

Like many of the molecular species that have been detected inthe interstellar medium, the singlet carbene cyclopropenylidene(C3H2), has been presumed too unstable to isolate in the laboratory.

一个名为cyclopropenylidene的三角形碳环分子过去只是在星际空间被探测到，现在一个研究小组在地球上的实验室中制造出了稳定的这种分子。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新