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According to Johnson's Rule and IR spectra, their possible structures are suggested. The bonding parameters of those complexes are calculated by ESR parameters. And the crystal field parameters are calculated by using electronic spectral data. It can be seen that the vanadyl complexes in the solution are ionic complexes and that the α〓 values of those complexes decrease following the increasing of the N donor replacing the O donor of water on the equatorial plane in those complexes. This means that the covalent bonding between vanadium and ligand increases as Ser, Phen or Bipy replace water ligands. The results show the competitive coordinate law that the coordination reactivity of Phen and Bipy is much stronger than that of Ser. The simulation program of ESR is compiled by the theory of ESR in the present work.
测定了VO-丝氨酸二元体系、VO-丝氨酸-邻菲咯啉三元体系和VO-丝氨酸联吡啶三元体系在不同酸度下(pH=1.0~14.0)的乙二醇/水(V/V=1:1)溶液低温ESR谱,发现不同pH下,溶液中具有不同组成的配合物,根据不同pH下ESR谱的变化,利用Johnson的加合规则并结合红外光谱,推测了它们在溶液中的可能结构;利用波谱参数计算了配合物键参数;利用电子光谱数据计算了配合物的晶体场参数,讨沦了它们的成配特性,结果表明:VO配合物属离子型配合物,随取代水分子的配体(Ser、Phen或Bipy)数目增加,键参数减小,配合物共价性增强,同时得出这些体系中,生物配体竞争配位规律:Phen和Bipy与VO的配位能力比Ser强。
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In order to testify the reliability of the approximate approach, the calculated value of volumetrically averaged energy dissipation rate based on the approximate approach are compared with the calculated results from an analytical equation derived on the thermodynamic laws and using the universally accepted equations for the friction factor.
为了检验能量耗散率近似算法的可靠性,将按近似算法计算得到的管内湍流体均能量耗散率与按热力学方法导出的解析式并采用公认的摩擦因子公式计算的体均能量耗散率进行了对比。
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Firstly, the flood control regulation of TGP in Sep is computed based on the analyses on the inflow in Sep and Oct, and the risk and loss on the ahead impounding scheme is calculated and analyzed. Then, the storage level, power production and releasing discharge are achieved by computing on the electricity generation model through reservoir regulation graph. Thirdly, obstruction in channel is analyzed and the problem in the Chongqing reach is more serious in 175-145-155m scheme. The sediment aggrading process and distribution on different schemes is calculated by 1-D reservoir mathematical model. The navigation benefit is computed by navigation model. Based on above calculations, the impounding time is decided by the multi-purpose decision model, and evaluate by analytical hierarchy and balance layout model. A best impounding scheme is achieved to match the requirement of flood control electricity generation and navigation et al.
首先,在对宜昌站9、10月份来水分析的基础上,采用第2章建立的防洪优化调度子模型进行了三峡水库9月份防洪调度,分析了汛末提前不同天蓄水对防洪的影响,计算了汛末不同蓄水方案水库9月份的洪灾风险率和风险损失;接着,根据第2章建立的发电调度子模型进行了三峡水库发电调度计算,得出了不同蓄水方案下水库的坝前水位、发电量及下泄流量过程;然后,分析了175-145-155m方案下三峡水库的碍航问题,指出175-145-155m方案下重庆河段的碍航问题最为严重,通过进行不同蓄水方案下水库一维泥沙冲淤计算,得出了不同蓄水方案下库区淤积过程及分布,并通过航运调度子模型,计算了不同蓄水方案下水库的航运效益;最后,根据以上防洪、发电及航运调度计算的结果,运用第3章水沙多目标决策模型对水库的蓄水时间进行了多目标决策,并采用层次加权均衡规划模型对计算结果进行评价,得到一个能满足水库防洪、发电及航运各方面要求的最佳蓄水方案。
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The first 0x10 bytes is an unknown hash calculated from the decrypted block. It is deduced that is calculated from the decrypted block and not the ciphered one due to the fact that 4.01 and 4.05 have a lot of ipl blocks in common, which, when decrypted, are similar, but they are totally different in its encrypted form.
前面的0x10字节是从译好的模块中计算出来的未知认证代码,之所以可以推断出是从译好的模块计算而来而非密码模块,是因为4.01和4.05有很多共同的初始程序模块,而这些模块在编译之后是相同的,然而他们在密码阶段则完全不相同。
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Through field measurement for the contact pressure of box foundation with Ⅰ shaped plane of a high rise building on cobble subsoil, the distribution law of the contact pressure has been diagrammed. At the same time, the contact pressure has been calculated with finite compression layer model, which is well accordant with the measured result. The relative error of average value for the measured to the calculated contact pressure is 6.9%. This shows that the numerical calculation is right.
通过对西南交通大学某教学楼箱形基础基底反力的实测结果,得出了&Ⅰ&形平面箱基置于密实卵石层上的基底反力分布规律,又用有限压缩层地基模型对该箱基反力进行了计算,结果表明:实测反力与计算反力分布规律一致,实测反力平均值与计算反力平均值相对误差为6.9%,也说明此法计算箱基反力是可行的。
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4According to rationale of dynamic of structures,the program of finiteelement method that calculated largescale dynamic structure is finished.Using theprogram of finite element method,the dottier element of some model gas operatedof rapid-fire gun is calculated.
4根据结构动力学的基本原理编制了计算大型结构动力问题的有限元程序,对某型自动火炮自动机中较薄弱的元件进行了数值分析。
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Resources of several geneses were calculated, migrating parameters and gathering parameters were calculated, and progress was made on translating degassing quantity into resources quantity.
对多成因CO〓进行资源量计算,获取较合理的运移系数和聚集系数,在脱气量和资源量转换研究方面取得进展。
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By means of FEM the magnetic field distributions of AMB are calculated and the coupling phenomena of AMB are discussed. Intercrossing magnetic force, which is used to weigh coupling degree, is calculated also.
采用有限元法对磁力轴承的磁场分布进行了计算和分析,研究了磁力轴承的耦合问题,针对空间电磁力的分布,计算出衡量耦合强弱的交叉电磁力。
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If rock compressibility is calculated by the elastic modulus method, its results are relatively reasonable. But if it is calculated by the Hall Plate empirical formula, the value of rock compressibility is too large. Thai's to say, it overvalues the elastic energy of formation rocks. And the velocity of pressure drawdown of the gas reservoir numerical simulation is caused to be too slow.
由Hall图版经验公式法计算得到的岩石压缩系数偏大,即对地层岩石的弹性能量估计偏大,从而导致气藏数值模拟计算的压降速度偏慢;而采用弹性模量法计算岩石压缩系数,其结果相对较为合理。
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Where a foreign investor reinvests all its annual after-tax profits derived from the enterprise with foreign investment in the same year, and the accumulative reinvestment amount is lower than the above said limited amount, the tax to be refunded shall be calculated on the basis of the actual reinvestment amount; if the accumulative reinvestment amount exceeds the above said limited amount, the tax to be refunded shall be calculated on the basis of the limited amount, and the part in excess shall not be entitled to tax refund.
外国投资者以源于外商投资企业同一年度的全部税后利润再投资的,其再投资额低于上述限额的,按实际投资额计算退税;超过上述限额的,按限额计算退税,超过部分不得计算退税。
- 相关中文对照歌词
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- 推荐网络例句
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Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.
在对危险的南部地区访问时,他斥责什叶派民兵领导人对中央集权的挑衅行为。
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In fact,I've got him on the satellite mobile right now.
实际上 我们已接通卫星可视电话了
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The enrich the peopling of Deng Xiaoping of century great person thought, it is the main component in system of theory of Deng Xiaoping economy, it is a when our country economy builds basic task important facet.
世纪伟人邓小平的富民思想,是邓小平经济理论体系中的重要组成部分,是我国经济建设根本任务的一个重要方面。