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Let C be a nonempty closed convex subset of a Hilbert space H, P:H→C be a nearest point projection, and T:C→H be a nonexpansive mapping satisfying the weakly inwardness condition, and :C→C be a fixed contractive mapping. Let the implicit iterative sequences {x},{y} and the explicit iterative sequences {x},{y}.

设C为实Hilbert空间H的非空闭凸子集，P：H→C为最近点投影映射，T：C→H为非扩张映象，且T满足弱内向条件，：C→C为压缩映象。t∈(0，l)，定义了2种隐式粘性迭代序列{x}，{y}和2种显式粘性迭代序列{x}，{y}，证明了T有不动点当且仅当序列{x}，{y}，{x}，{y}有界。

Compared with the graphite, the coefficients of friction of the RL-C/C are lower under the same load of about 0.08-0.12, and the increasing range of the volume losses are still lower than those of the graphite. Compared with the SL pyrocarbon material, the COF and the volume loss of the SL-C/C are about 0.02-0.05 and 0.2 mm^3, lower than those under the same load. The COFs of most RL-C/C and SL-C/C specimens remain stable or decrease slightly with time, while those of the graphite and pyrocarbon specimens increase. The thickness of the integrated friction film of the RL-C/C decreases with load, but the wear surface of the SL-C/C is rough. Tough the wear surface of the graphite is integrated, the serious abrasive wear make the debris move easily and accumulate on the edge of the wear trace to form a restacked morphology. On the wear surface of the pyrocarbon material, some loosed debris, circular worn holes and flake worn out pyrocarbon has been found.

结果表明：PAN炭纤维改善C/C复合材料的摩擦磨损行为；在实验载荷范围内，与高强度石墨材料相比，含RL炭C/C复合材料的摩擦因数降低0.08~0.12；体积磨损量增幅降低；与热解炭试样相比，具有SL炭C/C复合材料的摩擦因数降低0.02~0.05，体积磨损量低0.2立方公厘左右；随着时间的延长，大部分C/C复合材料的摩擦因数基本相对稳定或呈小幅下降，而石墨、热解炭块的摩擦因数均呈不同幅度的上升；具有RL炭的C/C复合材料摩擦表面膜厚度随载荷增加而降低，具有SL炭的C/C复合材料摩擦表面较粗糙；高强石墨能形成较完整致密的摩擦膜，但磨粒磨损严重，磨屑易在摩擦膜边缘形成层状堆积；热解炭块摩擦表面磨屑堆积松散，有较多的孔洞以及热解炭层整体剥落的形貌。

Compared with the graphite, the coefficients of friction of the RL-C/C are lower under the same load of about 0.080.12, and the increasing range of the volume losses are still lower than those of the graphite. Compared with the SL pyrocarbon material, the COF and the volume loss of the SL-C/C are about 0.020.05 and 0.2 mm3, lower than those under the same load. The COFs of most RL-C/C and SL-C/C specimens remain stable or decrease slightly with time, while those of the graphite and pyrocarbon specimens increase. The thickness of the integrated friction film of the RL-C/C decreases with load, but the wear surface of the SL-C/C is rough. Tough the wear surface of the graphite is integrated, the serious abrasive wear make the debris move easily and accumulate on the edge of the wear trace to form a restacked morphology. On the wear surface of the pyrocarbon material, some loosed debris, circular worn holes and flake worn out pyrocarbon has been found.

结果表明：PAN炭纤维改善C/C复合材料的摩擦磨损行为；在实验载荷范围内，与高强度石墨材料相比，含RL炭C/C复合材料的摩擦因数降低0.08~0.12；体积磨损量增幅降低；与热解炭试样相比，具有SL炭C/C复合材料的摩擦因数降低0.02~0.05，体积磨损量低0.2 mm3左右；随着时间的延长，大部分C/C复合材料的摩擦因数基本相对稳定或呈小幅下降，而石墨、热解炭块的摩擦因数均呈不同幅度的上升；具有RL炭的C/C复合材料摩擦表面膜厚度随载荷增加而降低，具有SL炭的C/C复合材料摩擦表面较粗糙；高强石墨能形成较完整致密的摩擦膜，但磨粒磨损严重，磨屑易在摩擦膜边缘形成层状堆积；热解炭块摩擦表面磨屑堆积松散，有较多的孔洞以及热解炭层整体剥落的形貌。

The results showed that the decomposition of 4-nitroimidazole began with the split of the C—NO2 bond in the temperature range of 185—210℃. The strongly oxidative product NO2 destroyed the instable annulus of 4-nitroimidazole instantly, all the other C＝N, C＝C, C—H and N—H bonds of the five membered ring were broken simultaneously, and the detected gas products of 4-nitroimidazole decomposition were NO2, CO2 and CO.

结果表明，4-硝基咪唑的催化热分解起始于其分子中C-NO2化学键的断裂，温度范围是185~210℃。C-NO2键的强氧化性的裂解产物NO2瞬间作用于4-硝基咪唑分子中不稳定的五员环，使化学键C=N、C=C、C-H和N-H同时被打破。4-硝基咪唑的气体分解产物包括NO2、CO2和CO。

The dissipation factor tip-up D tan d , the change of capacitance D C / C 0, the maximum discharge q max and the mean discharge magnitude q mean , A compared investigation of the correlations between V min , V av and service time were compared with those between D tan d , D C / C 0, q max, q mean and respectively.

对大量的不同运行年数的线棒进行了超声波 V min 和 V av 测量，以及介质损耗角增量 D tan d 、电容变化率 D C / C 0、最大放电量 q max 和平均放电量 q mean 等电气测量试验，对比研究了超声参数( V min 和 V av )和电气测量参数( D tan d 、 D C / C 0、 q max 和 q mean )与运行年数的相关性，发现， V min 和 V av 与的相关性很强，相关系数 R 分别为0.892和0.890，而 D tan d 、 q max 和 q mean 与的相关性较弱， R 在0.55~0.60范围内， D C / C 0与几乎没有相关性， R 仅为0.310；采用线性回归分析，分别建立了 V min 和 V av 与的二阶和三阶线性函数的数学模型， R-S 分别为0.828和0.903，并分别提出了最可靠运行年数和置信度为95％的可靠运行年数的预测方法。

In this thesis,the AM1,MNDO,MINDO/3(mainly AM1)and INDO/S-CI semiempirical MO methods were used toinvestigate the excited-state intramolecular protontransfer reactions of salicylic acid derivatives—salicylic acid,methyl salicylate,salicylaldehyde,o-hydroxyaceto-phenone,salicylamide and 3-hydroxy-picolinamide (6 conformers and 2-3 anion species);2-(2'-hydroxy-5' methylphenyl) benzotriazole(4 conformers),2-(2' hydroxyphenyl) benzimidazole (3 conformers and 3anion species),Bis-2,5-(2-benzoxazolyl)hydroquinone(3 conformers),2-(2'-hydroxyphenyl)benzothiazole(2conformers) and 7-azaindole dimer (2 conformers).Theinvestigations were described as follows.Geometry optimization,relative stability andhydrogen bonding energy First,for sylicylic acid derivative molecules,the AM1,MNDO and MINDO/3 methods were used toinvestigate ground-state geometry optimization,energies,relative stabilities and hydrogen-bondingenergies on the five kinds of the molecules(designing 6 conformers and 2-3 anion species).Comparing with experimental data,the optimizedgeometry,the order of stability,the hydrogen-bonding energies and the distances between O-O in O-H..O hydrogen bonds by AM1 method were in agreementwith the experimental data,however,the C-C bondlengths optimized by MNDO and MINDO/3 were longer,C-O and O-H bond lengths were shorter;for C-N bondlengths,the results opitimized by MNDO method werethe same as those by AM1 method,nevertheless the C-Nbond lengths given by MINDO/3 method were muchshorter.For some sylicylic acid derivatives(e.g.methyl salicylate,salicylamide),the order ofstabilities on the conformers given by MNDO andMINDO/3 methods were not in agreement with theexisting conformers deduced by experimental methods,and the hydrogen bonding energies calculated by MNDO.and MINDO/3 methods were smaller.Second,the studyon the other systems found that the optimizedgeometry of the proton-transfered product with INDOmethod could not be obtained,only could theoptimized geometry of reactant be obtained,and thecalculated hydrogen bonding energies were greater.Many results of calculation indicated that the studyon the excited-state intramolecular proton transferreaction system using AM1 method was suitable andreliable.

本论文用AM1、MNDO、MINDO/3（主要是AM1）和INDO/S-CI半经验分子轨道方法对水杨酸衍生物系列——水杨酸、水杨酸甲酯、水杨醛、O-羟基乙酰苯酮、水杨酰胺和3-羟基吡啶酰胺（6种异构体和2-3种阴离子）；2-（2'-羟基-5'-甲基苯基）苯并三〓唑（4种异构体）；2-（2'-羟基苯基）苯并咪唑（3种异构体和3种阴离子）；2，5-二间氮杂氧茚氢醌（3种异构体）；2-（2'-羟基苯基）间〓杂硫茚（2种异构体）和7-〓吲哚二体（2种异构体）的激发态分子内质子转移反应在以下几个方面进行了较系统的理论研究：几何构型优化和相对稳定性及氢键能首先以水杨酸衍生物系列分子为例，用AM1、MNDO和MINDO/3方法考察了5种分子（每种分子设计6种异构体和2-3种阴离子）的基态几何构型优化，能量、相对稳定性和氢键能计算，通过和实验数据进行比较，AM1方法给出的优化几何构型、稳定性次序、氢键能和O—H。。。O氢键的0—0距离与实验数据吻合最好，MNDO和MINDO/3方法优化的C-C键长偏长，C-O键和O-H键长偏短；对于C-N键长，MNDO和AM1优化结果差别不大，而MINDO/3给出了过短的C-N键长，MNDO和MINDO/3方法给出的有些水杨酸衍生物分子（如水杨酸甲酯和水杨酰胺）异构体的稳定性次序和实验上推测的可存在异构体结果不一致，MNDO和MINDO/3方法给出的氢键能偏低，对其他体系的研究发现INDO方法常常不能得到质子转移产物的优化几何构型，只能得到反应物的优化构型，并且估算的氢键能偏高，大量的计算结果表明AM1方法对本论文研究的激发态分子内质子转移反应体系是适宜和可靠的。

It was revealed that the film was constituted mainly by Zr-C, C=C (s^2) and C-C(sp^3) bonds; structure of the films was crystalline ZrCN embedded in an amorphous carbon and carbonitride matrix. With increasing flow rate, film Zr content decreased, but C and N contents increased.

实验结果表明薄膜结构是由ZrCN晶粒镶嵌在无定形碳和碳氮化合物基体中；膜中的化合键主要以Zr-C，C=C(sp^2)和C-C(sp^3)形式存在；随着混合气体流量的增加，薄膜的锆原子分数减小，而N和C的原子分数逐渐增大。

It indicated that the multiple-layered films were mainly composed by C-F, C=C and Si-O bonging, a little Si-C and Si-F bonding were also existed because of history effect. The bondgap were calculated as 2.7eV. The dielectric constant of the multiple-layered films was close relative to the thickness of the covering layer-SiOx, so the thickness had better be reduce. The bonding configurations of multiple-layered films had no evident changes after 400癈 annealing, the thickness raise very little and the dielectric constant increase 8%. Compared with one-layered a-C:F films prepared in the same conditions, the SiOx/a-C:F/SiOx multiple-layered films had a better thermal stability.

结果表明，多层膜主要由C-F，C=C，Si-O键构成，由于器壁的历史效应，薄膜中还存在少量Si-C和Si-F键；多层膜的光学带隙经计算约为2.7eV；多层膜的介电常数与包层SiO_x厚度有很大关系，应尽可能减小SiO_x厚度；在经历200-400℃的N_2氛围中退火后，多层膜的红外结构没有发生太大的变化：膜厚度稍微增大，介电常数只增加了8％，与同样制备条件下沉积的单层a-C：F薄膜相比具有较好的热稳定性。

The results show that the films are characterized by the amorphous microstructure and mainly composed of Si C bondings, C C bondings as well as a small mount of oxide impurity consorted with Si; the content of the C C bondings decreased after annealing in vacuum, meanwhile the Si C bondings content increased, annealing in vacuum is beneficial to the formation of SiC; after annealing at 800 in air, a thin dense layer of SiO2 formed on the surface, which prevented the oxygen from contacting with the film and effectively protected the inner SiC from oxidizing.

结果表明，薄膜主要以非晶为主，由Si--C键， C--C键和少量Si的氧化物杂质组成；在真空条件下经高温退火后，薄膜C--C键的含量减少，而Si--C键的含量增加，真空退火有利于SiC的形成；在800℃空气中退火后，薄膜表面生成一层致密的SiO2薄层，阻止了氧气与薄膜内部深层的接触，有效保护了内部的SiC。

The results show that the torsion energy and van der Waals interaction energy are the main types of energy and the substitution group has a great effect on the total energy of molecular. The aliphatic substitution would lead to the increase of total energy, while the aromatic substitution would lead to the decrease of total energy. The calculated results of bond length show that the bond length of aliphatic C���C is longer than that of aromatic C���C, which indicates that the rupture of aliphatic C���C is easier than that of aromatic C���C on heating.

研究结果表明，扭转能和范德华能是分子中的主要作用力，取代基对体系能量有明显影响，烷基取代基使体系能量增加，而苯基取代基使体系能量降低；脂肪C—C键长比芳香C—C键长长，说明脂肪C—C在受热过程中比芳香C—C更容易断裂分解。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。