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Both crystallographically unique Zn atoms exit as an octahedral geometry. The four equatorial positions of Zn1 atom are occupied by the carboxylate-oxygen atoms of the two tartrates, and the two oxygens of the left four carboxylate-oxygen atoms coordinate to two different Zn2 atoms, respectively, forming infinite coordination polymer chains. The left two of the trans equatorial positions of Zn2 atom are completed with two oxygen atoms of two water molecules. The axial positions of both Zn atoms are occupied by the nitrogen atoms from different 4,4'-bipyridine molecules to give a 2D rectangular-grid layers with a cavity dimension of 0.51165(3)nm×1.13896(5) nm. A three dimensional network is formed by the crystallization water chains joined by the carboxylate-oxygen atoms through hydrogen-bonding interactions.

两个晶体学独立的Zn原子均为八面体构型,其中Zn1原子赤道配位点被2个酒石酸根中的4个羧酸根氧螯合配位, 2个酒石酸根中剩下的4个羧酸根氧中的2个分别与2个Zn2原子连接形成无限一维链, Zn2原子的另外2个反式赤道配位点被2个水分子氧占据,同时这两种Zn原子的轴向配位点均被4,4'-联吡啶的氮原子占据,形成具有矩形格子[0.51165(3) nm×1.13896(5) nm]的二维层状结构,游离的2个水分子通过氢键作用形成二聚体,并与酒石酸根中未与Zn配位的羧酸氧连接,把二维层状结构连接成三维网状的超分子结构。

Its test result, after using agent of sewage disposal of biology of carapace god ocean and technology of flood body rehabilitate, build good oxygen biology to stabilize a bed, processing sewage effect is apparent, expression is: Black smelly sewage is rapid decolour, deodorization, become clear, insipidity, the COD after handling two days by 333 drop 76, achieve view and admire water and the water quality demand that breed water, can develop aquatic substance. A green alga, red snapper grows to feed after 4 days wait for primary live thing, breed the water biology such as water hyacinth to be able to put in a suitable place to breed view and admire a fish.

其试验结果,运用甲壳神海洋生物污水处理(通过物化方法去除水中一些物质的过程)剂和大水体修复技术后,建立好氧生物稳定床,处理污水效果明显,表现为:黑臭的污水迅速脱色、脱臭,变得澄清、无味,处理两天后COD由333下降到76,达到观赏水和养殖水的水质要求,可培养水生物。4天后长出绿藻、红鱼食等初级生物,养殖水葫芦等水生物并可放养观赏鱼。

The furnace body is made ф2200×1500 the outer covering main body by the 12mm steel plate, lower part the furnace body 45° the installment has the sensor, the sensor orientation silicon steel plate is made the weight 2 ton induction iron cores by Wuhan Steel Corporation Silicon steel plate Factory production top gear's W-151 the cold rolling 0.35m/m, primary is made the water cooling coil by 10×10×2 the copper pipe, and installs the stainless steel water cooling restricting, the power frequency has the core smelting furnace's metal melt fluid namely for the sensor sencondary coil, the entire electric stove is a transformer actually, the necessary 6 grades from the pair regulating transformer, shift gears by the electricity cabinet control, the voltage may from low to high, divide 6 promotions to arrive at 380V, each grade of voltages are different, the output is also different, the furnace temperature along with the files position is also different, but the height is different, adapts smelts colored or the black and so on melting point different metals, and may make the new furnace lining to smelt diamantine drying furnace fireproof.

炉体由12mm钢板制成Ф2200×1500外壳主体,炉体下部45°安装有感应器,感应器由武钢硅钢片厂生产的最高档的W-151冷轧0.35m/m取向硅钢片制成重2吨感应铁心,初级由10×10×2铜管制成水冷线圈,并安装不锈钢水冷保护套,工频有芯熔炼炉的金属熔液即为感应器的次级线圈,整个电炉实际就是一个变压器,配套一台6档的自耦调压变压器,由电柜控制换档,电压可由低到高,分6级升到380V,每档电压不同,输出功率也不同,炉温也随档位不同而高低不同,以适应熔炼有色或黑色等熔点不同的金属,并可作新炉衬耐火冶金砂烘炉之用。

The furnace body is made ф2200×1500 theouter covering main body by the 12mm steel plate, lower part the furnace body 45° the installment has the sensor, the sensor orientation silicon steel plate is made the weight 2 ton induction iron cores by Wuhan Steel Corporation Silicon steel plate Factory production top gear's W-151 the cold rolling0.35m/m, primary is made the water cooling coil by 10×10×2 the copper pipe, and installs the stainless steel water cooling restricting, the power frequency has the core smelting furnace's metal melt fluid namely for the sensor sencondary coil, the entire electric stove is a transformer actually, thenecessary 6 grades from the pair regulating transformer, shift gears by the electricity cabinet control, the voltage may from low to high, divide 6 promotions to arrive at 380V, each grade of voltages are different, the output is also different, the furnace temperature along with the files position isalso different, but the height is different, adapts smelts colored or the black and so on melting point different metals, and may make the new furnace lining to smelt diamantine drying furnace fireproof.

炉体由12mm钢板制成Ф2200×1500外壳主体,炉体下部45°安装有感应器,感应器由武钢硅钢片厂生产的最高档的W-151冷轧0.35m/m取向硅钢片制成重2吨感应铁心,初级由10×10×2铜管制成水冷线圈,并安装不锈钢水冷保护套,工频有芯熔炼炉的金属熔液即为感应器的次级线圈,整个电炉实际就是一个变压器,配套一台6档的自耦调压变压器,由电柜控制换档,电压可由低到高,分6级升到380V,每档电压不同,输出功率也不同,炉温也随档位不同而高低不同,以适应熔炼有色或黑色等熔点不同的金属,并可作新炉衬耐火冶金砂烘炉之用。

Because of this property, water is preferentially adsorbed by these surfaces, and large organic compounds cannot compete with strongly held water for adsorption sites on the clay surfaces. Thus, Na-clays are ine_ective sorbents for small organic molecules. However, it is possible to modify the surface properties of clays greatly by neutralizing the anionic framework of layer silicates by using positively charged organic species such as alkylammonim ions. In the modi_ed form (HDTMA-bentonite), the clay surface may become organophilic and interact strongly with organic compounds. Textile dyes represent a relatively large group of organic chemicals. In an HDTMA-bentonite-dye system it is possible that adsorption may be enhanced by the hydrophobic interaction between the adsorbed dye molecule and HDTMA-bentonite.

O组给予亲水的性质到矿物表面,因为这水是吸附在这些表面,和大的有机化合物不能比有坚强的为了吸附位置在泥土表面,因而,Na—泥土是ine_ective吸附剂为了小的分子,希,它是可能的到更改的表面属性,泥土非常在抵销anionic层硅酸盐在用的结构 Positively负荷的物种例如alkylammonim离子,在mod i_ed形状,泥土表面可能变成organophilic和互相作用坚强地有机化合物,织物染料表现相关的大的组化学的,在HDTMA—斑脱土—染料系统它是可能的那吸附可能是提高在交互作用在中间吸附染料分子和HDTMA—斑脱土,interlamellarHDTMA的间隔—斑脱土是获得在substracting泥土层从的厚度实验上坚决的基础的间隔(d001)。

The regulating reservoir water leakage enters the oxygen unit, through the biological degeneration function, enable the organic pollutant to obtain the thorough degeneration, the good oxygen unit enters the water to enter the precipitation unit, the precipitation unit water leakage flows automatically enters the middle basin; In the middle basin by the pump promotion to the micro flocculation unit, in the water before the residual soluble organic matter and the filtration throws the coagulant response production suspended solid which adds through the filtration pot filtration, the micro flocculation filtration water leakage enters the disinfection area, achieves the sterilization goal in the disinfection area using the chlorine dioxide strong oxidability.

调节池出水进入好氧单元,通过生物的降解作用,使有机污染物得到彻底的降解,好氧单元进水进入沉淀单元,沉淀单元出水自流进入中间水池;在中间水池由泵提升至微絮凝单元,水中残留溶解性有机物与过滤前投加的混凝剂反应生成悬浮固体通过过滤罐滤除,微絮凝过滤出水进入消毒区,在消毒区内利用二氧化氯的强氧化性达到杀菌目的。

The feasibility of the equipment to measure Tg of amorphous powder is verified with a lot of experimentl results.The Tgs of some typical starches such as corn, pachyrhizus, buckwheat and pea in different water content are obtained by TDA. It is found that the water has plastic effect on starch and the Tg of starch decreases with the increase of water content. Through this study a quantitative expression is established to relate Tg and water content, and it is testified with experimental results for the sticky rice starch with different water content.

采用热膨胀法测定不同含水量下玉米、地瓜、荞麦、豌豆淀粉的玻璃化转变温度,得到了随着含水量的增加Tg降低的关系,探讨了水的增塑作用及影响机理,得到含水量与Tg的定量表达式,并用糯米淀粉的实验值对该关联式的有效性进行了验证,为预测不同含水量的淀粉的玻璃化转变温度及对淀粉的储藏加工提供了理论依据。

1 Water stored in soils. 2 One of the most important elements involved in pedological processes and plant growth. There are three basic form-: water adhering in thin films by molecular attraction to the surface of soil particles and not available for plants is termed hygroscopic water. b Water forming thicker films and occupying the smaller pore spaces is termed capillary water.

储藏在土壤中的水分,2)在土壤过程和植物生长中最重要的元素之一,有三种基本形态-:(s:a 藉分子间引力以薄膜形式附著在土壤颗粒表面的水分,不能被植物利用,称为吸湿性水, b形成厚的水膜填充在较小土壤气孔中,称为毛细管水。

In order to clear heterogeneous reservoirs waterflooding performance, and decreased interlayer and within-layer contradictions, and improved the water flooding recovery, experimental study should be conducted first, This paper based on Pucheng Sasan reservoir sandstone cores to study object. Multi-point pressure measurement of water flooding oil experimental apparatus was established. Through the three-layer water flooding experiment to study injection strategy, interlayer interference and recovery factors. True sandstone micro-model water flooding used newly developed color visual image analysis system researched water-drive types, forms of residual oil and waterflood efficiency. Percolation mathematical model was established, black oil simulation program was developed, long-core displacement experimental results were matched, pressure and saturation change were researched by the simulation matching results.

为了明确非均质储层注水开发动态过程,减轻由于层间和层内非均质造成的开发矛盾,提高水驱采收率,本文从实验研究出发,以濮城沙三储层岩心为研究对象,建立了一套带多测压点的多层长岩心水驱油实验装置,通过开展三层水驱油实验,研究注水方式、层间干扰以及采收率影响因素;真实砂岩微观模型水驱油实验采用最新研制的彩色可视化图像分析系统研究水驱类型、残余油形成类型以及水驱油效率;建立并求解渗流数学模型,编制黑油模拟程序,对长岩心驱替实验进行拟合,通过拟合结果研究驱替过程中油水饱和度和压力的变化情况等研究工作。

Results show that the water environment of the upper Huangpu River is affected integratedly by land use and flow from the upper reaches; river water quality is negatively related to proportion of industrial land in the sample zones; and the water quality at the water catchment near the Songpu Bridge is closely related to the water quality of the flow coming down from the upper streams, and driving forces of change in land use, such as development of the industry and population density in the waterhead region.

结果表明,黄浦江上游水环境质量受到土地利用格局及上游来水的综合影响,各样带工业用地比例与水质改善指数呈极显著负相关(P.01),松浦大桥取水口水质与上游来水水质以及水源地当地的工业发展、人口密度等土地利用变化驱动力具有很好的关联性。

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